Kodamaite
A valid IMA mineral species
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About Kodamaite
Formula:
Na3(Ca5Na)Si16O36(OH)4F2 · (14-x)H2O
x ≈ 5
Colour:
tan to creamy-yellow to white in color, less often being colorless, light or dark green, or white.
Lustre:
Vitreous, Silky
Hardness:
2
Specific Gravity:
2.16 (Calculated)
Crystal System:
Triclinic
Member of:
Unique Identifiers
Mindat ID:
53862
Long-form identifier:
mindat:1:1:53862:4
IMA Classification of Kodamaite
Classification of Kodamaite
9.EE.35
9 : SILICATES (Germanates)
E : Phyllosilicates
E : Single tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bands
9 : SILICATES (Germanates)
E : Phyllosilicates
E : Single tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bands
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference |
|---|---|---|
| Kod | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Kodamaite
Vitreous, Silky
Transparency:
Transparent, Translucent
Colour:
Tan to creamy-yellow to white in color, less often being colorless, light or dark green, or white.
Streak:
White
Hardness:
2 on Mohs scale
Tenacity:
Sectile
Cleavage:
Perfect
{001}
{001}
Comment:
smooth fracture
Density:
2.16 g/cm3 (Calculated)
Optical Data of Kodamaite
Type:
Biaxial
Pleochroism:
Non-pleochroic
Comments:
An average nD = 1.507 (for λ = 590 nm) was calculated using data from the refined crystal structure.
Chemistry of Kodamaite
Mindat Formula:
Na3(Ca5Na)Si16O36(OH)4F2 · (14-x)H2O
x ≈ 5
x ≈ 5
Element Weights:
Crystallography of Kodamaite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 9.609(2) Å, b = 9.630(2) Å, c = 15.739(3) Å
α = 75.21(3)°, β = 75.21(3)°, γ = 60.12(3)°
α = 75.21(3)°, β = 75.21(3)°, γ = 60.12(3)°
Ratio:
a:b:c = 0.998 : 1 : 1.634
Unit Cell V:
1,206.63 ų (Calculated from Unit Cell)
Z:
1
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 15.148 Å | (100) |
| 4.191 Å | (5) |
| 3.833 Å | (7) |
| 3.139 Å | (5) |
| 3.068 Å | (7) |
| 2.996 Å | (18) |
| 2.780 Å | (14) |
| 1.831 Å | (9) |
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Kodamaite
General Appearance of Type Material:
Develops in spherulitic aggregates up to ∼2 mm across, comprising thin, platy to bladed crystals, with individual crystals averaging <0.05 × 0.5 mm.
Place of Conservation of Type Material:
Type material is deposited in the mineralogical collections of the Canadian Museum of Nature, P.O. Box 3443, Station D, Ottawa, Ontario K1P 6P4, Canada, catalogue number CMNMC 87262.
Associated Minerals at Type Locality:
Synonyms of Kodamaite
Other Language Names for Kodamaite
Relationship of Kodamaite to other Species
Member of:
Other Members of Reyerite Group:
| Minehillite | (K,Na)2-3Ca28Zn4Al4Si40O112(OH)16 | Hex. |
| Reyerite | (Na,K)2Ca14(Si,Al)24O58(OH)8 · 6H2O | Trig. 3 : P3 |
| Truscottite | (Ca,Mn)14Si24O58(OH)8 · 2H2O | Trig. |
Common Associates
Associated Minerals Based on Photo Data:
| 14 photos of Kodamaite associated with Varennesite | Na8Mn2Si10O25(OH,Cl)2 · 12H2O |
| 10 photos of Kodamaite associated with Sazhinite | |
| 7 photos of Kodamaite associated with Natrolite | Na2Al2Si3O10 · 2H2O |
| 2 photos of Kodamaite associated with Eudialyte Group | [N(1)N(2)N(3)N(4)N(5)]3[M(1.1)M(1.2)]3[M(2.1)M(2.2)M(2.3)]3-6[M(3)M(4)]Z3[Si24O72]Θ4X(1)X(2) |
| 1 photo of Kodamaite associated with Aegirine | NaFe3+Si2O6 |
| 1 photo of Kodamaite associated with Sphalerite | ZnS |
| 1 photo of Kodamaite associated with Zakharovite | Na4Mn5Si10O24(OH)6 · 6H2O |
Related Minerals - Strunz-mindat Grouping
| 9.EE. | Cairncrossite | Sr2Ca7-xNa2x(Si4O10)4(OH)2(H2O)15-x |
