Idaite
A valid IMA mineral species - grandfathered
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About Idaite
Formula:
Cu5FeS6
Very close to Cu5.5FeS6.5 according to Sugaki et al. (1975).
Colour:
red-brown, bronzy-brown, or coppery-red, like untarnished bornite.
Lustre:
Metallic, Sub-Metallic
Hardness:
2½ - 3½
Specific Gravity:
4.2 (Calculated)
Crystal System:
Hexagonal
Name:
Named for the type locality, the Ida mine in Namibia.
Type Locality:
Grandfathered but inadequately described and questionable mineral; name may refer to both impure nukundamite, which was originally called "idaite", or to a tetragonal phase close to Sn-poor mawsonite (Rice et al., 1979). Most data here are consistent with nukundamite.
It has sometimes been placed in Stannite Group but the formula and crystal system are incompatible. The IMA formula appears incorrect.
A lamellar, strongly anisotropic, bronze-coloured, decomposition product of bornite, commonly associated with fine spindles of chalcopyrite; apparently of secondary origin, a first product of secondary enrichment.
Chemically similar to bornite.
It has sometimes been placed in Stannite Group but the formula and crystal system are incompatible. The IMA formula appears incorrect.
A lamellar, strongly anisotropic, bronze-coloured, decomposition product of bornite, commonly associated with fine spindles of chalcopyrite; apparently of secondary origin, a first product of secondary enrichment.
Chemically similar to bornite.
Unique Identifiers
Mindat ID:
2002
Long-form identifier:
mindat:1:1:2002:8
Similar Names
| Ikaite | A valid IMA mineral species | CaCO3 · 6H2O |
| Iodite | A synonym of Iodargyrite | |
| Itatĩ | A synonym of Native Silver | |
| Itoite | A valid IMA mineral species | Pb3Ge4+(SO4)2O2(OH)2 |
IMA Classification of Idaite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Cu3FeS4
First published:
1958
Classification of Idaite
2.CB.15a
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2.9.14.1
2 : SULFIDES
9 : AmBnXp, with (m+n):p = 1:1
2 : SULFIDES
9 : AmBnXp, with (m+n):p = 1:1
3.1.29
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
1 : Sulphides etc. of Cu
3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
1 : Sulphides etc. of Cu
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Ida | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Ida | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Idaite
Metallic, Sub-Metallic
Transparency:
Opaque
Colour:
Red-brown, bronzy-brown, or coppery-red, like untarnished bornite.
Hardness:
2½ - 3½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
4.2 g/cm3 (Calculated)
Optical Data of Idaite
Anisotropism:
Strong, reddish orange to reddish brown
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 400nm | 13.9% | 17.7% |
| 420nm | 14.8% | 18.5% |
| 440nm | 15.7% | 19.3% |
| 460nm | 16.9% | 21.0% |
| 480nm | 18.4% | 23.2% |
| 500nm | 20.5% | 25.5% |
| 520nm | 23.2% | 27.8% |
| 540nm | 26.1% | 29.4% |
| 560nm | 28.9% | 30.6% |
| 580nm | 30.6% | 31.4% |
| 600nm | 31.9% | 31.6% |
| 620nm | 32.8% | 31.9% |
| 640nm | 33.5% | 32.2% |
| 660nm | 34.1% | 32.8% |
| 680nm | 34.7% | 33.2% |
| 700nm | 35.2% | 33.7% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 35.2%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Red-orange to yellow-grey.
Chemistry of Idaite
Mindat Formula:
Cu5FeS6
Very close to Cu5.5FeS6.5 according to Sugaki et al. (1975).
Very close to Cu5.5FeS6.5 according to Sugaki et al. (1975).
Element Weights:
Elements listed:
Crystallography of Idaite
Crystal System:
Hexagonal
Cell Parameters:
a = 3.90 Å, c = 16.95 Å
Ratio:
a:c = 1 : 4.346
Unit Cell V:
223.27 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Lamellar.
