Tetraferriphlogopite
A valid IMA mineral species - grandfathered
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About Tetraferriphlogopite
Formula:
KMg3(Fe3+Si3O10)(OH,F)2
Crystal System:
Monoclinic
Member of:
Name:
Named for its composition and crystal structure, containing iron 3+ cations (FERRIc, from Latin ferrum = 'iron') in TETRAhedrally coordinated sites, and its chemical relationship to phlogopite. During the IMA mica nomenclature review of 1998, the assigned name was tetra-ferriphlogopite, with a hyphen. The hyphen was removed by the IMA in 2008.
Mica Group.
The hydroxyl analogue of fluorotetraferriphlogopite and the magnesium analogue of tetraferriannite.
The hydroxyl analogue of fluorotetraferriphlogopite and the magnesium analogue of tetraferriannite.
Unique Identifiers
Mindat ID:
3922
Long-form identifier:
mindat:1:1:3922:8
IMA Classification of Tetraferriphlogopite
Approved, 'Grandfathered' (first described prior to 1959)
IMA status notes:
Renamed by the IMA
IMA Formula:
KMg3(Si3Fe3+)O10(OH)2
Approval year:
2008
Classification of Tetraferriphlogopite
9.EC.20
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference |
|---|---|---|
| Tfphl | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Tpf | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
| Tfphl | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30 |
Chemistry of Tetraferriphlogopite
Mindat Formula:
KMg3(Fe3+Si3O10)(OH,F)2
Element Weights:
Crystallography of Tetraferriphlogopite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 5.362 Å, b = 9.288 Å, c = 10.321 Å
β = 99.99°
β = 99.99°
Ratio:
a:b:c = 0.577 : 1 : 1.111
Unit Cell V:
506.22 ų (Calculated from Unit Cell)
Comment:
1M polytype
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4a: Earth’s earliest continental crust | >4.4-3.0 |
| 19 : Granitic intrusive rocks |
Type Occurrence of Tetraferriphlogopite
Place of Conservation of Type Material:
No designated type material.
Other Language Names for Tetraferriphlogopite
Dutch:Tetraferriphlogopiet
German:Tetraferriphlogopit
Russian:Тетраферрифлогопит
Spanish:Tetraferriphlogopita
Relationship of Tetraferriphlogopite to other Species
Member of:
Other Members of Biotite:
| Annite | KFe2+3(AlSi3O10)(OH)2 | Mon. 2/m : B2/m |
| Eastonite | KMg2Al(Al2Si2O10)(OH)2 | Mon. |
| Fluorannite | KFe2+3(Si3Al)O10F2 | Mon. 2/m : B2/m |
| Fluorophlogopite | KMg3(Si3Al)O10F2 | Mon. 2/m : B2/m |
| Fluorotetraferriphlogopite | KMg3(Fe3+Si3O10)F2 | Mon. 2/m : B2/m |
| Oxyphlogopite | K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2 | Mon. 2/m : B2/m |
| Phlogopite | KMg3(AlSi3O10)(OH)2 | Mon. 2/m : B2/m |
| Siderophyllite | KFe2+2Al(Al2Si2O10)(OH)2 | Mon. |
| Tetraferriannite | KFe2+3(Si3Fe3+)O10(OH)2 | Mon. 2/m : B2/m |
Common Associates
Associated Minerals Based on Photo Data:
| 5 photos of Tetraferriphlogopite associated with Pyroaurite-2H | Mg6Fe3+2(OH)16(CO3) · 4H2O |
| 3 photos of Tetraferriphlogopite associated with Albite | Na(AlSi3O8) |