| 9.EE.05 | Bementite | Mn7Si6O15(OH)8 |
| 9.EE.07 | Innsbruckite | Mn33(Si2O5)14(OH)38 |
| 9.EE.10 | Brokenhillite | Mn8Si6O15(OH)10 |
| 9.EE.10 | Mcgillite | (Mn,Fe)8Si6O15(OH)8Cl2 |
| 9.EE.10 | Friedelite | Mn2+8Si6O15(OH,Cl)10 |
| 9.EE.10 | Pyrosmalite-(Mn) | Mn2+8Si6O15(OH,Cl)10 |
| 9.EE.10 | Pyrosmalite-(Fe) | Fe2+8Si6O15(OH,Cl)10 |
| 9.EE.15 | Nelenite | (Mn,Fe)16(Si12O30)(OH)14[As3+3O6(OH)3] |
| 9.EE.15 | Schallerite | Mn2+16As3Si12O36(OH)17 |
| 9.EE.20 | Palygorskite | ◻Al2Mg2◻2Si8O20(OH)2(H2O)4 · 4H2O |
| 9.EE.20 | Yofortierite | Mn2+Mn2+2Mn2+2◻2Si8O20(OH)2(H2O)4 · 4H2O |
| 9.EE.20 | Windhoekite | Fe3+(Fe3+1.67◻0.33)Ca2◻2Si8O20(OH)2(H2O)4(OH)2 · 6H2O |
| 9.EE.20 | Windmountainite | ◻Fe3+2Mg2◻2Si8O20(OH)2(H2O)4 · 4H2O |
| 9.EE.20 | Ikorskyite | KMn3+(Si4O10) · 3H2O |
| 9.EE.20 | Tuperssuatsiaite | Fe3+Fe3+2(Na◻)◻2Si8O20(OH)2(H2O)4 · 2H2O |
| 9.EE.20 | Unnamed (Na-Ca-Fe-Silicate-Hydrate) | NaCa(Fe2+,Al,Mn)5[Si8O19(OH)](OH)7 · 5H2O |
| 9.EE.25 | Sepiolite | Mg4(Si6O15)(OH)2 · 6H2O |
| 9.EE.25 | Loughlinite | Na2Mg3Si6O16 · 8H2O |
| 9.EE.25 | Falcondoite | (Ni,Mg)4Si6O15(OH)2 · 6H2O |
| 9.EE.25 | Kalifersite | (K,Na)5Fe3+7Si20O50(OH)6 · 12H2O |
| 9.EE.30 | Orlymanite | Ca4Mn3Si8O20(OH)6 · 2H2O |
| 9.EE.30 | Tungusite | Ca4Fe2Si6O15(OH)6 |
| 9.EE.30 | Gyrolite | NaCa16Si23AlO60(OH)8 · 14H2O |
| 9.EE.35 | Reyerite | (Na,K)2Ca14(Si,Al)24O58(OH)8 · 6H2O |
| 9.EE.35 | Truscottite | (Ca,Mn)14Si24O58(OH)8 · 2H2O |
| 9.EE.40 | Natrosilite | Na2Si2O5 |
| 9.EE.45 | Makatite | Na2Si4O8(OH)2 · 4H2O |
| 9.EE.50 | Varennesite | Na8Mn2Si10O25(OH,Cl)2 · 12H2O |
| 9.EE.55 | Raite | Mn2+Mn2+2Na2(◻1.75Ti0.25)Si8O20(OH)2(H2O)4 · Na(H2O)6 |
| 9.EE.60 | Intersilite | Na6Mn2+Ti[Si10O24(OH)](OH)3 · 4H2O |
| 9.EE.65 | Zakharovite | Na4Mn5Si10O24(OH)6 · 6H2O |
| 9.EE.65 | Shafranovskite | Na3K2(Mn,Fe,Na)4[Si9(O,OH)27](OH)2 · nH2O |
| 9.EE.70 | Zeophyllite | Ca13Si10O28(OH)2F8 · 6H2O |
| 9.EE.75 | Minehillite | (K,Na)2-3Ca28Zn4Al4Si40O112(OH)16 |
| 9.EE.80 | Fedorite | (Na,K)2-3(Ca4Na3)Si16O38(OH,F)2 · 3.5H2O |
| 9.EE.80 | Martinite | (Na,◻,Ca)12Ca4(Si,S,B)14B2O38(OH,Cl)2F2 · 4H2O |
| 9.EE.80 | Ellingsenite | Na5Ca6Si18O38(OH)13 · 6H2O |
| 9.EE.85 | Lalondeite | (Na,Ca)6(Ca,Na)3Si16O38(F,OH)2 · 3H2O |
Fluorescence of Kodamaite
pronounced bluish-white fluorescence under both long- and medium-wave ultraviolet radiation, much less so under short-wave radiation
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Kodamaite
mindat.org URL:
https://www.mindat.org/min-53862.html
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External Links:
References for Kodamaite
Reference List:
Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2019) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 51. European Journal of Mineralogy, 31 (5-6) 1099-1104 doi:10.1127/ejm/2019/0031-2894
McDonald, Andrew M.; Chao, George Y. (2024) Kodamaite, Na3(Ca5Na)6Si16O36(OH)4F2·14−xH2O, x = ∼5, A New Layered Alkali-Alkaline Earth Fluorosilicate-Hydrate and Member of the Gyrolite Supergroup, from Mont Saint-Hilaire, Quebec, Canada: Description, Crystal-Chemical Considerations, and Genetic Implications. The Canadian Journal of Mineralogy and Petrology, 62 (1). doi:10.3749/2300046
Localities for Kodamaite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Canada (TL) | |
| Miyawaki et al. (2019) |
| Modris Baum specimen +1 other reference |
Namibia | |
| Blaß et al. (2021) |
USA | |
| Robin D. Tibbit (deceased) |
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The
Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Lajemmerais RCM, Montérégie, Québec, Canada