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Amarillite

A valid IMA mineral species - grandfathered
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About AmarilliteHide

Formula:
NaFe(SO4)2 · 6H2O
Colour:
Pale yellow with greenish tint.
Lustre:
Adamantine, Vitreous
Hardness:
2½ - 3
Specific Gravity:
2.19 - 2.2
Crystal System:
Monoclinic
Name:
For the type locality, Tierra Amarilla, near Copiapó, Chile.
The structure is based on octahedral–tetrahedral "sheets" comprising corner-sharing NaO4(H2O)2 octahedra and sulfate tetrahedra; their combination leads to a structural sheet, parallel to (001): [Na(SO4)2(H2O)2]3-. Interstitial Fe3+ cations and hydrogen bonds provide linkage of the sheets; Fe occurs in FeO2(H2O)4 octahedra; these octahedra are connected to the adjacent sheets by eight hydrogen bonds, that provides further stabilization of the structure.


Unique IdentifiersHide

Mindat ID:
183
Long-form identifier:
mindat:1:1:183:8

IMA Classification of AmarilliteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
NaFe3+(SO4)2 · 6H2O
First published:
1933

Classification of AmarilliteHide

7.CC.75

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations
29.5.3.2

29 : HYDRATED ACID AND NORMAL SULFATES
5 : AB(XO4)2·xH2O
25.11.5

25 : Sulphates
11 : Sulphates of Fe and other metals

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
AmrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AmarilliteHide

Adamantine, Vitreous
Transparency:
Transparent
Comment:
Brilliant, adamantine inclining toward vitreous.
Colour:
Pale yellow with greenish tint.
Hardness:
2½ - 3 on Mohs scale
Cleavage:
Distinct/Good
{110} difficult to develop.
Fracture:
Conchoidal
Density:
2.19 - 2.2 g/cm3 (Measured)    2.22 g/cm3 (Calculated)

Optical Data of AmarilliteHide

Type:
Biaxial (+)
RI values:
nα = 1.532(2) nβ = 1.555(3) nγ = 1.591(2)
Max. Birefringence:
δ = 0.059
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate
Dispersion:
medium
Comments:
Large 2V

Chemistry of AmarilliteHide

Mindat Formula:
NaFe(SO4)2 · 6H2O
Element Weights:
Element% weight
O59.093 %
S16.919 %
Fe14.733 %
Na6.065 %
H3.191 %

Calculated from ideal end-member formula.

Crystallography of AmarilliteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Cell Parameters:
a = 8.419(61) Å, b = 10.8409(40) Å, c = 12.4717(50) Å
β = 95.495°
Ratio:
a:b:c = 0.777 : 1 : 1.15
Unit Cell V:
1,133.06 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Equant, complexly faceted crystals, thick tabular or rarely prismatic parallel [001], with common forms {001}, {100}, {110}, {101}, and {111}; as groupings of parallel individuals, to 2 mm.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0012226AmarilliteLi J J, Zhou J L, Dong W (1990) The structure of amarillite Chinese Science Bulletin 35 2073-20751990Qinghai Province, China0293
CIF Raw Data - click here to close

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]
Geological Setting:
Formed in the oxidation zones of sulfide deposits.

Type Occurrence of AmarilliteHide

General Appearance of Type Material:
Veinlets in massive coquimbite.
Place of Conservation of Type Material:
National School of Mines, Paris, France, 133.69.
Associated Minerals at Type Locality:

Other Language Names for AmarilliteHide

French:Amarillite
German:Amarillit
Norwegian:Amarillitt
Simplified Chinese:黄铁钠矾
Spanish:Amarillita

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Amarillite associated with Magnesioaubertite(Mg,Cu)Al(SO4)2Cl · 14H2O
1 photo of Amarillite associated with Halotrichite-Pickeringite Series

