User:ThisSpace/FunctionalGroups

Functional Groups

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Hydrocarbons

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Chemical class Group Formula Structural Formula Prefix Suffix Example
AlkaneAlkyl RH Alkyl alkyl--ane methane
Ethane
AlkeneAlkenyl R2C=CR2 alkenyl--ene ethylene
Ethylene
(Ethene)
AlkyneAlkynyl RC=CR' Alkyne alkynyl--yne acetylene
Acetylene
(Ethyne)
Benzene derivative Phenyl RC6H5
RPh
Phenyl phenyl--benzene Cumene
Cumene
(2-phenylpropane)
Toluene derivative Benzyl RCH2C6H5
RBn
Benzyl benzyl- 1-(substituent)toluene Benzyl bromide
Benzyl bromide
(1-Bromotoluene)

Groups containing halogens

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Chemical class Group Formula Structural Formula Prefix Suffix Example
haloalkanehalo RX Halide group halo-alkyl halide Chloroethane
Chloroethane
(Ethyl chloride)
chloroalkanechloro RCl Chloro group chloro-alkyl chloride Chloromethane
Chloromethane
(Methyl chloride)

Groups containing oxygen

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Chemical class Group Formula Structural Formula Prefix Suffix Example
Acyl halideHaloformyl RCOX Acyl halide haloformyl--oyl halide Acetyl chloride
Acetyl chloride
(Ethanoyl chloride)
AlcoholHydroxyl ROH Hydroxyl hydroxy--ol methanol
Methanol
KetoneCarbonyl RCOR' Ketone keto-, oxo--one Butanone
Methyl ethyl ketone
(Butanone)
AldehydeAldehyde RCHO Aldehyde aldo--al acetaldehyde
Acetaldehyde
(Ethanal)
Carbonate Carbonate ester ROCOOR Carbonate alkyl carbonate
Carboxylate CarboxylateRCOO- Carboxylate

Carboxylate

carboxy--oate Sodium acetate
Sodium acetate
(Sodium ethanoate)
Carboxylic acid CarboxylRCOOH Carboxylic acid carboxy--oic acid Acetic acid
Acetic acid
(Ethanoic acid)
EtherEther ROR' Ether alkoxy- alkyl alkyl ether Diethyl ether
Diethyl ether
(Ethoxyethane)
EsterEster RCOOR' Ester alkyl alkanoate Ethyl butyrate
Ethyl butyrate
(Ethyl butanoate)
Hydroperoxide Hydroperoxy ROOH Hydroperoxy hydroperoxy- alkyl hydroperoxide Methyl ethyl ketone peroxide
Methyl ethyl ketone peroxide
Peroxide Peroxy ROOR Peroxy peroxy- alkyl peroxide Di-tert-butyl peroxide
Di-tert-butyl peroxide

Groups containing nitrogen

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Chemical class Group Formula Structural Formula Prefix Suffix Example
AmideCarboxamide RCONR2 Amide carboxamido--amide acetamide
Acetamide
(Ethanamide)
Amines Primary amine RNH2 Primary amine amino--amine methylamine
Methylamine
(Methanamine)
Secondary amine R2NH Secondary amine amino--amine dimethylamine
Dimethylamine
Tertiary amine R3N Tertiary amine amino--amine trimethylamine
Trimethylamine
4° ammonium ion R4N+ Quaternary ammonium cation ammonio--ammonium choline
Choline
Azo compound Azo
(Diimide)
RN2R' Azo.pngl azo--diazene Methyl orange
Methyl orange
(p-dimethylamino-azobenzenesulfonic acid)
NitrateNitrate RONO2 Nitrate nitrooxy-, nitroxy-

alkyl nitrate

Amyl nitrate
Amyl nitrate
(1-nitrooxypentane)
NitrileNitrile RCN Nitrile cyano-

alkanenitrile
alkyl cyanide

Benzonitrile
Benzonitrile
(Phenyl cyanide)
NitriteNitrosooxy RONO Nitrite nitrosooxy-

alkyl nitrite

Amyl nitrite
Isoamyl nitrite
(3-methyl-1-nitrosooxybutane)
Nitro compound Nitro RNO2 Nitro nitro-  Nitromethane
Nitromethane