Jahnsite-(CaMnMg)
A valid IMA mineral species
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About Jahnsite-(CaMnMg)
Formula:
{Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O
Colour:
Brown, golden brown, Purplish brown, Yellow, Yellow orange, Greenish yellow
Lustre:
Sub-Adamantine, Sub-Vitreous, Resinous
Hardness:
4
Specific Gravity:
2.706 - 2.718
Crystal System:
Monoclinic
Member of:
Name:
Named in 1974 by Paul (Paulus) Brian Moore and Takaharu Araki in honor of Richard Henry Jahns (March 10, 1915 Los Angeles, California, USA - December 31, 1983 Palo Alto, California, USA), mineralogist and pegmatite expert, Stanford University, Palo Alto, California, USA. The suffix indicates metal site occupancies.
Unique Identifiers
Mindat ID:
2067
Long-form identifier:
mindat:1:1:2067:7
IMA Classification of Jahnsite-(CaMnMg)
Approved
IMA status notes:
Redefined by the IMA
IMA Formula:
CaMn2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O
Approval history:
Approved by IMA as a new species, as Jahnsite (IMA 1973-022).
Redefined as Jahnsite-(CaMnMg) (Moore & Ito 1978).
Redefined as Jahnsite-(CaMnMg) (Moore & Ito 1978).
Type description reference:
Classification of Jahnsite-(CaMnMg)
8.DH.15
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
Dana 7th ed.:
42.11.2.1
42.11.2.1
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
19.12.43
19 : Phosphates
12 : Phosphates of Mn
19 : Phosphates
12 : Phosphates of Mn
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference |
|---|---|---|
| Jah-CaMnMg | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Jhn | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Jahnsite-(CaMnMg)
Sub-Adamantine, Sub-Vitreous, Resinous
Transparency:
Transparent, Translucent
Colour:
Brown, golden brown, Purplish brown, Yellow, Yellow orange, Greenish yellow
Streak:
White
Hardness:
4 on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
Good on the {001}
Good on the {001}
Density:
2.706 - 2.718 g/cm3 (Measured) 2.715 g/cm3 (Calculated)
Optical Data of Jahnsite-(CaMnMg)
Type:
Biaxial (+)
RI values:
nα = 1.640 nβ = 1.658 nγ = 1.670
Birefringence:
0.030
Max. Birefringence:
δ = 0.030
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.
Surface Relief:
Moderate
Dispersion:
relatively weak
Optical Extinction:
Y^c = 18°, Z=b
Pleochroism:
Strong
Comments:
X = pale purple, Y=deep purplish brown, Z = yellow to greenish yellow
Chemistry of Jahnsite-(CaMnMg)
Mindat Formula:
{Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O
Element Weights:
Crystallography of Jahnsite-(CaMnMg)
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P2/b
Setting:
P2/a
Cell Parameters:
a = 14.94 Å, b = 7.14 Å, c = 9.93 Å
β = 110.16°
β = 110.16°
Ratio:
a:b:c = 2.092 : 1 : 1.391
Unit Cell V:
991 ų
Z:
2
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0000414 | Jahnsite-(CaMnMg) | Moore P B, Araki T (1974) Jahnsite, CaMnMg2(H2O)8Fe2(OH)2[PO4]4: A novel stereoisomerism of ligands about octahedral corner-chains American Mineralogist 59 964-973 | ![]() | 1974 | Tip Top mine, Custer Country, South Dakota, USA | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 9.27 Å | (100) |
| 5.66 Å | (40) |
| 4.91 Å | (60) |
| 4.63 Å | (40) |
| 3.522 Å | (50) |
| 2.950 Å | (50) |
| 2.825 Å | (80) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Near-surface Processes | |
| 22 : Hydration and low-? subsurface aqueous alteration (see also #23) | |
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites |
Type Occurrence of Jahnsite-(CaMnMg)
Geological Setting of Type Material:
Late stage phosphate mineralization in a granite pegmatite.
