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Polylithionite-Trilithionite Series

A solid-solution series between two end-member minerals
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About Polylithionite-Trilithionite SeriesHide

Series Formula:
KLi2Al(Si4O10)(F,OH)2 to K(Li1.5Al1.5)(AlSi3O10)(F,OH)2
A series between Polylithionite and Trilithionite


Unique IdentifiersHide

Mindat ID:
28887
Long-form identifier:
mindat:1:1:28887:1

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0002496PolylithioniteBrigatti M F, Lugli C, Poppi L, Foord E E, Kile D E (2000) Crystal chemical variations in Li- and Fe-rich micas from Pikes Peak batholith (central Colorado) American Mineralogist 85 1275-128620000293
0002497PolylithioniteBrigatti M F, Lugli C, Poppi L, Foord E E, Kile D E (2000) Crystal chemical variations in Li- and Fe-rich micas from Pikes Peak batholith (central Colorado) American Mineralogist 85 1275-128620000293
0002498PolylithioniteBrigatti M F, Lugli C, Poppi L, Foord E E, Kile D E (2000) Crystal chemical variations in Li- and Fe-rich micas from Pikes Peak batholith (central Colorado) American Mineralogist 85 1275-128620000293
0002499PolylithioniteBrigatti M F, Lugli C, Poppi L, Foord E E, Kile D E (2000) Crystal chemical variations in Li- and Fe-rich micas from Pikes Peak batholith (central Colorado) sample: 130(1) American Mineralogist 85 1275-128620000293
0002500PolylithioniteBrigatti M F, Lugli C, Poppi L, Foord E E, Kile D E (2000) Crystal chemical variations in Li- and Fe-rich micas from Pikes Peak batholith (central Colorado) sample: 130(2) American Mineralogist 85 1275-128620000293
0002501PolylithioniteBrigatti M F, Lugli C, Poppi L, Foord E E, Kile D E (2000) Crystal chemical variations in Li- and Fe-rich micas from Pikes Peak batholith (central Colorado) American Mineralogist 85 1275-128620000293
0002502PolylithioniteBrigatti M F, Lugli C, Poppi L, Foord E E, Kile D E (2000) Crystal chemical variations in Li- and Fe-rich micas from Pikes Peak batholith (central Colorado) American Mineralogist 85 1275-128620000293
0002503PolylithioniteBrigatti M F, Lugli C, Poppi L, Foord E E, Kile D E (2000) Crystal chemical variations in Li- and Fe-rich micas from Pikes Peak batholith (central Colorado) American Mineralogist 85 1275-128620000293
0002504PolylithioniteBrigatti M F, Lugli C, Poppi L, Foord E E, Kile D E (2000) Crystal chemical variations in Li- and Fe-rich micas from Pikes Peak batholith (central Colorado) American Mineralogist 85 1275-128620000293
0002505PolylithioniteBrigatti M F, Lugli C, Poppi L, Foord E E, Kile D E (2000) Crystal chemical variations in Li- and Fe-rich micas from Pikes Peak batholith (central Colorado) sample: 140(1) American Mineralogist 85 1275-128620000293
0004416PolylithioniteBrigatti M F, Mottana A, Malferrari D, Cibin G (2007) Crystal structure and chemical composition of Li-, Fe-, and Mn-rich micas American Mineralogist 92 1395-14002007Hirukawa mine, Ena county, Gifu prefecture, Chibu region, Japan0293
0004417PolylithioniteBrigatti M F, Mottana A, Malferrari D, Cibin G (2007) Crystal structure and chemical composition of Li-, Fe-, and Mn-rich micas American Mineralogist 92 1395-14002007Mokrusha mine, Yuzhakova village, Murzinka region, Russia0293
0007102PolylithioniteBrigatti M F, Caprilli E, Malferrari D, Medici L, Poppi L (2005) Crystal structure and chemistry of trilithionite-2M2 and polylithionite-2M2 European Journal of Mineralogy 17 475-4812005Varutrask, Vasterbotten, Sweden0293
0012230PolylithioniteSwanson T H, Bailey S W (1981) Redetermination of the lepidolite-2M_1 structure Clays and Clay Minerals 29 81-901981Bikupice, Czech Republic0293
0015663PolylithioniteSartori F (1977) The crystal structure of a 2M_1 lepidolite Tschermaks Mineralogische und Petrographische Mitteilungen 24 23-371977Biskupice, Moravia, Czech Republic0293
0007103TrilithioniteBrigatti M F, Caprilli E, Malferrari D, Medici L, Poppi L (2005) Crystal structure and chemistry of trilithionite-2M2 and polylithionite-2M2 European Journal of Mineralogy 17 475-4812005Chedeville, France0293
0007104TrilithioniteBrigatti M F, Caprilli E, Malferrari D, Medici L, Poppi L (2005) Crystal structure and chemistry of trilithionite-2M2 and polylithionite-2M2 European Journal of Mineralogy 17 475-4812005Chedeville, France0293
CIF Raw Data - click here to close

