Manitobaite
A valid IMA mineral species
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About Manitobaite
Flag of Manitoba
Formula:
Na16Mn2+ 25Al8(PO4)30
Colour:
Dark green to brown
Lustre:
Sub-Vitreous, Resinous
Hardness:
5 - 5½
Specific Gravity:
3.621
Crystal System:
Monoclinic
Member of:
Name:
Named in 2010 by Scott T. Ercit, Kimberley T. Tait, Mark A. Cooper, Yassir Abdu, Neil A. Ball, Alan J. Anderson, Petr Černý, Frank C. Hawthorne for the province where the type locality is.
This page provides mineralogical data about Manitobaite.
Unique Identifiers
Mindat ID:
39331
Long-form identifier:
mindat:1:1:39331:3
IMA Classification of Manitobaite
Classification of Manitobaite
8.AC.18
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
38.2.10.
38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference |
|---|---|---|
| Mtb | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Manitobaite
Sub-Vitreous, Resinous
Transparency:
Translucent
Colour:
Dark green to brown
Streak:
Pale greenish brown
Hardness:
5 - 5½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
{010}
{010}
Fracture:
Irregular/Uneven, Hackly
Density:
3.621(6) g/cm3 (Measured) 3.628 g/cm3 (Calculated)
Optical Data of Manitobaite
Type:
Biaxial (-)
RI values:
nα = 1.682 nβ = 1.691 nγ = 1.697
2V:
Measured: 78° , Calculated: 78°
Birefringence:
0.015
Max. Birefringence:
δ = 0.015
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
Surface Relief:
Moderate
Dispersion:
r>v, medium
Optical Extinction:
X ∧ a = 31.7° (in β obtuse); Y = b; Z ∧ c = 20.2 (in β acute).
Pleochroism:
Strong
Comments:
X = orange brown; Y = green; Z = greenish brown.
Comments:
Absorption: Y ≥ Z > X.
Chemistry of Manitobaite
Mindat Formula:
Na16Mn2+ 25Al8(PO4)30
Element Weights:
Crystallography of Manitobaite
Crystal System:
Monoclinic
Class (H-M):
m - Domatic
Space Group:
Pb
Setting:
Pc
Cell Parameters:
a = 13.451(7) Å, b = 12.5266(7) Å, c = 26.6765(13) Å
β = 101.582(1)°
β = 101.582(1)°
Ratio:
a:b:c = 1.074 : 1 : 2.13
Unit Cell V:
4,403.34 ų (Calculated from Unit Cell)
Z:
2
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0018618 | Manitobaite | Tait K T, Ercit T S, Abdu Y A, Cerny P, Hawthorne F C (2011) The crystal structure and crystal chemistry of manitobaite, ideally (Na16_)Mn2+25Al8(PO4)30, from Cross Lake, Manitoba The Canadian Mineralogist 49 1221-1242 | 2011 | Cross Lake, Manitoba, Canada | 0 | 293 | |
| 0018619 | Manitobaite | Tait K T, Ercit T S, Abdu Y A, Cerny P, Hawthorne F C (2011) The crystal structure and crystal chemistry of manitobaite, ideally (Na16_)Mn2+25Al8(PO4)30, from Cross Lake, Manitoba The Canadian Mineralogist 49 1221-1242 | 2011 | Cross Lake, Manitoba, Canada | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 6.260 Å | (20) |
| 3.494 Å | (47) |
| 3.078 Å | (27) |
| 2.881 Å | (21) |
| 2.730 Å | (50) |
| 2.715 Å | (100) |
| 2.524 Å | (20) |
| 2.518 Å | (22) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites |
Type Occurrence of Manitobaite
General Appearance of Type Material:
Dark green to brown resinous masses.
Place of Conservation of Type Material:
Royal Ontario Museum, Toronto, Ontario, Canada, number M53321.
Geological Setting of Type Material:
Granite pegmatite.
