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Pseudocotunnite

A valid IMA mineral species - grandfathered - questionable
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About PseudocotunniteHide

Formula:
K2PbCl4
Colour:
Colourless, white
Lustre:
Dull
Crystal System:
Orthorhombic
Name:
From the resemblance of the crystals to cotunnite.
Doubtful species, although the compound K2PbCl4 is known in synthetic form.
See also the related challacolloite.


Unique IdentifiersHide

Mindat ID:
3303
Long-form identifier:
mindat:1:1:3303:5

IMA Classification of PseudocotunniteHide

Approved, 'Grandfathered' (first described prior to 1959), Questionable
IMA Formula:
K2PbCl4 (?)

Classification of PseudocotunniteHide

3.AA.90

3 : HALIDES
A : Simple halides, without H2O
A : M:X = 1:1, 2:3, 3:5, etc.
11.2.1.1

11 : HALIDE COMPLEXES
2 : AmBX4
8.8.12

8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
8 : Halides of Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
PcotIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PseudocotunniteHide

Colour:
Colourless, white

Optical Data of PseudocotunniteHide

Type:
Biaxial
Dispersion:
relatively weak

Chemistry of PseudocotunniteHide

Mindat Formula:
K2PbCl4
Element Weights:
Element% weight
Pb48.501 %
Cl33.195 %
K18.304 %

Calculated from ideal end-member formula.

Crystallography of PseudocotunniteHide

Crystal System:
Orthorhombic
Cell Parameters:
a = 9.82 Å, b = 11.8 Å, c = 5.77 Å
Ratio:
a:b:c = 0.832 : 1 : 0.489
Unit Cell V:
668.60 ų (Calculated from Unit Cell)
Morphology:
Crystals flattened on {010} or {100}, with indistinct {hk0} and {0kl} faces; elongated [001] into needle-like or lath-like shapes. Verruciform aggregates and dendritic crusts.
Comment:
Probably orthorhombic (synthetic crystals have space group Pnma).

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
45b : [Other oxidized fumarolic minerals]

Type Occurrence of PseudocotunniteHide

Geological Setting of Type Material:
Active volcanic fumaroles.
Associated Minerals at Type Locality:

Synonyms of PseudocotunniteHide

Other Language Names for PseudocotunniteHide

Common AssociatesHide

Associations Based on Photo Data:
4 photos of Pseudocotunnite associated with ChallacolloiteKPb2Cl5
3 photos of Pseudocotunnite associated with BismuthiniteBi2S3
3 photos of Pseudocotunnite associated with CannizzaritePb48Bi56S132
2 photos of Pseudocotunnite associated with CotunnitePbCl2
1 photo of Pseudocotunnite associated with HaliteNaCl
1 photo of Pseudocotunnite associated with SteropesiteTl3BiCl6

Related Minerals - Strunz-mindat GroupingHide

3.AA.Brontesite(NH4)3PbCl5Orth. mmm (2/m 2/m 2/m) : Pnma
3.AA.05MarshiteCuIIso. 4 3m : F4 3m
3.AA.05NantokiteCuClIso. 4 3m : F4 3m
3.AA.05'UM1999-11:I:CuS'Cu(I,S)
3.AA.05Miersite(Ag,Cu)IIso. 4 3m : F4 3m
3.AA.10Tocornalite(Ag,Hg)I (?)Hex.
3.AA.10IodargyriteAgIHex. 6mm : P6mm
3.AA.15BromargyriteAgBrIso. m3m (4/m 3 2/m) : Fm3m
3.AA.15ChlorargyriteAgClIso. m3m (4/m 3 2/m) : Fm3m
3.AA.20SylviteKClIso. m3m (4/m 3 2/m) : Fm3m
3.AA.20HaliteNaClIso. m3m (4/m 3 2/m) : Fm3m
3.AA.20VilliaumiteNaFIso. m3m (4/m 3 2/m) : Fd3m
3.AA.20CarobbiiteKFIso. m3m (4/m 3 2/m) : Fm3m
3.AA.20GriceiteLiFIso. m3m (4/m 3 2/m) : Fm3m
3.AA.25'UM1998-03-Cl:Tl'TlCl
3.AA.25NataliyamalikiteTlIOrth. mmm (2/m 2/m 2/m) : Cmcm
3.AA.25LafossaiteTl(Cl,Br)Iso. m3m (4/m 3 2/m) : Pm3m
3.AA.25SalammoniacNH4ClIso. m3m (4/m 3 2/m)
3.AA.30Calomel[Hg2]2+Cl2Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
3.AA.30Moschelite[Hg2]2+I2Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
3.AA.30Kuzminite[Hg2]2+(Br,Cl)2Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
3.AA.35NeighboriteNaMgF3Orth. mmm (2/m 2/m 2/m)
3.AA.35ParascandolaiteKMgF3Iso. m3m (4/m 3 2/m) : Pm3m
3.AA.40JavorieiteKFeCl3Orth. mmm (2/m 2/m 2/m) : Pnma
3.AA.40ChlorocalciteKCaCl3Orth. mmm (2/m 2/m 2/m) : Pnma
3.AA.45KolaritePbTeCl2Orth.
3.AA.50RadhakrishnaitePbTe3(Cl,S)2Tet.
3.AA.55ChallacolloiteKPb2Cl5Mon. 2/m : P21/b
3.AA.60HephaistositeTlPb2Cl5Mon. 2/m : P21/b

RadioactivityHide

Other InformationHide

Notes:
Totally soluble in warm water.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for PseudocotunniteHide

References for PseudocotunniteHide

Localities for PseudocotunniteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy (TL)
 
  • Campania
    • Metropolitan City of Naples
Russo +2 other references
Pelloux (1927) +1 other reference
  • Sicily
    • Metropolitan City of Messina
      • Eolie Islands (Aeolian Islands)
        • Lipari
          • Vulcano Island
Campostrini et al. (2010)
 
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