Associated Minerals at Type Locality:
Synonyms of Jahnsite-(CaMnMg)
Other Language Names for Jahnsite-(CaMnMg)
Relationship of Jahnsite-(CaMnMg) to other Species
Member of:
Other Members of Jahnsite Subgroup:
| Jahnsite-(CaFeFe) | {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. |
| Jahnsite-(CaFeMg) | {Ca}{Fe2+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P2/b |
| Jahnsite-(CaMgMg) | {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O | |
| Jahnsite-(CaMnFe) | {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P2/b |
| Jahnsite-(CaMnMn) | {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P2/b |
| Jahnsite-(CaMnZn) | {Ca}{Mn2+}{Zn2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P2/b |
| Jahnsite-(MnMnFe) | {Mn2+}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P2/b |
| Jahnsite-(MnMnMg) | {Mn2+}{Mn2+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P2/b |
| Jahnsite-(MnMnMn) | {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P21/b |
| Jahnsite-(MnMnZn) | {Mn2+}{Mn2+}{Zn2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P2/b |
| Jahnsite-(NaFeMg) | {Na}{Fe3+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P2/b |
| Jahnsite-(NaMnMg) | {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P2/b |
| Jahnsite-(NaMnMn) | {Na}{Mn2+}{(Mn2+,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O | Mon. 2/m : P2/b |
| Keckite | CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O | Mon. 2/m : P2/b |
Common Associates
Associated Minerals Based on Photo Data:
| 7 photos of Jahnsite-(CaMnMg) associated with Jahnsite-(NaFeMg) | {Na}{Fe3+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 5 photos of Jahnsite-(CaMnMg) associated with Whitlockite | Ca9Mg(PO4)6(PO3OH) |
| 5 photos of Jahnsite-(CaMnMg) associated with Kosnarite | KZr2(PO4)3 |
| 5 photos of Jahnsite-(CaMnMg) associated with Eosphorite | Mn2+Al(PO4)(OH)2 · H2O |
| 5 photos of Jahnsite-(CaMnMg) associated with Albite | Na(AlSi3O8) |
| 5 photos of Jahnsite-(CaMnMg) associated with Muscovite | KAl2(AlSi3O10)(OH)2 |
| 5 photos of Jahnsite-(CaMnMg) associated with Leucophosphite | KFe3+2(PO4)2(OH) · 2H2O |
| 4 photos of Jahnsite-(CaMnMg) associated with Mitridatite | Ca2Fe3+3(PO4)3O2 · 3H2O |
| 2 photos of Jahnsite-(CaMnMg) associated with Hureaulite | Mn2+5(PO3OH)2(PO4)2 · 4H2O |
| 2 photos of Jahnsite-(CaMnMg) associated with Jahnsite-(CaMgMg) | {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
Related Minerals - Strunz-mindat Grouping
| 8.DH. | Thebaite-(NH4) | (NH4)3Al(C2O4)(PO3OH)2(H2O) |
| 8.DH. | Whiteite-(MnMnMn) | Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O |
| 8.DH. | Ferroberaunite | Fe2+Fe3+5(PO4)4(OH)5 · 6H2O |
| 8.DH. | Regerite | KFe6(PO4)4(OH)7(H2O)6 · 4H2O |
| 8.DH. | Ammoniotinsleyite | (NH4)Al2(PO4)2(OH) · 2H2O |
| 8.DH. | Dendoraite-(NH4) | (NH4)2NaAl(C2O4)(PO3OH)2(H2O)2 |
| 8.DH. | Rowleyite | [Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl] |
| 8.DH. | Hochleitnerite | Mn2Ti3(PO4)4O2(H2O)2 · 14H2O |
| 8.DH. | Whiteite-(CaMnFe) | CaMnFe2Al2(PO4)4(OH)2 · 8H2O |
| 8.DH.05 | Minyulite | KAl2(PO4)2F · 4H2O |
| 8.DH.10 | Leucophosphite | KFe3+2(PO4)2(OH) · 2H2O |
| 8.DH.10 | Tinsleyite | KAl2(PO4)2(OH) · 2H2O |
| 8.DH.10 | Spheniscidite | (NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2O |
| 8.DH.15 | Jahnsite-(CaMnFe) | {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(NaMnMn) | {Na}{Mn2+}{(Mn2+,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(CaMnMn) | {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(MnMnMg) | MnMnMg2Al2(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(CaMnZn) | {Ca}{Mn2+}{Zn2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnMg) | {Mn2+}{Mn2+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnFe) | {Mn2+}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(CaFeFe) | {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Rittmannite | {(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Keckite | CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O |
| 8.DH.15 | Jahnsite-(NaMnMg) | {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(CaMgMg) | {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnZn) | {Mn2+}{Mn2+}{Zn2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaMgMg) | CaMg3Al2(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaFeMg) | {Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaMnMg) | {Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(MnFeMg) | {(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(MnMnMn) | {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Kaluginite | (Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2O |
