Chukhrovite-(Ca)
A valid IMA mineral species
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About Chukhrovite-(Ca)
Formula:
Ca3Ca1.5Al2(SO4)F13 · 12H2O
Also given as Ca4.5Al2(SO4)F13 · 12H2O.
Colour:
Colorless, white
Lustre:
Vitreous
Hardness:
3½
Specific Gravity:
2.23 (Calculated)
Crystal System:
Isometric
Member of:
Name:
Named in 2011 by P. Vignola, F. Hatert, Olaf Medenbach, D. Bersani, V. Diella, P. Gentile, and A. Risplendente in honor of Fedor Vasil'evich Chukhrov and for its being the Ca analogue of chukrovite-(Ce).
Unique Identifiers
Mindat ID:
41907
Long-form identifier:
mindat:1:1:41907:3
IMA Classification of Chukhrovite-(Ca)
Approved
Approval year:
2011
First published:
2012
Type description reference:
Vignola, Pietro, Hatert, Frédéric, Bersani, Danilo, Diella, Valeria, Gentile, Paolo, Risplendente, Andrea (2012) Chukhrovite-(Ca), Ca4.5Al2(SO4)F13·12H2O, a new mineral species from the Val Cavallizza Pb-Zn-(Ag) mine, Cuasso al Monte, Varese province, Italy. European Journal of Mineralogy, 24 (6) 1069-1076 doi:10.1127/0935-1221/2012/0024-2247
Classification of Chukhrovite-(Ca)
3.CG.3.CG.
3 : HALIDES
C : Complex halides
G : Aluminofluorides with CO3, SO4, PO4
3 : HALIDES
C : Complex halides
G : Aluminofluorides with CO3, SO4, PO4
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference |
|---|---|---|
| Chk-Ca | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Chk | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Chukhrovite-(Ca)
Vitreous
Transparency:
Transparent, Translucent
Colour:
Colorless, white
Streak:
White
Hardness:
3½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Without a distinct cleavage.
Without a distinct cleavage.
Density:
2.23 g/cm3 (Calculated)
Optical Data of Chukhrovite-(Ca)
Type:
Isotropic
RI values:
n = 1.432(1)
Birefringence:
Isotropic minerals have no birefringence
Surface Relief:
Moderate
Chemistry of Chukhrovite-(Ca)
Mindat Formula:
Ca3Ca1.5Al2(SO4)F13 · 12H2O
Also given as Ca4.5Al2(SO4)F13 · 12H2O.
Also given as Ca4.5Al2(SO4)F13 · 12H2O.
Element Weights:
Crystallography of Chukhrovite-(Ca)
Crystal System:
Isometric
Class (H-M):
m3 (2/m 3) - Diploidal
Space Group:
Fd3
Cell Parameters:
a = 16.749(1) Å
Unit Cell V:
4698.6 ų
Z:
8
Morphology:
Sharp octahedra up to 150 µm in diameter.
Twinning:
Twinning along the [001] axis, with a rotation of 90 deg (iron cross law), is widespread, while spinel law twins are rare.
Comment:
Fd-3
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0019596 | Chukhrovite-(Ca) | Vignola P, Hatert F, Bersani D, Diella V, Gentile P, Risplendente A (2012) Chukhrovite-(Ca), Ca4.5Al2(SO4)F13*12H2O, a new mineral species from the Val Cavallizza Pb-Zn-(Ag) mine, Cuasso al Monte, Varese province, Italy European Journal of Mineralogy 24 1069-1076 | 2012 | Val Cavallizza mine, Cuasso al Monte, Varese province, Italy | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 9.665 Å | (100) |
| 5.921 Å | (31) |
| 5.053 Å | (16) |
| 4.190 Å | (10) |
| 3.226 Å | (15) |
| 2.556 Å | (10) |
| 2.182 Å | (12) |
| 1.915 Å | (17) |
Reference:
Vignola, Pietro, Hatert, Frédéric, Bersani, Danilo, Diella, Valeria, Gentile, Paolo, Risplendente, Andrea (2012) Chukhrovite-(Ca), Ca4.5Al2(SO4)F13·12H2O, a new mineral species from the Val Cavallizza Pb-Zn-(Ag) mine, Cuasso al Monte, Varese province, Italy. European Journal of Mineralogy, 24 (6) 1069-1076 doi:10.1127/0935-1221/2012/0024-2247
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 46 : Near-surface hydrothermal alteration of minerals (see also #22) | |
| 47a : [Near-surface hydration of prior minerals] | |
| 47b : [Sulfates and sulfites] | |
| 47g : [Halogen-bearing surface weathering minerals] | |
| Stage 10b: Anthropogenic minerals | <10 Ka |
| 56 : Slag and smelter minerals (see also #51 and #55) |
Type Occurrence of Chukhrovite-(Ca)
General Appearance of Type Material:
Colourless to whitish, transparent to translucent, sharp octahedral crystals up to 100–150 µm diameter.