Associated Minerals at Type Locality:
Synonyms of Manitobaite
Other Language Names for Manitobaite
Dutch:Manitobaiet
German:Manitobait
Relationship of Manitobaite to other Species
Member of:
Common Associates
Associated Minerals Based on Photo Data:
| 1 photo of Manitobaite associated with Bobfergusonite | Na2Mn5FeAl(PO4)6 |
| 1 photo of Manitobaite associated with Pieczkaite | Mn5(PO4)3Cl |
Related Minerals - Strunz-mindat Grouping
| 8.AC. | Crocobelonite-1M | CaFe3+2O(PO4)2 |
| 8.AC. | Magnesioqingheiite | Na2Mg(MgAl)(PO4)3 |
| 8.AC. | Manganobadalovite | NaNaMn(MgFe3+)(AsO4)3 |
| 8.AC. | Changesite-(Y) | (Ca8Y)◻Fe2+(PO4)7 |
| 8.AC. | Babunaite-(Nd) | NdAsO4 |
| 8.AC. | Crocobelonite | CaFe3+2O(PO4)2 |
| 8.AC. | Wopmayite | Ca6Na3◻Mn(PO4)3(PO3OH)4 |
| 8.AC. | Beershevaite | CaFe3+3(PO4)3O |
| 8.AC. | Epiebnerite | (NH4)Zn(PO4) |
| 8.AC. | Ebnerite | (NH4)Zn(PO4) |
| 8.AC.X | Dyrnaesite-(La) | Na8Ce4+(La,REE)2(PO4)6 |
| 8.AC. | Edtollite | K2NaCu5Fe3+O2(AsO4)4 |
| 8.AC. | Angarfite | NaFe3+5(PO4)4(OH)4 · 4H2O |
| 8.AC. | Kabalovite | Fe2+3Fe3+4(PO4)6 |
| 8.AC. | Nazarchukite | Ca2NiFe3+2(PO4)4 |
| 8.AC. | Calciohatertite | NaNaCa(CaFe3+)(AsO4)3 |
| 8.AC. | Alumoedtollite | K2NaCu5AlO2(AsO4)4 |
| 8.AC.02 | Grigorievite | Cu3Fe3+2Al2(VO4)6 |
| 8.AC.02 | Koksharovite | CaMg2Fe3+4(VO4)6 |
| 8.AC.02 | Ziminaite | Fe3+ 6 (VO4)6 |
| 8.AC.05 | Hatertite | Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 |
| 8.AC.05 | Erikapohlite | Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O |
| 8.AC.05 | Unnamed (Na-Mg Arsenate Hydroxyarsenate) | NaMg3(AsO4)(AsO3OH)2 |
| 8.AC.05 | Unnamed (Na-Zn-H Arsenate Hydroxyarsenate) | Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 |
| 8.AC.05 | Calciojohillerite | NaCaMg3(AsO4)3 |
| 8.AC.05 | Magnesiohatertite | (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 |
| 8.AC.05 va | Alluaudite-Na[] | ◻4Na4Mn2+4Fe3+8(PO4)12 |
| 8.AC.05 va | Alluaudite-Ca[] | ◻4Ca4Mn2+4Fe3+8(PO4)12 |
| 8.AC.05 va | Ferroalluaudite-NaNa | Na4Na4Fe2+4Fe3+8(PO4)12 |
| 8.AC.05 | Hagendorfite-NaNa | NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) |
| 8.AC.05 | O'Danielite | Na(Zn,Mg)3(AsO4)(AsO3OH)2 |
| 8.AC.05 | Howardevansite | NaCuFe2(VO4)3 |
| 8.AC.05 | Khrenovite | Na3Fe3+2(AsO4)3 |
| 8.AC.05 | Zincobradaczekite | NaZn2Cu2(AsO4)3 |
| 8.AC.05 | Paraberzeliite | NaCa2Mg2(AsO4)3 |
| 8.AC.05 | Badalovite | Na2Mg2Fe(AsO4)3 |
| 8.AC.05 | Magnesiocanutite | NaMnMg2[AsO4]2[AsO2(OH)2] |
| 8.AC.05 | Manganohatertite | NaNaCa(MnFe3+)(AsO4)3 |
| 8.AC.05 | Camanchacaite | NaCaMg2[AsO4][AsO3(OH)]2 |
| 8.AC.07 | Zhanghuifenite | Na3Mn4Mg2Al(PO4)6 |
| 8.AC.07 | Ferrobobfergusonite | Na2Fe2+5Fe3+Al(PO4)6 |
| 8.AC.10 | Hagendorfite | NaCaMn2+Fe2+2(PO4)3 |
| 8.AC.10 | Ferrohagendorfite | NaCaFe2+Fe2+2(PO4)3 |
| 8.AC.10 | Johillerite | Na(Mg,Zn)3Cu(AsO4)3 |
| 8.AC.10 | Varulite | NaCaMn2+Mn2+2(PO4)3 |
| 8.AC.10 | Nickenichite | Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 |
| 8.AC.10 | Arseniopleite | NaCaMnMn2(AsO4)3 |
| 8.AC.10 | Groatite | NaCaMn2(PO4)[PO3(OH)]2 |
| 8.AC.10 | Alluaudite | (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 |
| 8.AC.10 | Bradaczekite | NaCu4(AsO4)3 |
| 8.AC.10 | Caryinite | (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 |
| 8.AC.10 | Ferroalluaudite | (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 |
| 8.AC.10 | Maghagendorfite | (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 |