Relationship of Polylithionite-Trilithionite Series to other SpeciesHide

Other Members of Lepidolite:
FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m : B2/m
LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m : B2/b
PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m : B2/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Polylithionite-Trilithionite SeriesHide

References for Polylithionite-Trilithionite SeriesHide

Localities for Polylithionite-Trilithionite SeriesHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • Catamarca Province
    • Sierra de Ancasti
      • El Portezuelo
[Polylithionite] Colombo et al. (2011)
  • La Rioja Province
    • Sanagasta department
[Polylithionite] Lira et al. (2023)
  • Salta Province
    • La Poma Department
      • El Quemado mining district
[Polylithionite] López de Azarevich et al. (2021)
  • San Luis Province
    • Sierra de Comechingones
      • Comechingones Pegmatitic field
[Polylithionite] Demartis et al. (2011)
Australia
 
  • Victoria
    • East Gippsland Shire
      • Glen Valley
[Polylithionite] Eagle (2009)
  • Western Australia
    • Coolgardie Shire
      • Nepean
[Trilithionite] Peter Keller Collection
    • East Pilbara Shire
      • Pilgangoora
[Trilithionite] Aylmore et al. (2018)
    • Upper Gascoyne Shire
      • Yinnietharra
[Trilithionite] R. Bottrill
    • Yilgarn Shire
      • Marvel Loch
Luke Morgan Collection
Austria
 
  • Salzburg
    • Zell am See District
      • Bramberg am Wildkogel
        • Nasenkopf mountain
          • Leckbachgraben
[Trilithionite] Nikopoulou et al. (2025)
Brazil
 
  • Amazonas
    • Presidente Figueiredo
[Polylithionite] Ronchi et al. (2019) +1 other reference
[Polylithionite] Sighnolfi et al. (2008) +3 other references
[Trilithionite] Queiroz et al. (2018)
  • Mato Grosso
    • Peixoto de Azevedo
      • Peixoto de Azevedo river
[Polylithionite] Lopes et al. (2024)
  • Minas Gerais
    • Conselheiro Pena
[Trilithionite] Wilson (2012)
    • Nazareno
[Polylithionite] Lagache et al. (1997)
  • Tocantins
[Trilithionite] Coelho et al. (2025)
    • São Salvador do Tocantins
[Trilithionite] Queiroz et al. (2018)
Cambodia
 
  • Takeo Province
    • Kiri Vong District
[Polylithionite] Piilonen et al. (2023)
Canada
 
  • British Columbia
    • Revelstoke Mining Division
      • Boulder Mountain Pegmatite Group
[Trilithionite] Breasley et al. (2024)
      • Revelstoke
[Trilithionite] RRUFF Database Specimen No. RO60004 +1 other reference
  • Manitoba
    • Lac-du-Bonnet area
      • Bernic Lake
[Trilithionite] Van Lichterveld et al. (2008) +1 other reference
    • Red Cross Lake
[Polylithionite] Cerny et al. 2012 +1 other reference
  • Northwest Territories
[Polylithionite] Feng et al. (2015)
[Polylithionite] Feng et al. (2015)
    • North Slave Region
      • Blachford Lake alkaline complex
        • Thor Lake syenite complex
[Polylithionite] Feng et al. (2015)
    • O'Grady Lake area
      • O'Grady Batholith
[Polylithionite] Northern Mineral Showings Database
  • Québec
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
[Polylithionite] PERRAULT (1966) +3 other references
      • Lajemmerais RCM
        • Varennes & St-Amable
[Polylithionite] Horváth et al. (1998)
[Polylithionite] Horváth et al. (1998)
[Polylithionite] Miller (1990) +4 other references
China
 