Comment:
Space group unknown.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.38 Å | (5) |
| 3.27 Å | (60) |
| 3.14 Å | (100) |
| 3.00 Å | (5) |
| 2.82 Å | (100) |
| 2.70 Å | (80) |
| 2.42 Å | (40) |
| 2.20 Å | (40) |
| 2.13 Å | (5) |
| 1.89 Å | (100) |
| 1.85 Å | (100) |
| 1.79 Å | (5) |
| 1.73 Å | (40) |
| 1.686 Å | (5) |
| 1.630 Å | (60) |
| 1.564 Å | (100) |
| 1.500 Å | (5) |
| 1.442 Å | (40) |
| 1.317 Å | (80) |
| 1.275 Å | (5) |
| 1.225 Å | (40) |
| 1.206 Å | (40) |
| 1.188 Å | (5) |
| 1.161 Å | (60) |
| 1.141 Å | (5) |
| 1.104 Å | (5) |
| 1.091 Å | (20) |
| 1.081 Å | (80) |
| 1.058 Å | (40) |
| 1.043 Å | (80) |
| 1.017 Å | (40) |
| 1.006 Å | (40) |
| 0.987 Å | (40) |
Comments:
ICDD 13-161. Research articles suggest that idaite needs re-investigation.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 2: Planetesimal differentiation and alteration | 4.566-4.550 |
| 6 : Secondary asteroid phases | 4.566-4.560 |
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Idaite
General Appearance of Type Material:
Lamellar.
Place of Conservation of Type Material:
Not recorded.
Geological Setting of Type Material:
A decomposition product of bornite.
Associated Minerals at Type Locality:
Synonyms of Idaite
Copper Sulphides (in part)
Other Language Names for Idaite
Common Associates
Associations Based on Photo Data:
| 53 photos of Idaite associated with Chalcopyrite | CuFeS2 |
| 51 photos of Idaite associated with Covellite | CuS |
| 31 photos of Idaite associated with Bornite | Cu5FeS4 |
| 10 photos of Idaite associated with Pyrite | FeS2 |
| 5 photos of Idaite associated with Tennantite Subgroup | Cu6(Cu4C2+2)As4S12S |
| 2 photos of Idaite associated with Digenite | Cu9S5 |
| 1 photo of Idaite associated with Charoite | (K,Sr)15-16(Ca,Na)32[Si6O11(O,OH)6]2[Si12O18(O,OH)12]2[Si17O25(O,OH)18]2(OH,F)4 · ~3H2O |
| 1 photo of Idaite associated with Aegirine | NaFe3+Si2O6 |
| 1 photo of Idaite associated with Pectolite | NaCa2Si3O8(OH) |
| 1 photo of Idaite associated with Nukundamite | Cu3.33Fe0.66S4 |
Related Minerals - Strunz-mindat Grouping
| 2.CB. | Richardsite | Zn2CuGaS4 |
| 2.CB. | Okruginite | Cu2SnSe3 |
| 2.CB. | Hanswilkeite | KFeS2 |
| 2.CB. | Auroselenide | AuSe |
| 2.CB. | Ruizhongite | (Ag2◻)Pb3Ge2S8 |
| 2.CB. | Agmantinite | Ag2MnSnS4 |
| 2.CB. | Tolstykhite | Au3S4Te6 |
| 2.CB. | Gachingite | Au(Te1-xSex) |
| 2.CB.05a | Hawleyite | CdS |
| 2.CB.05 | 'UM1998-15-S:CuFeZn' | Cu2Fe3Zn5S10 |
| 2.CB.05a | Coloradoite | HgTe |
| 2.CB.05a | Metacinnabar | HgS |
| 2.CB.05a | Tiemannite | HgSe |
| 2.CB.05a | Sphalerite | ZnS |
| 2.CB.05b | Sakuraiite | (Cu,Zn,Fe)3(In,Sn)S4 |
| 2.CB.05c | Polhemusite | (Zn,Hg)S |
| 2.CB.05a | Rudashevskyite | (Fe,Zn)S |
| 2.CB.05a | Stilleite | ZnSe |
| 2.CB.05a | Ishiharaite | (Cu,Ga,Fe,In,Zn)S |
| 2.CB.07a | 'Unnamed (Cu-Mn-Sn Sulphide)' | Cu2MnSnS4 |