| 3 photos of Tetraferriphlogopite associated with Calcite | CaCO3 |
| 3 photos of Tetraferriphlogopite associated with Fluorapatite | Ca5(PO4)3F |
| 3 photos of Tetraferriphlogopite associated with Pyrochlore Group | A2Nb2(O,OH)6Z |
| 2 photos of Tetraferriphlogopite associated with Armalcolite | (Mg,Fe2+)Ti2O5 |
| 2 photos of Tetraferriphlogopite associated with Sanidine | K(AlSi3O8) |
| 2 photos of Tetraferriphlogopite associated with Richterite | Na(NaCa)Mg5(Si8O22)(OH)2 |
| 2 photos of Tetraferriphlogopite associated with Chalcopyrite | CuFeS2 |
| 1 photo of Tetraferriphlogopite associated with Forsterite | Mg2SiO4 |
Related Minerals - Strunz-mindat Grouping
| 9.EC. | Meifuite | KFe6(Si7Al)O19(OH)4Cl2 |
| 9.EC. | Balestraite | KLi2V5+Si4O12 |
| 9.EC.05 | Talc | Mg3Si4O10(OH)2 |
| 9.EC.05 | Minnesotaite | Fe2+3Si4O10(OH)2 |
| 9.EC.05 | Willemseite | Ni3Si4O10(OH)2 |
| 9.EC.9.EC. | Voloshinite | Rb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2 |
| 9.EC.10 | Fluorluanshiweiite | KLiAl1.5(Si3.5Al0.5)O10F2 |
| 9.EC.10 | Garmite | CsLiMg2(Si4O10)F2 |
| 9.EC.10 | Gorbunovite | CsLi2(Ti,Fe)Si4O10(F,OH,O)2 |
| 9.EC.10 | Ferripyrophyllite | Fe3+Si2O5(OH) |
| 9.EC.10 | Manganiceladonite | K(MgMn3+◻)(Si4O10)(OH)2 |
| 9.EC.10 | Luanshiweiite | KLiAl1.5(Si3.5Al0.5)O10(OH)2 |
| 9.EC.10 | Pyrophyllite | Al2Si4O10(OH)2 |
| 9.EC.15 | Paragonite | NaAl2(AlSi3O10)(OH)2 |
| 9.EC.15 | Ferroaluminoceladonite | K(Fe2+Al◻)(Si4O10)(OH)2 |
| 9.EC.15 | Nanpingite | CsAl2(AlSi3O10)(OH,F)2 |
| 9.EC.15 | Ferroceladonite | K(Fe2+Fe3+◻)(Si4O10)(OH)2 |
| 9.EC.15 | Ganterite | (Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2 |
| 9.EC.15 | Kreiterite | CsLi2Fe3+(Si4O10)F2 |
| 9.EC.15 | Roscoelite | KV3+2(AlSi3O10)(OH)2 |
| 9.EC.15 | Aluminoceladonite | K(MgAl◻)(Si4O10)(OH)2 |
| 9.EC.15 | Tobelite | (NH4)Al2(AlSi3O10)(OH)2 |
| 9.EC.15 | Tainiolite | KLiMg2(Si4O10)F2 |
| 9.EC.15 | Celadonite | K(MgFe3+◻)(Si4O10)(OH)2 |
| 9.EC.15 | Chromceladonite | K(MgCr◻)(Si4O10)(OH)2 |
| 9.EC.15 | Montdorite | KFe2+1.5Mn2+0.5Mg0.5Si4O10(F,OH)2 |
| 9.EC.15 | Chromphyllite | KCr2(AlSi3O10)(OH)2 |
| 9.EC.15 | Boromuscovite | KAl2(BSi3O10)(OH)2 |
| 9.EC.15 | UM1988-22-SiO:AlCaFFeHKLiMg | KLiMgAl2Si3O10F2 |
| 9.EC.15 | Chernykhite | (Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2 |
| 9.EC.15 | Muscovite | KAl2(AlSi3O10)(OH)2 |
| 9.EC.20 | Masutomilite | K(LiAlMn2+)[AlSi3O10]F2 |
| 9.EC.20 | Oxyphlogopite | K(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2 |
| 9.EC.20 | Chloroferrokinoshitalite | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2 |
| 9.EC.20 | Siderophyllite | KFe2+2Al(Al2Si2O10)(OH)2 |
| 9.EC.20 | Sokolovaite | CsLi2Al(Si4O10)F2 |
| 9.EC.20 | Hendricksite | KZn3(Si3Al)O10(OH)2 |
| 9.EC.20 | Fluorannite | KFe2+3(Si3Al)O10F2 |
| 9.EC.20 | Aspidolite | NaMg3(AlSi3O10)(OH)2 |
| 9.EC.20 | Suhailite | (NH4)Fe2+3(AlSi3O10)(OH)2 |
| 9.EC.20 | Ephesite | NaLiAl2(Al2Si2O10)(OH)2 |
| 9.EC.20 | Norrishite | KLiMn3+2(Si4O10)O2 |
| 9.EC.20 | Phlogopite | KMg3(AlSi3O10)(OH)2 |