Related Minerals - Strunz-mindat GroupingHide

7.CC.CobaltoblöditeNa2Co(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.AndychristyitePbCu2+Te6+O5(H2O)Tric. 1 : P1
7.CC.Ammoniovoltaite(NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18Iso. m3m (4/m 3 2/m) : Fd3c
7.CC.05KrausiteKFe(SO4)2 · H2OMon. 2/m : P21/m
7.CC.10TamarugiteNaAl(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.15MendoziteNaAl(SO4)2 · 11H2OMon. 2/m : B2/b
7.CC.15KaliniteKAl(SO4)2 · 11H2OMon. 2/m : B2/b
7.CC.20Alum-(Na)NaAl(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.20Lonecreekite(NH4)Fe3+(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.20Alum-(K)KAl(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.20Tschermigite(NH4)Al(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.20LanmuchangiteTl+Al(SO4)2 · 12H2OIso. m3 (2/m 3) : Pa3
7.CC.25ZincovoltaiteK2Zn5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.25VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.25MagnesiovoltaiteK2Mg5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.25PertlikiteK2(Fe2+,Mg)2(Mg,Fe3+)4Fe3+2Al(SO4)12 · 18H2OTet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.CC.25Ammoniomagnesiovoltaite(NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m (4/m 3 2/m) : Fd3c
7.CC.30KröhnkiteNa2Cu(SO4)2 · 2H2OMon. 2/m : P21/b
7.CC.35FerrinatriteNa3Fe(SO4)3 · 3H2OTrig. 3 : P3
7.CC.40GoldichiteKFe(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.45LöweiteNa12Mg7(SO4)13 · 15H2OTrig. 3 : R3
7.CC.50NickelblöditeNa2Ni(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.50BlöditeNa2Mg(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.50ChangoiteNa2Zn(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.55LeoniteK2Mg(SO4)2 · 4H2OMon. 2/m : B2/m
7.CC.55MereiteriteK2Fe(SO4)2 · 4H2OMon. 2/m : B2/m
7.CC.60NickelpicromeriteK2Ni(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60Nickelboussingaultite(NH4)2Ni(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60Katerinopoulosite(NH4)2Zn(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60PicromeriteK2Mg(SO4)2 · 6H2OMon. 2/m : P2/b
7.CC.60CyanochroiteK2Cu(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60Mohrite(NH4)2Fe(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.60Boussingaultite(NH4)2Mg(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.65PolyhaliteK2Ca2Mg(SO4)4 · 2H2OTric. 1
7.CC.70LeightoniteK2Ca2Cu(SO4)4 · 2H2OMon. 2/m : B2/b
7.CC.80KonyaiteNa2Mg(SO4)2 · 5H2OMon. 2/m : P21/b
7.CC.85WattevilleiteNa2Ca(SO4)2 · 4H2O (?)Orth.
7.CC.85XocolatliteCa2Mn4+2(Te6+O6)2 · H2OMon. 2/m : P2/m
7.CC.90Eckhardite(Ca,Pb)Cu2+Te6+O5(H2O)Mon. 2/m

Other InformationHide

IR Spectrum:
Strong absorption bands in the 3000-3500 cm-1 range, with maxima at ca. 3110 and 3342 cm-1.
Notes:
Soluble in water, astringent taste.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for AmarilliteHide

References for AmarilliteHide

Localities for AmarilliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Brazil
 
  • Goiás
    • Cavalcante
Pires et al. (2020)
Canada
 
  • Nova Scotia
    • Cape Breton Co.
Zodrow (1989)
Chile
 
  • Antofagasta
    • Antofagasta Province
      • Mejillones
        • Mejillones peninsula
XRD by Joachim Lorenz
Pekov et al. (2019)
  • Atacama
    • Copiapó Province
C.R.Acad.Sci. (1933) +1 other reference
  • Tarapacá
    • Tamarugal Province
Peter G. Seroka collection
China
 
  • Qinghai
    • Haixi Mongol and Tibetan Autonomous Prefecture
      • Da Qaidam (Dachaidan Co.)
        • Xitieshan
American Mineralogist 90 +2 other references
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Plaka
          • Plaka Mines
Rieck et al. (2022)
Italy
 
  • Campania
    • Metropolitan City of Naples
      • Pozzuoli
Mormone et al. (2015, April) +1 other reference
  • Sicily
    • Metropolitan City of Messina
      • Eolie Islands (Aeolian Islands)
        • Lipari
          • Vulcano Island
            • Porto Levante
              • Faraglioni di Levante
Mikhail Murashko find and collection
Russia
 
  • Kamchatka Krai
    • Yelizovsky District
      • Mutnovsky volcano
Zhitova et al. (2022)
 
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