| 2.CB.07a | Shenzhuangite | NiFeS2 |
| 2.CB.10b | Talnakhite | Cu9(Fe,Ni)8S16 |
| 2.CB.10b | Haycockite | Cu4Fe5S8 |
| 2.CB.10a | Lenaite | AgFeS2 |
| 2.CB.10a | Gallite | CuGaS2 |
| 2.CB.10a | Roquesite | CuInS2 |
| 2.CB.10a | Eskebornite | CuFeSe2 |
| 2.CB.10a | 'UM1984-30-S:CuFeSn' | Cu2Fe2Sn3S7 |
| 2.CB.10c | Omariniite | Cu8Fe2ZnGe2S12 |
| 2.CB.10a | Chalcopyrite | CuFeS2 |
| 2.CB.10a | 'Unnamed (Cu-Zn-In Sulphide)' | CuZn2InS4 |
| 2.CB.10b | Mooihoekite | Cu9Fe9S16 |
| 2.CB.10a | Laforêtite | AgInS2 |
| 2.CB.10b | Putoranite | Cu1.1Fe1.2S2 |
| 2.CB.15a | Velikite | Cu2HgSnS4 |
| 2.CB.15c | 'UM2006-11-S:CuFeGeZn' | Cu8(Fe,Zn)3Ge2S12 (?) |
| 2.CB.15a | Hocartite | Ag2(Fe2+,Zn)SnS4 |
| 2.CB.15a | Kësterite | Cu2ZnSnS4 |
| 2.CB.15a | Pirquitasite | Ag2ZnSnS4 |
| 2.CB.15a | Stannite | Cu2FeSnS4 |
| 2.CB.15c | Stannoidite | Cu+6Cu2+2(Fe2+,Zn)3Sn2S12 |
| 2.CB.15b | Mohite | Cu2SnS3 |
| 2.CB.15a | Černýite | Cu2CdSnS4 |
| 2.CB.15a | Ferrokësterite | Cu2FeSnS4 |
| 2.CB.15a | Kuramite | Cu3SnS4 |
| 2.CB.17a v | 'Arsenic-bearing Renierite' | Cu11GeAsFe4S16 |
| 2.CB.20 | Mawsonite | Cu6Fe2SnS8 |
| 2.CB.20 | Chatkalite | Cu6FeSn2S8 |
| 2.CB.30 | 'Frieseite' | Ag2Fe5S8 (?) |
| 2.CB.30 | Nekrasovite | Cu26V2(Sn,As,Sb)6S32 |
| 2.CB.30 | 'Argyropyrite' | near Ag2Fe7S11 |
| 2.CB.30 | Maikainite | Cu20(Fe,Cu)6Mo2Ge6S32 |
| 2.CB.30 | Colusite | Cu13VAs3S16 |
| 2.CB.30 | Germanite | Cu13Fe2Ge2S16 |
| 2.CB.30 | Germanocolusite | Cu26V2(Ge,As)6S32 |
| 2.CB.30 | Stibiocolusite | Cu13V(Sb,Sn,As)3S16 |
| 2.CB.30 | Ovamboite | Cu20(Fe,Cu,Zn)6W2Ge6S32 |
| 2.CB.35a | Morozeviczite | (Pb,Fe)3Ge1-xS4 |
| 2.CB.35a | Renierite | (Cu1+,Zn)11Fe4(Ge4+,As5+)2S16 |
| 2.CB.35a | Hemusite | Cu6SnMoS8 |
| 2.CB.35b | Catamarcaite | Cu6GeWS8 |
| 2.CB.35a | Vinciennite | Cu+7Cu2+3Fe2+2Fe3+2Sn(As,Sb)S16 |
| 2.CB.35a | Kiddcreekite | Cu6SnWS8 |
| 2.CB.35a | Polkovicite | (Fe,Pb)3(Ge,Fe)1-xS4 |
| 2.CB.40 | Lautite | CuAsS |
| 2.CB.42 | Lingbaoite | AgTe3 |
| 2.CB.45 | Cadmoselite | CdSe |
| 2.CB.45 | Rambergite | MnS |
| 2.CB.45 | Buseckite | (Fe,Zn,Mn)S |
| 2.CB.45 | Maletoyvayamite | Au3Se4Te6 |
| 2.CB.45 | Greenockite | CdS |
| 2.CB.45 | Wurtzite | (Zn,Fe)S |
| 2.CB.47 | Murchisite | Cr5S6 |
| 2.CB.50 | 'Zincselenide' | ZnSe |
| 2.CB.50 | Wassonite | TiS |
| 2.CB.52 | 'Dzhezkazganite' | ReMoCu2PbS6 ? |
| 2.CB.55b | Isocubanite | CuFe2S3 |
| 2.CB.55a | Cubanite | CuFe2S3 |
| 2.CB.60 | Raguinite | TlFeS2 |
| 2.CB.60 | Picotpaulite | TlFe2S3 |
| 2.CB.65 | Argentopyrite | AgFe2S3 |
| 2.CB.65 | Sternbergite | AgFe2S3 |
| 2.CB.70 | Sulvanite | Cu3VS4 |
| 2.CB.75 | Vulcanite | CuTe |
| 2.CB.80 | Empressite | AgTe |
| 2.CB.85 | Muthmannite | AuAgTe2 |
Fluorescence of Idaite
Not fluorescent in UV
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Idaite
mindat.org URL:
https://www.mindat.org/min-2002.html
Please feel free to link to this page.
