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Bokite

A valid IMA mineral species
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About BokiteHide

04292860017271921713155.jpg
Ivan I. Bok
Formula:
(Al,Fe)1.3(V5+,V4+,Fe3+)8O20 · 7.5H2O
Colour:
Black
Lustre:
Sub-Metallic, Dull
Hardness:
3
Specific Gravity:
2.97 - 3.1
Crystal System:
Monoclinic
Name:
Named in 1963 by E.A. Ankinovich in honor of Ivan Ivanovich Bok (Иван Иванович Бок) (10 October 1898, Belebey, Bashkortostan, Russian Empire - 30 September 1983, Leningrad, USSR), geologist, Institute of Geosciences, Alma-Ata, Kazakhstan and instructor, Sverdlovsk Mining Institute (then Kazakhstan Mining and Metallurgical Institute).
Compare the chemically similar bariandite.


Unique IdentifiersHide

Mindat ID:
709
Long-form identifier:
mindat:1:1:709:0

IMA Classification of BokiteHide

Classification of BokiteHide

4.HE.20

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
H : V[5,6] Vanadates
E : Phyllovanadates
47.3.2.5

47 : VANADIUM OXYSALTS
3 : Hydrated Normal Vanadium Oxysalts
21.4.25

21 : Vanadates (and vanadates with arsenate or phosphate)
4 : Vanadates of U, Mn, Fe or Ni

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
BktIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BokiteHide

Sub-Metallic, Dull
Transparency:
Opaque
Colour:
Black
Streak:
Black, may be brownish black
Hardness:
Cleavage:
Perfect
parallel to elongation; fair, perpendicular to first direction
Density:
2.97 - 3.1 g/cm3 (Measured)    3.41 g/cm3 (Calculated)

Optical Data of BokiteHide

Type:
Biaxial
RI values:
nα = 2.01 nγ = 2.06
Max. Birefringence:
δ = 0.050
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate
Anisotropism:
Strong, brownish yellow to grey-blue
Dispersion:
Relatively weak
Colour in reflected light:
Light grey
Pleochroism:
Strong
Comments:
Dirty olive-green to deep reddish brown

Chemistry of BokiteHide

Mindat Formula:
(Al,Fe)1.3(V5+,V4+,Fe3+)8O20 · 7.5H2O
Element Weights:
Element% weight
V52.144 %
O46.061 %
Al1.151 %
H0.645 %

Calculated from ideal end-member formula.

Crystallography of BokiteHide

Crystal System:
Monoclinic
Cell Parameters:
a = 11.838(5) Å, b = 3.643(1) Å, c = 11.142(5) Å
β = 110.58(4)°
Ratio:
a:b:c = 3.25 : 1 : 3.058
Unit Cell V:
449.84 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Platy to columnar or wedge-shaped grains, to 0.3 mm; reniform crusts with radiating structure; also in veinlets.
Comment:
Point Group: n.d.; Space Group: n.d.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.47 Å(100)
3.452 Å(30)
2.907 Å(12)
2.592 Å(12)
1.8208 Å(11)
3.177 Å(9)
2.760 Å(9)
Comments:
Recorded on material from the Kurumsak deposit, Kazakhstan

Geological EnvironmentHide

Paragenetic Mode(s):
Geological Setting:
As a constituent of U-V ores in triassic stream channels and impregnating sandstone

Type Occurrence of BokiteHide

General Appearance of Type Material:
Platy to columnar or wedge-shaped grains, to 0.3 mm long,
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA (No. 139767)
Geological Setting of Type Material:
In carbonaceous vanadiferous shales
Associated Minerals at Type Locality:

Other Language Names for BokiteHide

Dutch:Bokiet
German:Bokit
Spanish:Bokita

Relationship of Bokite to other SpeciesHide

Other Members of Straczekite Group:
BarianditeAl0.6(V5+,V4+)8O20 · 9H2OMon.
Corvusite(Na,K,Ca,Mg)2(V5+,V4+,Fe2+)8O20 · 6-10H2OMon. 2/m : B2/m
Fernandinite(Ca,K)(V5+,V4+,Fe2+)8O20 · 10H2OMon. 2/m : B2/m
Straczekite(Ca,K,Ba)(V5+,V4+)8O20 · 3H2OMon. 2/m : B2/m