| 9.EC.20 | Yangzhumingite | KMg2.5(Si4O10)F2 |
| 9.EC.20 | Orlovite | KLi2Ti(Si4O10)OF |
| 9.EC.20 | Tetraferriannite | KFe2+3(Si3Fe3+)O10(OH)2 |
| 9.EC.20 | Shirokshinite | K(NaMg2)(Si4O10)F2 |
| 9.EC.20 | Trilithionite | K(Li1.5Al1.5)(AlSi3O10)(F,OH)2 |
| 9.EC.20 | Polylithionite | KLi2Al(Si4O10)(F,OH)2 |
| 9.EC.20 | Shirozulite | KMn2+3(Si3Al)O10(OH)2 |
| 9.EC.20 | Preiswerkite | NaMg2Al(Al2Si2O10)(OH)2 |
| 9.EC.20 | Fluorophlogopite | KMg3(Si3Al)O10F2 |
| 9.EC.20 | Wonesite | (Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4 |
| 9.EC.20 | UM2004-49-SiO:AlCsFHKLi | (Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2 |
| 9.EC.20 | Fluorotetraferriphlogopite | KMg3(Fe3+Si3O10)F2 |
| 9.EC.20 | Annite | KFe2+3(AlSi3O10)(OH)2 |
| 9.EC.20 | Eastonite | KMg2Al(Al2Si2O10)(OH)2 |
| 9.EC.22 | Pimelite | Ni3Si4O10(OH)2 · 4H2O |
| 9.EC.30 | Margarite | CaAl2(Al2Si2O10)(OH)2 |
| 9.EC.30 | Chlorophaeite | (Ca,Mg,Fe)2Fe2Si4O13 · 10H2O |
| 9.EC.35 | Kinoshitalite | (Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2 |
| 9.EC.35 | Ferrokinoshitalite | (Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2 |
| 9.EC.35 | Clintonite | CaAlMg2(SiAl3O10)(OH)2 |
| 9.EC.35 | Oxykinoshitalite | (Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2 |
| 9.EC.35 | Fluorokinoshitalite | BaMg3(Al2Si2O10)F2 |
| 9.EC.35 | Bityite | CaLiAl2(AlBeSi2O10)(OH)2 |
| 9.EC.35 | Anandite | (Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2 |
| 9.EC.40 | Montmorillonite | (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O |
| 9.EC.40 | Beidellite | (Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.40 | Volkonskoite | Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.40 | Nontronite | Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.40 | Kurumsakite | (Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?) |
| 9.EC.40 | Yakhontovite | (Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O |
| 9.EC.45 | Swinefordite | Li(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2O |
| 9.EC.45 | Hectorite | Na0.3(Mg,Li)3(Si4O10)(F,OH)2 |
| 9.EC.45 | Zincsilite | Zn3Si4O10(OH)2 · 4H2O (?) |
| 9.EC.45 | Hanjiangite | Ba2CaV3+Al(H2AlSi3O12)(CO3)2F |
| 9.EC.45 | Spadaite | MgSiO2(OH)2 · H2O (?) |
| 9.EC.45 | Ferrosaponite | Ca0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.45 | Stevensite | (Ca,Na)xMg3-x(Si4O10)(OH)2 |
| 9.EC.45 | Saponite | Ca0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O |
| 9.EC.45 | Sauconite | Na0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O |
| 9.EC.50 | Vermiculite | Mg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2O |
| 9.EC.52 | Tarasovite | near NaKAl11Si13O40(OH)9 · 3H2O |
| 9.EC.55 | Clinochlore | Mg5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Borocookeite | (LiAl4◻)[BSi3O10](OH)8 |
| 9.EC.55 | Franklinfurnaceite | Ca2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8 |
| 9.EC.55 | Pennantite | Mn2+5Al(AlSi3O10)(OH)8 |
| 9.EC.55 | Vakhrushevaite | Mg5Cr(AlSi3O10)(OH)8 |