  • Guangdong
    • Shaoguan
      • Qujiang District
[Polylithionite] Liu et al. (2018)
  • Henan
    • Sanmenxia
      • Lushi County
        • Guanpo
          • Guanpo pegmatite field
[Trilithionite] Fan G. et al. (2013)
[Polylithionite] Qu et al. (2023)
[Polylithionite] Qu et al. (2020) +1 other reference
  • Jiangxi
    • Yichun
      • Yifeng Co.
[Trilithionite] Ganfu Shen and Jinsha Xu (2006)
  • Sichuan
    • Dazhou
      • Wanyuan Co.
[Polylithionite] Yuzhuang Sun et al. (2010)
    • Garzê Autonomous Prefecture (Ganzi Autonomous Prefecture)
      • Yajiang County
[Trilithionite] Lei et al. (2025)
  • Xinjiang
    • Bayin'gholin Autonomous Prefecture
      • Ruoqiang Co. (Qakilik Co.; Chaqiliq Co.)
[Trilithionite] Qin et al. (2025)
    • Ili Kazakh Autonomous Prefecture
      • Altay Prefecture (Aletai Prefecture)
        • Fuyun Co. (Koktokay Co.)
          • Koktokay pegmatite field (Keketuohai pegmatite field)
            • Altay Mine
[Polylithionite] www.smartminerals.com (2004)
Czech Republic
 
  • South Bohemian Region
    • Český Krumlov District
      • Nová Ves
[Polylithionite] Welser +1 other reference
  • South Moravian Region
    • Znojmo District
      • Ctidružice
[Polylithionite] Scarlett Urbanová (2021)
  • Ústí nad Labem Region
    • Teplice District
      • Krupka
        • Knöttel area
[Trilithionite] Rieder et al. (1970)
        • Steinknochen area
[Polylithionite] Rob Lavinsky (ex. Josef Vajdak specimen)
  • Vysočina Region
    • Třebíč District
      • Biskupice-Pulkov
[Polylithionite] Rieder et al. (1970)
[Polylithionite] Scarlett Urbanová (2021)
      • Stařeč
[Polylithionite] Škoda et al. (2012) +1 other reference
    • Žďár nad Sázavou District
[Trilithionite] Novák et al. (1999)
[Polylithionite] Novotný et al. (2019)
[Polylithionite] Flégr et al. (2017)
[Polylithionite] Novák +4 other references
[Polylithionite] Flégr et al. (2017)
      • Rožná
[Polylithionite] Novák +2 other references
[Polylithionite] P. Pauliš (2001)
[Polylithionite] P. Pauliš (2001)
Egypt
 
  • Red Sea Governorate
[Polylithionite] Abd El-Naby (2009)
[Polylithionite] Mahdy et al. (2025)
    • Wadi Sikait
[Trilithionite] Elsagheer et al. (2025)
Eswatini
 
  • Lubombo Region
    • Sinceni Mountain
      • Sinceni pegmatite field
        • Sinceni West area
[Polylithionite] Grew et al. (2018)
Europe
 
  • Ore Mountains
[Polylithionite] Rieder et al. (1970)
Finland
 
  • Pirkanmaa
    • Orivesi
      • Eräjärvi area
[Trilithionite] Sandström et al. (2009)
France
 
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Limoges
        • Ambazac
[Trilithionite] Brigatti et al. (2005)
Germany
 
  • Saxony
    • Erzgebirgskreis
      • Geyer
[Polylithionite] René (2019)
    • Görlitz District
      • Vierkirchen
        • Döbschütz
          • Arnsdorf-Melaune Quarry
[Trilithionite] Witzke et al. (2001)
Greenland
 
  • Kujalleq
    • Igaliku
      • Narsaarsuk Plateau
[Polylithionite] Bøggild (1953) +1 other reference
      • Narsaarsuup Qaava
[Polylithionite] McDonald et al. (2001) +1 other reference
[Polylithionite] Petersen (2001)
[Polylithionite] Lorenzen (1881) +2 other references
        • Head of Kangerluarsuk
          • Lilleelv
[Polylithionite] B. Otter collection
[Polylithionite] Petersen (2001)
[Polylithionite] Julian Gray (2002)
[Polylithionite] Friis et al. (2004)
[Polylithionite] Metcalf-Johansen (1977)
[Polylithionite] Friis et al. (2004)
[Polylithionite] Pavel.M. Kartashov (n.d.)
[Polylithionite] Cole (2003)
      • Tunulliarfik Fjord
[Polylithionite] Bøggild (1953)
[Polylithionite] Otter (2016)
Ireland
 
  • Leinster
[Polylithionite] Barros et al. (2022)
Italy
 
  • Trentino-Alto Adige (Trentino-South Tyrol)
    • Trento Province
      • Canal San Bovo
        • Vanoi Valley
          • Pralongo
[Trilithionite] Venzo et al. (2017)
Japan
 