Place of Conservation of Type Material:
Museum of Natural History of Milano, Italy, catalogue number M37901.
Laboratory of Mineralogy of the University of Liege, Belgium, catalogue number 20383.
Laboratory of Mineralogy of the University of Liege, Belgium, catalogue number 20383.
Geological Setting of Type Material:
Found as low temperature hydrothermal crystallizations covering the surfaces of brittle fractures crosscutting a marcasite and REE-bearing fluorite vein.
Associated Minerals at Type Locality:
Reference:
Vignola, Pietro, Hatert, Frédéric, Bersani, Danilo, Diella, Valeria, Gentile, Paolo, Risplendente, Andrea (2012) Chukhrovite-(Ca), Ca4.5Al2(SO4)F13·12H2O, a new mineral species from the Val Cavallizza Pb-Zn-(Ag) mine, Cuasso al Monte, Varese province, Italy. European Journal of Mineralogy, 24 (6) 1069-1076 doi:10.1127/0935-1221/2012/0024-2247
Synonyms of Chukhrovite-(Ca)
Chukhrovite (in part)
Other Language Names for Chukhrovite-(Ca)
Dutch:Chukhroviet-(Ca)
German:Chukhrovit-(Ca)
Relationship of Chukhrovite-(Ca) to other Species
Member of:
Other Members of Chukhrovite Group:
| Chukhrovite-(Ce) | Ca3CeAl2(SO4)F13 · 12H2O | Iso. |
| Chukhrovite-(Nd) | Ca3NdAl2(SO4)F13 · 12H2O | Iso. m3 (2/m 3) : Fd3 |
| Chukhrovite-(Y) | Ca3YAl2(SO4)F13 · 12H2O | Iso. m3 (2/m 3) : Fd3 |
| Meniaylovite | Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O | Iso. m3 (2/m 3) : Fd3 |
Common Associates
Associated Minerals Based on Photo Data:
| 2 photos of Chukhrovite-(Ca) associated with Plumbojarosite | Pb0.5Fe3+3(SO4)2(OH)6 |
| 2 photos of Chukhrovite-(Ca) associated with Limonite | |
| 1 photo of Chukhrovite-(Ca) associated with Leonardsenite | MgAlF5 · 2H2O |
| 1 photo of Chukhrovite-(Ca) associated with Anglesite | PbSO4 |
Related Minerals - Strunz-mindat Grouping
| 3.CG.05 | Stenonite | Sr2Al(CO3)F5 |
| 3.CG.10 | Meniaylovite | Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O |
| 3.CG.10 | Chukhrovite-(Ce) | Ca3CeAl2(SO4)F13 · 12H2O |
| 3.CG.10 | Chukhrovite-(Y) | Ca3YAl2(SO4)F13 · 12H2O |
| 3.CG.10 | Chukhrovite-(Nd) | Ca3NdAl2(SO4)F13 · 12H2O |
| 3.CG.15 | Creedite | Ca3Al2(SO4)(OH)2F8 · 2H2O |
| 3.CG.20 | Bøggildite | Na2Sr2Al2PO4F9 |
| 3.CG.25 | Thermessaite-(NH4) | (NH4)2AlF3(SO4) |
| 3.CG.25 | Thermessaite | K2AlF3(SO4) |
| 3.CG.30 | Kruijenite | Ca4Al4(SO4)F2(OH)16 · 2H2O |
Fluorescence of Chukhrovite-(Ca)
Non-fluorescent either under short-wave (254 nm) or long-wave (366 nm) ultraviolet light
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Chukhrovite-(Ca)
mindat.org URL:
https://www.mindat.org/min-41907.html
Please feel free to link to this page.
Please feel free to link to this page.
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External Links:
References for Chukhrovite-(Ca)
Reference List:
Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) Newsletter 8. Mineralogical Magazine, 75 (2) 289-294 doi:10.1180/minmag.2011.075.2.289
Vignola, Pietro, Hatert, Frédéric, Bersani, Danilo, Diella, Valeria, Gentile, Paolo, Risplendente, Andrea (2012) Chukhrovite-(Ca), Ca4.5Al2(SO4)F13·12H2O, a new mineral species from the Val Cavallizza Pb-Zn-(Ag) mine, Cuasso al Monte, Varese province, Italy. European Journal of Mineralogy, 24 (6) 1069-1076 doi:10.1127/0935-1221/2012/0024-2247
Localities for Chukhrovite-(Ca)
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Austria | |
| Kolitsch et al. (2013) |
Germany | |
| Möhn |
Greece | |
| Rieck et al. (2018) |
Italy (TL) | |
| Williams et al. (2011) +1 other reference |
| Mercurio et al. (2021) |
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Valvassera mine, Valganna, Varese Province, Lombardy, Italy