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Murphyite

A valid IMA mineral species
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About MurphyiteHide

05841180017272473436467.jpg
Bruce J. Murphy (murphyite)
Formula:
Pb(Te6+O4)
Colour:
colorless to very pale yellow
Lustre:
Adamantine
Hardness:
Specific Gravity:
7.579 (Calculated)
Crystal System:
Monoclinic
Name:
Murphyite is named after Bruce J. Murphy (1952-2023), who provided the specimen for research on Te-bearing minerals. Bruce received his B.S. degree in geological engineering from the University of Arizona and retired after a distinguished career as an engineering geologist and consultant in the waste management industry. He has been a mineral collector for over 50 years, with a special interest in minerals from Arizona and specifically the Tombstone District and the Mammoth-Saint Anthony Mine. Bruce has provided numerous samples for scientific research worldwide.
The Te6+ analogue of raspite.


Unique IdentifiersHide

Mindat ID:
55963
Long-form identifier:
mindat:1:1:55963:6

IMA Classification of MurphyiteHide

Approved
Approval year:
2022

Classification of MurphyiteHide

7.AD.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
A : Sulfates (selenates, etc.) without additional anions, without H2O
D : With only large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
MpyIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MurphyiteHide

Adamantine
Transparency:
Transparent
Colour:
Colorless to very pale yellow
Streak:
White
Hardness:
3½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
{100}
Density:
7.579 g/cm3 (Calculated)

Chemistry of MurphyiteHide

Mindat Formula:
Pb(Te6+O4)
Element Weights:
Element% weight
Pb51.956 %
Te31.996 %
O16.048 %

Calculated from ideal end-member formula.

Crystallography of MurphyiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/a
Cell Parameters:
a = 13.6089(3) Å, b = 5.0175(1) Å, c = 5.5767(2) Å
β = 107.928(1)°
Ratio:
a:b:c = 2.712 : 1 : 1.111
Unit Cell V:
362.30 ų (Calculated from Unit Cell)
Z:
4
Twinning:
common on {100}, forming so-called fish-tail twins

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.655 Å(100)
3.604 Å(43)
3.513 Å(69)
3.235 Å(34)
2.768 Å(51)
2.718 Å(57)
2.515 Å(48)
1.857 Å(55)
Comments:
From Type Description.

Type Occurrence of MurphyiteHide

General Appearance of Type Material:
bladed or prismatic crystals
up to 0.20 x 0.05 x 0.05 mm in size
Place of Conservation of Type Material:
Type material is deposited in the collections of the University of Arizona Alfie Norville Gem and Mineral Museum, 15 N Church Ave, Tucson, AZ 85701, USA, catalogue no. 22715 (holotype), and the RRUFF Project, deposition no. R210011 (cotype)
Geological Setting of Type Material:
a Ag-Au-Pb-Cu-Zn deposit in which the ore, consisting principally of oxidized Ag- and Au-bearing galena, occurs in faulted and fractured portions of a large dike hosted by the Bisbee Group limestone
Associated Minerals at Type Locality:

Synonyms of MurphyiteHide

Other Language Names for MurphyiteHide

Dutch:Murphyiet
German:Murphyit

Common AssociatesHide

Associated Minerals Based on Photo Data:
2 photos of Murphyite associated with OttoitePb2TeO5

Related Minerals - Strunz-mindat GroupingHide

7.AD.BubnovaiteK2Na8Ca(SO4)6Trig. 3m : P3 1c
7.AD.DobrovolskyiteNa4Ca(SO4)3Trig. 3 : R3
7.AD.CalciolangbeiniteK2Ca2(SO4)3 Iso. 2 3 : P21 3
7.AD.CuprodobrovolskyiteNa4Cu(SO4)3Trig. 3 : R3
7.AD.KristjániteKNa2H(SO4)2Mon. 2/m
7.AD.05Mascagnite(NH4)2SO4Orth. mmm (2/m 2/m 2/m) : Pnma
7.AD.05ArcaniteK2SO4Orth. mmm (2/m 2/m 2/m)
7.AD.10MercalliteKHSO4Orth. mmm (2/m 2/m 2/m) : Pbca
7.AD.15MiseniteK8H6(SO4)7Mon.
7.AD.20Letovicite(NH4)3H(SO4)2Tric.
7.AD.25ThénarditeNa2SO4Orth. mmm (2/m 2/m 2/m) : Fddd
7.AD.25GlauberiteNa2Ca(SO4)2Mon. 2/m : B2/b
7.AD.30MetathénarditeNa2SO4Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
7.AD.30AnhydriteCaSO4Orth. mmm (2/m 2/m 2/m)
7.AD.35BaryteBaSO4Orth. mmm (2/m 2/m 2/m) : Pnma
7.AD.35CelestineSrSO4Orth. mmm (2/m 2/m 2/m) : Pnma
7.AD.35OlsacheritePb2(Se6+O4)(SO4)Orth.
7.AD.35AnglesitePbSO4Orth. mmm (2/m 2/m 2/m) : Pnma
7.AD.40KalistrontiteK2Sr(SO4)2Trig. 3m (3 2/m) : R3m
7.AD.40PalmieriteK2Pb(SO4)2Trig. 3m (3 2/m) : R3m
7.AD.45IvsiteNa3H(SO4)2Mon. 2/m : P21/b
7.AD.55MarkhininiteTlBi(SO4)2Tric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MurphyiteHide

References for MurphyiteHide

Localities for MurphyiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA (TL)
 
  • Arizona
    • Cochise County
      • Tombstone Mining District
        • Contention-Grand Central Mine group
Miyawaki et al. (2022) +1 other reference
 
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