Carrboydite
A valid IMA mineral species - questionable
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About Carrboydite
Formula:
(Ni1-xAlx)(SO4)x/2(OH)2 · nH2O
(x<0.5, n>3x/2)
Colour:
Yellowish-green, blue-green
Lustre:
Waxy, Dull
Specific Gravity:
2.50
Crystal System:
Hexagonal
Member of:
Name:
Named for the Carr Boyd nickel mine, Australia, the type locality.
As part of the recent re-evaluation of the nomenclature of the hydrotalcite supergroup (Mills et al., 2012), carrboydite was identified as a questionable species which needs further investigation.
Unique Identifiers
Mindat ID:
910
Long-form identifier:
mindat:1:1:910:4
IMA Classification of Carrboydite
Approved, Questionable
IMA Formula:
(Ni1-xAlx)(SO4)x/2(OH)2 · nH2O (x 3x/2)
First published:
1976
Classification of Carrboydite
7.DD.35
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
31.10.1.1
31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
10 : Miscellaneous
31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
10 : Miscellaneous
12.2.22
12 : Carbonates with other anions
2 : Carbonates with sulphate
12 : Carbonates with other anions
2 : Carbonates with sulphate
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference |
|---|---|---|
| Cby | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Cby | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30 |
Physical Properties of Carrboydite
Waxy, Dull
Transparency:
Translucent
Colour:
Yellowish-green, blue-green
Density:
2.50 g/cm3 (Measured) 2.692 g/cm3 (Calculated)
Optical Data of Carrboydite
Type:
Uniaxial (-)
RI values:
nω = 1.56 nε = 1.54
Max. Birefringence:
δ = 0.020
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
Surface Relief:
Moderate
Comments:
may be biaxial (–)
Chemistry of Carrboydite
Mindat Formula:
(Ni1-xAlx)(SO4)x/2(OH)2 · nH2O
(x<0.5, n>3x/2)
(x<0.5, n>3x/2)
Crystallography of Carrboydite
Crystal System:
Hexagonal
Cell Parameters:
a = 9.14 Å, c = 10.34 Å
Ratio:
a:c = 1 : 1.131
Unit Cell V:
748.07 ų (Calculated from Unit Cell)
Z:
1
Comment:
Point Group: n.d; Space Group: n.d.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 10.5 Å | (vs) |
| 5.25 Å | (s) |
| 2.55 Å | (ms) |
| 3.48 Å | (m) |
| 1.51 Å | (m) |
| 2.62 Å | (w) |
| 2.36 Å | (wb) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47b : [Sulfates and sulfites] |
Type Occurrence of Carrboydite
Place of Conservation of Type Material:
Western Australian Museum, Perth, Australia, M.74.1991.
National Museum of Natural History, Washington, D.C., USA, 135930.
National Museum of Natural History, Washington, D.C., USA, 135930.
Geological Setting of Type Material:
secondary mineral in the oxidized zone of nickel sulfide deposits
Associated Minerals at Type Locality:
Synonyms of Carrboydite
Other Language Names for Carrboydite
Relationship of Carrboydite to other Species
Member of:
Other Members of Glaucocerinite Group:
| Glaucocerinite | (Zn1-xAlx)(OH)2(SO4)x/2 · nH2O | Hex. |
| Hydrohonessite | (Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2O | Hex. |
| Hydrowoodwardite | (Cu1-xAlx)(OH)2[SO4]x/2 · nH2O | Trig. 3m (3 2/m) : R3m |
| Mountkeithite | [(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2O | Hex. |
| Zincaluminite | (Zn1-xAlx)(SO4)x/2(OH)2 · nH2O |
Common Associates
Associated Minerals Based on Photo Data:
| 2 photos of Carrboydite associated with Gillardite | Cu3Ni(OH)6Cl2 |
| 2 photos of Carrboydite associated with Gaspéite | NiCO3 |
| 2 photos of Carrboydite associated with Gypsum | CaSO4 · 2H2O |
| 1 photo of Carrboydite associated with Aurichalcite | (Zn,Cu)5(CO3)2(OH)6 |
| 1 photo of Carrboydite associated with Jarosite | KFe3+3(SO4)2(OH)6 |
Related Minerals - Strunz-mindat Grouping
| 7.DD. | Asagiite | NiCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.05 | Felsőbányaite | Al4(SO4)(OH)10 · 4H2O |
| 7.DD.07 | Llantenesite | Cu6Al[SeO4](OH)12Cl · 3H2O |
| 7.DD.10 | Langite | Cu4(SO4)(OH)6 · 2H2O |
| 7.DD.10 | Fehrite | MgCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.10 | Posnjakite | Cu4(SO4)(OH)6 · H2O |
| 7.DD.10 | Wroewolfeite | Cu4(SO4)(OH)6 · 2H2O |