| 9.EC.55 | Nimite | (Ni,Mg,Al)6((Si,Al)4O10)(OH)8 |
| 9.EC.55 | Cookeite | (LiAl4◻)[AlSi3O10](OH)8 |
| 9.EC.55 | Gonyerite | (Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8 |
| 9.EC.55 | Chamosite | (Fe2+,Mg,Al,Fe3+)6(Si,Al)4O10(OH,O)8 |
| 9.EC.55 | Orthochamosite | (Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8 |
| 9.EC.55 | Baileychlore | (Zn,Fe2+,Al,Mg)6(Si,Al)4O10(OH)8 |
| 9.EC.55 | Sudoite | Mg2Al3(Si3Al)O10)(OH)8 |
| 9.EC.55 | Glagolevite | Na(Mg,Al)6(AlSi3O10)(OH,O)8 |
| 9.EC.55 | Donbassite | Al4.33(Si3Al)O10(OH)8 |
| 9.EC.60 | Dozyite | Mg7Al2(Al2Si4O15)(OH)12 |
| 9.EC.60 | Rectorite | (Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O |
| 9.EC.60 | Corrensite | (Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O |
| 9.EC.60 | Aliettite | Ca0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O |
| 9.EC.60 | Karpinskite | (Ni,Mg)2Si2O5(OH)2 (?) |
| 9.EC.60 | Lunijianlaite | Li0.7Al6.2(AlSi7O20)(OH,O)10 |
| 9.EC.60 | Tosudite | Na0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O |
| 9.EC.60 | Hydrobiotite | K(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2O |
| 9.EC.60 | Saliotite | (Li,Na)Al3(AlSi3O10)(OH)5 |
| 9.EC.60 | Kulkeite | Mg8Al(AlSi7O20)(OH)10 |
| 9.EC.60 | Brinrobertsite | Na0.3Al4(Si4O10)2(OH)4 · 3.5 H2O |
| 9.EC.65 | Macaulayite | (Fe,Al)24Si4O43(OH)2 |
| 9.EC.70 | Burckhardtite | Pb2(Fe3+Te6+)[AlSi3O8]O6 |
| 9.EC.75 | Niksergievite | (Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2O |
| 9.EC.75 | Ferrisurite | (Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2O |
| 9.EC.75 | Surite | (Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2 |
| 9.EC.80 | Kegelite | Pb8Al4(Si8O20)(SO4)2(CO3)4(OH)8 |
Radioactivity
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Tetraferriphlogopite
mindat.org URL:
https://www.mindat.org/min-3922.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
References for Tetraferriphlogopite
Reference List:
Wahl, W. (1925) Die Gesteine des Wiborger Rapakiwigebietes [The rocks of the Vyborg Rapakivi area]. Fennia Vol. 45 (20). Geographical Society of Finland p.1-126. pp.83-88
Brigatti, Maria Franca (1996) Refinement of the Structure of Natural Ferriphlogopite. Clays and Clay Minerals, 44 (4) 540-545 doi:10.1346/ccmn.1996.0440413
Jambor, John L.; Pertsev, Nikolai N.; Roberts, Andrew C. (1997) New Mineral Names. American Mineralogist, 82 (3-4). 430-433
Rieder, M., Cavazzini, G., D’Yakonov, Y.S., Frank-Kamenetskii, V.A., Gottardt, G., Guggenheim, S., Koval, P.V., Muller, G., Neiva, A.M.R., Radoslovich, E.W., Robert, J.L., Sassi, F.P., Takeda, H., Weiss, Z., Wones, D.R. (1998) Nomenclature of the micas. The Canadian Mineralogist, 36 (3) 905-912
Redhammer, G. J., Amthauer, G., Lottermoser, W., Bernroider, M., Tippelt, G., Roth, G. (2005) X-ray powder diffraction and 57Fe – Mössbauer spectroscopy of synthetic trioctahedral micas {K}[Me3]⟨TSi3⟩O10(OH)2, Me = Ni2+, Mg2+, Co2+, Fe2+; T = Al3+, Fe3+. Mineralogy and Petrology, 85 (1-2). 89-115 doi:10.1007/s00710-005-0096-2