  • Ehime Prefecture
    • Ochi District
      • Iwagi Island
[Polylithionite] Imaoka et al. (2024)
  • Fukuoka Prefecture
    • Fukuoka City
[Polylithionite] ...
  • Ibaraki Prefecture
    • Hitachiota City
[Trilithionite] Kataoka & Uehara (2000)
Kazakhstan
 
  • Abai Region
    • Tarbagatai Range
      • Akzhaylyautas Mts (Akzhailyautas Mts; Akjaylautas Mts; Akzhalautas Mts)
[Polylithionite] Pavel.M. Kartashov (n.d.)
Kyrgyzstan
 
  • Batken Region
    • Batken District
[Polylithionite] Pautov et al. (2013)
Madagascar
 
  • Anosy
    • Taolagnaro District
[Trilithionite] Vandall King
Malawi
 
  • Southern Region
    • Zomba
[Polylithionite] Petersen et al. (1994)
Mongolia
 
  • Khovd Province
    • Myangad District
[Polylithionite] Econ Geol (1995) +2 other references
[Polylithionite] Kovalenko et al. (1995) +2 other references
[Polylithionite] Econ Geol (1995)
  • Ömnögovi Province
    • Khanbogd District
      • Khan Bogd Peralkaline Granite
[Polylithionite] Hawthorne et al. (1986)
Morocco
 
  • Drâa-Tafilalet Region
    • Midelt Province
      • Midelt Cercle
        • Aït Oufella Caïdat
          • Amersid
[Polylithionite] Khadem Allah (1993)
Mozambique
 
[Trilithionite] University of Arizona Mineral Museum ...
    • Alto Mólocuè District
[Polylithionite] Gomes et al. (2022)
    • Gilé District
      • Muiane-Naipa group
[Polylithionite] Thomas et al. (2010)
[Polylithionite] Neiva (2014)
Namibia
 
  • Khomas Region
    • Windhoek Rural
      • Aris
[Polylithionite] www.koeln.netsurf.de (1999) +5 other references
Norway
 
  • Telemark
    • Drangedal
      • Tørdal
[Polylithionite] Rosing-Schow et al. (2017)
    • Porsgrunn
      • Auenlandet
        • Sagåsen
[Polylithionite] Larsen et al. (2005)
      • Eidanger
        • Bergsbygda
[Polylithionite] Larsen et al. (2010)
      • Siktesøya
[Polylithionite] Larsen et al. (1991)
  • Vestfold
    • Larvik Commune
      • Hedrum
        • Lågendalen
[Polylithionite] Larsen et al. (2010)
[Polylithionite] Berge (n.d.)
[Polylithionite] Berge (n.d.)
        • Lysebo
[Polylithionite] Berge (n.d.)
[Polylithionite] Raade et al. (1980)
      • Lille Arøya
[Polylithionite] Larsen et al. (2010)
      • Stavern (Fredriksvärn)
        • Fuglevika
[Polylithionite] Larsen et al. (2010)
        • Jahren pegmatite
[Polylithionite] Åsheim (1994)
      • Tjølling
        • Håkestad
[Polylithionite] Larsen et al. (2010)
        • Klåstad
[Polylithionite] Knut Edvard Larsen collection # MM-324 (Visual id only)
      • Tvedalen
[Polylithionite] Larsen et al. (2010)
[Polylithionite] Larsen et al. (2010)
      • Vesle Arøya
[Polylithionite] Raade et al. (1980) +1 other reference
    • Sandefjord
      • Vesterøya
[Polylithionite] Larsen et al. (2010) +1 other reference
[Polylithionite] Larsen et al. (2013)
[Polylithionite] Raade et al. (1980)
Pakistan
 
  • Gilgit-Baltistan
    • Shigar District
      • Braldu Valley
[Polylithionite] Jose Zendrera Collection
[Polylithionite] imported from Shigar District +1 other reference
Portugal
 
  • Castelo Branco
    • Covilhã
      • Barco e Coutada
[Trilithionite] B. Charoy et al.
Russia
 