| 7.DD.10 | Gobelinite | CoCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.15 | Kobyashevite | Cu5(SO4)2(OH)6 · 4H2O |
| 7.DD.15 | Spangolite | Cu6Al(SO4)(OH)12Cl · 3H2O |
| 7.DD.15 | Unnamed (Dimorph of Devilline) | CaCu4(SO4)2(OH)6 · 3H2O |
| 7.DD.20 | Ktenasite | ZnCu4(SO4)2(OH)6 · 6H2O |
| 7.DD.25 | Christelite | Cu2Zn3(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Edwardsite | Cu3Cd2(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Niedermayrite | CdCu4(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Serpierite | Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O |
| 7.DD.30 | Campigliaite | Mn2+Cu4(SO4)2(OH)6 · 4H2O |
| 7.DD.30 | Orthoserpierite | Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O |
| 7.DD.30 | Devilline | CaCu4(SO4)2(OH)6 · 3H2O |
| 7.DD.35 | Shigaite | Mn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
| 7.DD.35 | Zincaluminite | (Zn1-xAlx)(SO4)x/2(OH)2 · nH2O |
| 7.DD.35 | Zincowoodwardite | Zn1-xAlx(OH)2[SO4]x/2 · nH2O |
| 7.DD.35 | Natroglaucocerinite | Zn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
| 7.DD.35 | Hydrowoodwardite | (Cu1-xAlx)(OH)2[SO4]x/2 · nH2O |
| 7.DD.35 | Honessite | (Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2O |
| 7.DD.35 | Glaucocerinite | (Zn1-xAlx)(OH)2(SO4)x/2 · nH2O |
| 7.DD.35 | Wermlandite | Mg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2O |
| 7.DD.35 | Nikischerite | Fe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
| 7.DD.35 | Hydrohonessite | (Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2O |
| 7.DD.35 | Woodwardite | Cu1-xAlx(OH)2(SO4)x/2 · nH2O |
| 7.DD.35 | Motukoreaite | Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O |
| 7.DD.35 | Mountkeithite | [(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2O |
| 7.DD.40 | Lawsonbauerite | (Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2O |
| 7.DD.40 | Torreyite | (Mg,Mn2+)7◻2Mn2+2Zn4(SO4)2(OH)22 · 8H2O |
| 7.DD.40 | Isselite | Cu6(SO4)(OH)10(H2O)4 · H2O |
| 7.DD.45 | Mooreite | Mg9◻2Mn2Zn4(SO4)2(OH)26 · 8H2O |
| 7.DD.45 | Hodgesmithite | (Cu,Zn)6Zn(SO4)2(OH)10 · 3H2O |
| 7.DD.47 | Lahnsteinite | Zn4(SO4)(OH)6 · 3H2O |
| 7.DD.50 | Namuwite | Zn4(SO4)(OH)6 · 4H2O |
| 7.DD.50 | Minohlite | (Cu,Zn)7(SO4)2(OH)10 · 8H2O |
| 7.DD.52 | Lauraniite | Cu6Cd2(SO4)2(OH)12 · 5H2O |
| 7.DD.55 | Bechererite | Zn7Cu(OH)13[(SiO(OH)3(SO4)] |
| 7.DD.60 | Ramsbeckite | (Cu,Zn)15(SO4)4(OH)22 · 6H2O |
| 7.DD.65 | Vonbezingite | Ca6Cu3(SO4)3(OH)12 · 2H2O |
| 7.DD.70 | Redgillite | Cu6(SO4)(OH)10 · H2O |
| 7.DD.75 | Nickelalumite | NiAl4(SO4)(OH)12(H2O)3 |
| 7.DD.75 | Kyrgyzstanite | ZnAl4(SO4)(OH)12 · 3H2O |
| 7.DD.75 | Chalcoalumite | CuAl4(SO4)(OH)12 · 3H2O |
| 7.DD.80 | Schulenbergite | (Cu,Zn)7(SO4)2(OH)10 · 3H2O |
| 7.DD.80 | UM1992-30-SO:CCuHZn | (Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2O |
| 7.DD.80 | Thérèsemagnanite | NaCo4(SO4)(OH)6Cl · 6H2O |
| 7.DD.80 | Guarinoite | Zn6(SO4)(OH)10 · 5H2O |
| 7.DD.85 | Montetrisaite | Cu6(SO4)(OH)10 · 2H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Carrboydite
mindat.org URL:
https://www.mindat.org/min-910.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
References for Carrboydite
Reference List:
Nickel, Ernest, H., Clarke, Richard M. (1976) Carrboydite, a hydrated sulfate of nickel and aluminum: a new mineral from Western Australia. American Mineralogist, 61 (5-6) 366-372
Nickel, Ernest H., Wildman, John E. (1981) Hydrohonessite—a new hydrated Ni-Fe hydroxy-sulphate mineral; its relationship to honessite, carrboydite, and minerals of the pyroaurite group. Mineralogical Magazine, 44 (335) 333-337 doi:10.1180/minmag.1981.044.335.14
Localities for Carrboydite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia | |
| Nickel et al. (1993) +2 other references |
| Pryce et al. (1974) +4 other references |
Portugal | |
| Antonio Jesus Pimentel specimens +1 other reference |
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The
Carr Boyd Rocks Ni mine, Menangina Station, Menzies Shire, Western Australia, Australia