Localities for Tetraferriphlogopite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Afghanistan | |
| Vikhter et al. (1976) +1 other reference |
Angola | |
| Lapido-Loureiro +3 other references |
| Gonçalves +1 other reference |
| Amores-Casals et al. (2019) |
Antarctica | |
| Luttinen et al. (2002) |
Australia | |
| Black et al. (1978) +3 other references |
| Woolley (2019) |
| Dunkan et al. (1990) +4 other references |
| Hamilton et al. (1990) |
| Atkinson et al. (1984) +5 other references |
| Jaques et al. (1986) +1 other reference |
Belarus | |
| Mikhailov +6 other references |
Brazil | |
| Silva et al. (2019) |
| Guarino (2010) | |
| Traversa et al. (2001) |
| Traversa et al. (2001) | |
| Barbosa et al. (2020) |
| Comin-Chiaramonti et al. (2008) |
| Comin-Chiaramonti et al. (2008) | |
Canada | |
| Chakhmouradian et al. (2002) |
| Kamenetsky et al. (2013) |
| Abersteiner et al. (2020) | |
| Abersteiner et al. (2018) | |
| Digonnet et al. (2000) +1 other reference |
China | |
| Jinhua Hao et al. (2010) |
| Weng et al. (2022) |
Czech Republic | |
| Ulrych et al. (1996) |
DR Congo | |
| Woolley et al. (1995) +1 other reference |
Finland | |
| Mutanen |
| Albers +21 other references |
| Kresten et al. (1977) +2 other references |
| Puustinnen +14 other references |
| Puustinen (1973) | |
Greenland | |
| Tappe et al. (2009) |
India | |
| Kaur et al. (2016) |
| Kaur et al. (2013) | |
| Bergman (1987) |
| Basu et al. (1982) +1 other reference |
| Subrahmanyam et al. (1977) +3 other references |
| Kaur et al. (2016) |
| Middlemost et al. (1988) +1 other reference |
| Kent et al. (1998) |
Namibia | |
| Jackson +6 other references |
Norway | |
| Mitchell (1980) |
| Mitchell (1980) |
| Zozulya et al. (2010) +1 other reference |
| Zozulya et al. (2010) +1 other reference | |
Russia | |
| Golovin et al. (2023) |
| Ripp et al. (2019) |
| Nedosekova (2007) +1 other reference |
| Vladykin et al. (2008) |
| Koneva A.A. et al. (2010) |
| Lennikov et al. (2004) |
| Ras et al. (2011) +1 other reference |
| Nedosekova et al. (2021) | |
| Sharygin et al. (2017, August) |
| Zaitsev et al. (2022) |
| Zaitsev et al. (2014) +2 other references |
| Haas (n.d.) | |
| World of Stones 95: 5-6 +3 other references |
| ... | |
| ... +1 other reference |
| ... +1 other reference |
| Putintseva et al. (2017) |
| Doroshkevich et al. (2022) |
| Rezvukhin +7 other references |
| Sharygin et al. (2021, October) |
| Sharygin (2016) +2 other references |
Serbia | |
| Glišic +2 other references |
South Africa | |
| Kamenetsky et al. (2014) |
| Tarasov et al. (2021, April) +1 other reference |
| Abersteiner et al. (2024) |
| Henrietta Farr et al. (2018) |
Sweden | |
| Holtstam et al. (1999) |
Ukraine | |
| Ryabchikov et al. (2008) |
USA | |
| Scott Smith et al. (1984) |
| Hutchinson et al. (2022) |
Venezuela | |
| Sharygin et al. (2009) |
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The
Kovdor Zheleznyi Mine, Kovdor Massif, Kovdorsky District, Murmansk Oblast, Russia