| 8.AC.15 | Ferrowyllieite | (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 |
| 8.AC.15 | Qingheiite | NaNaMn2+(MgAl)(PO4)3 |
| 8.AC.15 | Rosemaryite | (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 |
| 8.AC.15 | Ferroqingheiite | NaNaFe2+(MgAl)(PO4)3 |
| 8.AC.15 | Ferrorosemaryite | ◻NaFe2+Fe3+Al(PO4)3 |
| 8.AC.15 | Bobfergusonite | Na2Mn5FeAl(PO4)6 |
| 8.AC.15 | Wyllieite | (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 |
| 8.AC.17 | Czochralskiite | Na4Ca3Mg(PO4)4 |
| 8.AC.20 | Marićite | NaFe2+(PO4) |
| 8.AC.25 | Schäferite | (NaCa2)Mg2(VO4)3 |
| 8.AC.25 | Berzeliite | (NaCa2)Mg2(AsO4)3 |
| 8.AC.25 | Matyhite | Ca18(Ca,◻)2Fe2+2(PO4)14 |
| 8.AC.25 | Hedegaardite | (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) |
| 8.AC.25 | Manganberzeliite | (NaCa2)Mn2+2(AsO4)3 |
| 8.AC.25 | Palenzonaite | (NaCa2)Mn2+2(VO4)3 |
| 8.AC.30 | Brianite | Na2CaMg(PO4)2 |
| 8.AC.35 | Vitusite-(Ce) | Na3(Ce,La,Nd)(PO4)2 |
| 8.AC.40 | Bario-olgite | (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · |
| 8.AC.40 | Olgite | (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 |
| 8.AC.45 | Tuite | Ca3(PO4)2 |
| 8.AC.45 | Ferromerrillite | Ca9NaFe2+(PO4)7 |
| 8.AC.45 | Strontiowhitlockite | Sr9Mg(PO4)6(PO3OH) |
| 8.AC.45 | Merrillite | Ca9NaMg(PO4)7 |
| 8.AC.45 | Whitlockite | Ca9Mg(PO4)6(PO3OH) |
| 8.AC.47 | Iwateite | Na2BaMn(PO4)2 |
| 8.AC.47 | Ozerovaite | Na2KAl3(AsO4)4 |
| 8.AC.47 | Yurmarinite | Na7(Fe3+,Mg,Cu)4(AsO4)6 |
| 8.AC.47 | Pansnerite | K3Na3(Fe3+,Al)6(AsO4)8 |
| 8.AC.47 | Anatolyite | Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 |
| 8.AC.50 | Fillowite | Na3CaMn2+11(PO4)9 |
| 8.AC.50 | Galileiite | Na3Fe2+Fe2+11(PO4)9 |
| 8.AC.50 | Johnsomervilleite | Na3CaFe11(PO4)9 |
| 8.AC.50 | Xenophyllite | Na4Fe2+7(PO4)6 |
| 8.AC.50 | Udinaite | NaMg4(VO4)3 |
| 8.AC.50 | Arsenudinaite | NaMg4(AsO4)3 |
| 8.AC.50 | Chladniite | Na3CaMg11(PO4)9 |
| 8.AC.52 | Lasnierite | (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 |
| 8.AC.55 | Pharmazincite | KZnAsO4 |
| 8.AC.57 | Zubkovaite | Ca3Cu3(AsO4)4 |
| 8.AC.60 | Kosnarite | KZr2(PO4)3 |
| 8.AC.65 | Panethite | (Na,Ca)2(Mg,Fe2+)2(PO4)2 |
| 8.AC.70 | Stanfieldite | Ca4Mg5(PO4)6 |
| 8.AC.75 | Ronneburgite | K2MnV4O12 |
| 8.AC.80 | Tillmannsite | Ag3Hg[(V,As)O4] |
| 8.AC.85 | Filatovite | K(Al,Zn)2(As,Si)2O8 |
Fluorescence of Manitobaite
Not fluorescent in UV
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Manitobaite
mindat.org URL:
https://www.mindat.org/min-39331.html
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References for Manitobaite
Reference List:
Ercit, T. Scott, Tait, Kim T., Cooper, Mark A., Abdu, Yassir, Ball, N. A., Anderson, A. J., Černý, Petr, Hawthorne, Frank C., Galliski, Miguel (2010) Manitobaite, Na16Mn2+25Al8(PO4)30, a new phosphate mineral species from Cross Lake, Manitoba, Canada. The Canadian Mineralogist, 48 (6) 1455-1463 doi:10.3749/canmin.48.5.1455
Tait, Kim T., Ercit, T. Scott, Abdu, Yassir A., Černý, Petr, Hawthorne, Frank C. (2011) The crystal structure and crystal chemistry of manitobaite, ideally (Na16◻)Mn2+25Al8(PO4)30, from Cross Lake, Manitoba. The Canadian Mineralogist, 49 (5) 1221-1242 doi:10.3749/canmin.49.5.1221
Localities for Manitobaite
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Canada (TL) | |
| Ercit et al. (2010) |
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Pegmatite No. 22, North Group, Cross Lake, Manitoba, Canada