Hmmm...
I admit, I was NOT a GnR fan, so it doesn't have the same resonance for me.
I'm trying to think if Release is fifth for me... but if I do put it there (it might be higher for me), what an incredibly inventive, complex, powerful song.
I can remember a whole lot of dark nights in college when "Black" and "Release" were the songs that just straight up spoke to me.
I'd stack that up against the fifth best song on most albums.