Please feel free to link to this page.
Search Engines:
External Links:
Mineral Dealers:
References for Idaite
Reference List:
Yund, Richard A. (1963) Crystal Data For Synthetic Cu5.5xFexS6.5x (IDAITE). American Mineralogist, 48 (5-6). 672-677
Constantinou, G. (1975) Idaite from the Skouriotissa massive sulfide orebody, Cyprus: Its composition and conditions of formation. American Mineralogist, 60 (11-12) 1013-1018
Sugaki, A., Shima, H., Kitakaze, A., Harada, H. (1975) Isothermal phase relations in the system Cu-Fe-S under hydrothermal conditions at 350°C and 300°C. Economic Geology, 70 (4) 806-823 doi:10.2113/gsecongeo.70.4.806
Localities for Idaite
Showing 188 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Angola | |
| Milesi et al. (2006) |
Antarctica | |
| El Gorsey et al. (1988) |
Argentina | |
| Minerales de la Republica Argentina +1 other reference |
| Brodtkorb et al. (1999) |
| Singer et al. (2005) | |
| Brodtkorb (2002) |
| American Mineralogist: 51: 1-13 | |
| Brodtkorb (2002) |
| Brodtkorb (2002) |
Atlantic Ocean | |
| Mozgova et al. (2007) |
| Firstova et al. (2019) |
| Mozgova et al. (2000) |
Australia | |
| McClatchie (1971) |
| Gilligan et al. (1993) | |
| Gilligan et al. (1993) | |
| Ehrig et al. (2012) |
| Annells (1981) |
Austria | |
| Huber et al. (1977) +1 other reference |
| Paar et al. (1982) +1 other reference |
| Tufar (1967) +1 other reference |
| Hackenberg (2003) | |
| Tufar (1966) |
| R.Poeverlein (2016) |
| R.Poeverlein (2016) | |
| R.Poeverlein (2016) | |
| Vavtar (1986) |
| Vohryzka (1968) +1 other reference |
Belgium | |
| Hatert et al. (2014) |
| Michel Blondieau. +5 other references |
| Hatert (1996) +1 other reference |
Brazil | |
| Bello (1986) |
Bulgaria | |
| Bul. Acad. Sci. (1998) |
| Bogdanov et al. (1997) |
| Anthony et al. (1990) |
| Cioacă et al. (2018) |
| Terziev (1966) +1 other reference |
| Mladenova et al. (2017) |
Canada | |
| Goble (1980) |
| Goble (1980) | |
| personal correspondence with Giles ... +1 other reference |
| Badham et al. (1980) |
| Wilson et al. (2013) |
| Mineralium Deposita 44 (2009) |
| Econ Geol (1994) |
Chile | |
| Singer et al. (2008) |
| Cook (1978) |
| "Faja de mineralización de oro +2 other references |
| HENLEY et al. (2011) | |
China | |
| Lin et al. (2002) |
| Zhengqin Li (1991) |
| Zhengqin Li (1991) |
Cyprus | |
| Constantinou (1975) +1 other reference |
DR Congo | |
| Deliens (1996) |
| J. Cailteux (Shaba, République du Zaïre) |
Ecuador | |
| Chiaradia et al. (2000) |
| Chiaradia et al. (2000) |
Europe | |
| Ferenc et al. (2001) |
Fiji | |
| 1996 +5 other references |
Finland | |
| Mutanen |
| Nurmi |
France | |
| Picot et al. (1977) |
| Pélisson (1989) |
| Pélisson (1989) |
| Wittern et al. (1997) |
| Cesbron et al. (1985) +1 other reference |
| Chauris (2014) |
| Pierrot et al. (1973) |
| Chauris (2014) |
| Azias (1968) |
| Azias (1968) | |
| Briggs (1975) |
| Briggs (1975) |
| Pierrot et al. (France) |
| |
| |
| Galvier et al. (1997) +1 other reference |
| R. Pierrot |
| R. Pierrot |
| R. Pierrot |
| R. Pierrot |
| R. Pierrot | |
| R. Pierrot | |
| R. Pierrot |
| R. Pierrot |
| A. Sinojmeri et al. (Hautes Alpes) |
| R. Pierrot |
| R. Pierrot |
Germany | |
| Walenta (1992) |