  • Buryatia
    • Mama River Basin
      • Maigunda River
[Polylithionite] Bailey (1980)
  • Murmansk Oblast
    • Khibiny Massif
[Polylithionite] [World of Stones 95:5-6
[Polylithionite] Pekov et al. (2004)
    • Lovozersky District
      • Alluaiv Mountain
        • Umbozero mine
[Polylithionite] Pekov (2000)
      • Karnasurt Mountain
[Polylithionite] Pekov (1998)
[Polylithionite]
      • Seidozero Lake
[Polylithionite] Pekov (2003)
[Polylithionite] Pavel.M. Kartashov (n.d.) +1 other reference
[Polylithionite] Semenov E.I. (1972)
    • Voron'i Tundry
[Polylithionite] Pekov et al. (2010) +1 other reference
[Polylithionite] [World of Stones 12:49]
    • Tomponsky District
[Polylithionite] Trunilina et al. (2024)
    • Ust-Yansky District
      • Omchikandya Ore Field
[Trilithionite] Trunilina et al. (2024)
    • Verkhoyansk District
      • Yana River Basin
        • Yana-Adycha Region
[Polylithionite] Trunilina et al. (2024)
  • Tuva
    • Kaa-Khemsky District
      • Erzin massif
[Polylithionite] Seltmann et al. (2010)
    • Sangilen Upland
[Polylithionite] Kapustin et al. (1965)
    • Todzhinsky District
[Polylithionite] Pavel.M. Kartashov (n.d.)
  • Zabaykalsky Krai
    • Aginsky District
      • Khangilai pluton
[Polylithionite] Thomas et al. (2009)
    • Kalarsky District
[Polylithionite] Sharygin et al. (2014)
Spain
 
  • Canary Islands
    • Santa Cruz de Tenerife Province
      • Tenerife
[Polylithionite] Dill et al. (2023)
        • Arico
[Polylithionite] Dill et al. (2023)
        • Granadilla de Abona
[Polylithionite] Dill et al. (2023)
  • Community of Madrid
    • La Cabrera
[Polylithionite] Tánago et al. (2012)
Sweden
 
  • Norrbotten County
    • Gällivare
      • Leipojärvi
[Trilithionite] Analysis by the Swedish Museum of ...
  • Västerbotten County
    • Skellefteå
[Polylithionite] Sandström (2008) +1 other reference
Tajikistan
 
  • Districts of Republican Subordination
[Polylithionite] Grew et al. (1994) +7 other references
Ukraine
 
  • Zhytomyr Oblast
    • Zhytomyr Raion
[Trilithionite] Lyckberg et al. (2009)
USA
 
  • Arizona
    • Graham County
      • Aravaipa Mining District
        • Aravaipa
          • Landsman Camp
[Polylithionite] Anthony et al. (1995)
[Polylithionite] Anthony et al. (1995)
  • Arkansas
    • Hot Spring County
      • Magnet Cove
[Polylithionite] Karl Estes (1998) +1 other reference
    • Pulaski County
      • Little Rock
        • Granite Mountain area
[Polylithionite] H. Barwood - unpublished (2010)
  • California
    • San Bernardino County
      • Yucca Valley
[Polylithionite-1M] David Lowe personally analyzed sample ...
  • Colorado
    • Douglas County
[Polylithionite] Brigatti et al. (2000)
    • El Paso County
[Polylithionite] Brigatti et al. (2000)
[Polylithionite] Brigatti et al. (2000)
[Polylithionite] Brigatti et al. (2000)
    • Fremont County
      • Cotopaxi Mining District
[Trilithionite] RRUFF Database Specimen No. RO50486
    • Gunnison County
      • Quartz Creek Pegmatite Mining District
[Trilithionite] University of Arizona Mineral Museum ...
[Polylithionite] Bob Cobban
[Polylithionite] Walstrom (n.d.)
[Polylithionite] Eckel et al. (1997)
    • Jefferson County
[Polylithionite] Brigatti et al. (2000)
    • Park County
[Polylithionite] Brigatti et al. (2000)
    • Teller County
      • Pikes Peak batholith
[Polylithionite] Brigatti et al. (2000)
  • Massachusetts
    • Essex County
[Trilithionite] Foster et al. (1962) +1 other reference
  • New Mexico
    • Colfax County
      • Springer
        • Point of Rocks Mesa
[Polylithionite] 4th Annual New Mexico Mineral Symposium (1985)
    • Otero County
      • Cornudas Mountains
[Polylithionite] Laszlo Horvath collection
  • Virginia
    • Augusta County
      • West Augusta
[Polylithionite] Robin D. Tibbit (deceased)
  • Washington
    • Okanogan County
      • Golden Horn Batholith
[Polylithionite] Micro Probe Volume VI Number 8 +1 other reference
Zimbabwe
 
  • Mashonaland Central
    • Mazowe District
[Polylithionite] Martin (2020)
 
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To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
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