Common AssociatesHide

Associated Minerals Based on Photo Data:
8 photos of Bokite associated with MetatyuyamuniteCa(UO2)2(VO4)2 · 3H2O
5 photos of Bokite associated with MikehowarditeFe3+4(V5+O4)4(H2O)2 · H2O
4 photos of Bokite associated with DonowensiteCa(H2O)3Fe3+2(V2O7)2
3 photos of Bokite associated with SericiteKAl2(AlSi3O10)(OH)2
2 photos of Bokite associated with BaryteBaSO4
2 photos of Bokite associated with RoscoeliteKV3+2(AlSi3O10)(OH)2
2 photos of Bokite associated with Corvusite(Na,K,Ca,Mg)2(V5+,V4+,Fe2+)8O20 · 6-10H2O
1 photo of Bokite associated with FervaniteFe3+4V5+4O16 · 5H2O
1 photo of Bokite associated with FluorapatiteCa5(PO4)3F
1 photo of Bokite associated with VashegyiteAl11(PO4)9(OH)6 · 38H2O

Related Minerals - Strunz-mindat GroupingHide

4.HE.05MelanovanaditeCa(V5+,V4+)4O10 · 5H2OTric. 1 : P1
4.HE.10ShcherbinaiteV5+2O5Orth. mmm (2/m 2/m 2/m) : Pmmn
4.HE.15HewettiteCaV6O16 · 9H2OMon. 2/m : P21/m
4.HE.15MetahewettiteCaV6O16 · 3H2OMon. 2/m
4.HE.20BarianditeAl0.6(V5+,V4+)8O20 · 9H2OMon.
4.HE.20Corvusite(Na,K,Ca,Mg)2(V5+,V4+,Fe2+)8O20 · 6-10H2OMon. 2/m : B2/m
4.HE.20Fernandinite(Ca,K)(V5+,V4+,Fe2+)8O20 · 10H2OMon. 2/m : B2/m
4.HE.20Straczekite(Ca,K,Ba)(V5+,V4+)8O20 · 3H2OMon. 2/m : B2/m
4.HE.25HäggiteV3+V4+O2(OH)3Mon. 2/m : B2/m
4.HE.30DoloresiteV4+3O4(OH)4Mon. 2/m : B2/m
4.HE.35DuttoniteV4+O(OH)2Mon. 2/m
4.HE.40CavoiteCaV4+3O7Orth. mmm (2/m 2/m 2/m) : Pnma

Other InformationHide

Thermal Behaviour:
Melts at 950 C.
Notes:
Slightly soluble in cold acids with the formation of a pale green solution, dissolves completely in 40% KOH or NaOH. Heated in the closed tube it gives off acid water.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BokiteHide

References for BokiteHide

Localities for BokiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Kazakhstan
 
  • Jambyl Region
    • Talas Alatau Range (Talas Ala-Too Range)
Pekov (1998)
  • Kyzylorda Region
    • Shieli District
Ankinovich (1963) +2 other references
  • Turkistan Region
    • Ran River valley
Pekov (1998)
    • Sozak District
      • Aksumbe
Ankinovich (1963) +2 other references
USA
 
  • Arizona
    • Apache County
      • Cane Valley Mining District
        • Yazzie Mesa
          • Monument No. 2 channel
Haynes (1991) +1 other reference
  • Arkansas
    • Garland County
      • Wilson Springs (Potash Sulfur Springs)
        • Union Carbide Mine
Howard +1 other reference
  • Nevada
    • Eureka County
      • Gibellini Mining District
Anthony (1997)
        • Fish Creek Range
Walstrom (n.d.) +3 other references
Castor et al. (2004)
Anthony (1997)
 
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