| Weiß (1990) |
| Walenta (1992) |
| Walenta (1992) |
| |
| Weiß (1990) |
| Kopp et al. (2006) +1 other reference |
| Weiß (1990) |
| Heider (2014) |
| Wittern (2001) |
| Krupp (1989) |
| Wittern (2001) |
Hungary | |
| NAGY et al. (2000) |
| Szakáll: Minerals of Rudabánya | |
India | |
| Sikka et al. (1991) +1 other reference |
| Tripathi et al. (2022) |
Indian Ocean | |
| Wang et al. (2018) |
| Wang et al. (2014) |
Indonesia | |
| Econ Geol (1997) +1 other reference |
Italy | |
| Bedognè et al. (1993) |
| - (n.d.) |
| Venerandi Pirri (2002) |
| Exel (1987) |
Japan | |
| - (n.d.) +1 other reference |
| - (microprobe analysis of specimen field collected by Alfredo Petrov) |
| Nagashima et al. (2021) |
Kazakhstan | |
| Baibatsha et al. (2015) +1 other reference |
| Duczmal-Czernikiewicz et al. (2021) |
Morocco | |
| Weiß (2006) |
Namibia (TL) | |
| Frenzel (1958) |
| Gebhard (1999) |
New Zealand | |
| Mason et al. (Zn) |
Norway | |
| Krause (1965) +1 other reference |
| Prospektering AS (1981) |
| Neumann (1985) |
| Frenzel (1960) |
| Cook et al. (2008) |
| Dons (1963) |
| Krause (1965) +1 other reference |
| - (1997) |
| Bergstøl et al. (1974) |
| Witsø (1995) |
| Witsø (1995) | |
| Geological Survey of Norway. The Ore ... | |
| Størseth (2016) |
| Pinet et al. (1985) |
Pacific Ocean | |
| Econ Geol (1985) |
Papua New Guinea | |
| Noku et al. (2002) +1 other reference |
| K92 Mining |
Peru | |
| Weigeli (1994) +1 other reference |
Philippines | |
| Singer et al. (2008) |
| Singer et al. (2008) |
Poland | |
| Mochnacka et al. (2012) +1 other reference |
| Mochnacka et al. (2015) |
| Mochnacka et al. (2015) |
| Chmielewski et al. (2016) | |
| Kucha H. 2007: Mineralogia kruszcowa i ... |
| Chmielewski et al. (2022) |
| Manecki (Polish Geological Institute) |
Romania | |
| Constantinescu et al. (1982) +1 other reference |
Russia | |
| Konev et al. (1993) +2 other references |
| Kaneva et al. (2020) |
| Andreeva et al. (2013) |
| Savva et al. (2023) |
| Ivashchenko et al. (2011, September) |
| Gongalsky et al. (2019) |
Serbia | |
| RTB Bor |
| Aleksandar Pacevski (2007) |
Slovakia | |
| Ferenc Š. & Rojkovič I. |
| Ďuda et al. (1996) |
Sweden | |
| Pieslinger (2023) |
| Carnegie Museum of Natural History ... |
| Dobbe (1991) |
Switzerland | |
| Stalder et al. (1998) |
| - (1993) |
| Ansermet (2012) |
| Ansermet (2012) |
| Ansermet (2012) |
| Stalder et al. (1998) +1 other reference | |
| Ansermet (2012) |
Turkey | |
| Oyman (2010) |
| Kalender et al. (2004) |
| GÜNER (1980) |
| Çağatay et al. (1989) |
| Kilic et al. (2024) |
UK | |
| Ixer et al. (1993) +1 other reference |
| Ixer et al. (2005) |
USA | |
| - (2008) |
| USGS OFR 99-342 | |
| - (2008) | |
| - (2008) | |
| - (2008) | |
| Merritt Stephen Enders (2000) |
| Dunning et al. (2005) |
| - (2005) |
| Eckel et al. (1997) |
| Eckel et al. (1997) |
| Mines of the Washington D.C Area |
| The Spar Lake Strata-Bound Cu-Ag Deposit Formed Across a Mixing Zone Between Trapped Natural Gas and Metals-Bearing Brine Econ Geol (1986) +1 other reference |
| Northrop et al. (1996) |
| Econ Geol (1986) |
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The
Gruvberget, Svappavaara, Kiruna, Norrbotten County, Sweden