| 8.DH.15 | Jahnsite-(CaFeMg) | {Ca}{Fe2+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Whiteite-(CaMnMn) | {Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2O |
| 8.DH.15 | Jahnsite-(NaFeMg) | {Na}{Fe3+}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
| 8.DH.20 | Segelerite | Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O |
| 8.DH.20 | Lun'okite | (Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2O |
| 8.DH.20 | Manganosegelerite | (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O |
| 8.DH.20 | Wilhelmvierlingite | CaMnFe3+(PO4)2(OH) · 2H2O |
| 8.DH.20 | Juonniite | CaMgSc(PO4)2(OH) · 4H2O |
| 8.DH.20 | Overite | CaMgAl(PO4)2(OH) · 4H2O |
| 8.DH.25 | Calcioferrite | Ca2Fe3+2(PO4)3(OH) · 7H2O |
| 8.DH.25 | Zodacite | Ca4Mn2+Fe3+4(PO4)6(OH)4 · 12H2O |
| 8.DH.25 | Fanfaniite | Ca4MnAl4(PO4)6(OH)4 · 12H2O |
| 8.DH.25 | Kingsmountite | Ca3MnFeAl4(PO4)6(OH)4 · 12H2O |
| 8.DH.25 | Montgomeryite | Ca4MgAl4(PO4)6(OH)4 · 12H2O |
| 8.DH.30 | Pararobertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
| 8.DH.30 | Robertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
| 8.DH.30 | Arseniosiderite | Ca2Fe3+3(AsO4)3O2 · 3H2O |
| 8.DH.30 | Sailaufite | (Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2O |
| 8.DH.30 | Mitridatite | Ca2Fe3+3(PO4)3O2 · 3H2O |
| 8.DH.30 | Kolfanite | Ca2Fe3+3O2(AsO4)3 · 2H2O |
| 8.DH.35 | Mantienneite | KMg2Al2Ti(PO4)4(OH)3 · 15H2O |
| 8.DH.35 | Sperlingite | (H2O)K(Mn2+Fe3+)(Al2Ti)(PO4)4[O(OH)] [(H2O)9(OH)] · 4H2O |
| 8.DH.35 | Paulkerrite | K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2O |
| 8.DH.35 | Hydroxylbenyacarite | (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O |
| 8.DH.35 | Macraeite | K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2O |
| 8.DH.35 | Benyacarite | (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O |
| 8.DH.35 | Fluormacraeite | [(H2O)K]Mn2(Fe2Ti)(PO4)4(OF)(H2O)10 · 4H2O |
| 8.DH.40 | Xanthoxenite | Ca4Fe3+2(PO4)4(OH)2 · 3H2O |
| 8.DH.45 | Mahnertite | NaCu3(AsO4)2Cl · 5H2O |
| 8.DH.50 | Andyrobertsite | KCdCu5(AsO4)4(H2AsO4) · 2H2O |
| 8.DH.50 | Calcioandyrobertsite | KCaCu5(AsO4)4(H2AsO4) · 2H2O |
| 8.DH.55 | Englishite | K3Na2Ca10Al15(PO4)21(OH)7 · 26H2O |
| 8.DH.60 | Bouazzerite | Bi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2O |
| 8.DH.65 | Galliskiite | Ca4Al2(PO4)2F8 · 5H2O |
| 8.DH.70 | Joteite | Ca2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2O |
| 8.DH.75 | Kampelite | Ba6Mg3Sc8(PO4)12(OH)6 · 7H2O |
| 8.DH.80 | Kapundaite | NaCaFe4(PO4)4(OH)3 · 5H2O |
| 8.DH.85 | Vaniniite | Ca2Mn2+3Mn3+2O2(AsO4)4 · 2H2O |
Fluorescence of Jahnsite-(CaMnMg)
Not Fluorescent in UV
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Jahnsite-(CaMnMg)
mindat.org URL:
https://www.mindat.org/min-2067.html
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References for Jahnsite-(CaMnMg)
Reference List:
Moore, Paul Brian, Ito, J. (1974) I. Jahnsite, segelerite, and robertsite, three new transition metal phosphate species. II. Redefinition of overite, an isotype of segelerite. III. Isotypy of robertsite, mitridatite, and arseniosiderite. American Mineralogist, 59 (1-2) 48-59
Moore, Paul Brian, Araki, and Takaharu (1974) Jahnsite, CaMn2+Mg2(H2O)8Fe3+2(OH)2[PO4]4: A novel stereoisomerism of ligands about octahedral corner-chains. American Mineralogist, 59 (9-10) 964-973
Moore, Paul Brian, Ito, J. (1974) I. Jahnsite, segelerite, and robertsite, three new transition metal phosphate species. II. Redefinition of overite, an isotype of segelerite. III. Isotypy of robertsite, mitridatite, and arseniosiderite. American Mineralogist, 59 (1-2) 48-59
Localities for Jahnsite-(CaMnMg)
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina | |
| Colombo et al. (2012) |
| Colombo et al. (2012) |
| Roda-Robles et al. (2012) |
| Raúl J. Tauber Larry (2012) |
| Raúl Jorge Tauber Larry | |
Austria | |
| J. Taucher et al. (1992) |
Brazil | |
| Sergio Varvello collection |
| King (n.d.) |
Germany | |
| Steffen Michalski collection - ex ... |
| ... |
Morocco | |
| Fontan (1978) |
Spain | |
| Christian Rewitzer collection |
USA | |
| Castor et al. (2004) |
| Kreinik (2022) |
| Nizamoff (2006) | |
| |
| Boutry Collection |
| Moore et al. (1974) +1 other reference |
| Moore et al. (1974) |
| Rocks & Minerals: 67 (6) |
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The
Tip Top Mine, Fourmile, Custer Mining District, Custer County, South Dakota, USA