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Cacoxenite

A valid IMA mineral species - grandfathered
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About CacoxeniteHide

Formula:
Fe3+24AlO6(PO4)17(OH)12 · 75H2O
Colour:
Yellow to brownish yellow, reddish orange, golden yellow, deep orange, green
Lustre:
Silky
Hardness:
3 - 4
Specific Gravity:
2.2 - 2.6
Crystal System:
Hexagonal
Name:
From the Greek κακός for "bad" and ξένος for "guest" due to the fact that the phosphorous content of cacoxenite lessens the quality of iron smelted from ore containing it.
A secondary mineral found in oxidized zones of phosphatic magnetite deposits, in novaculites, in phosphate-rich pegmatites, and rarely in iron-rich sediments and soils.


Unique IdentifiersHide

Mindat ID:
840
Long-form identifier:
mindat:1:1:840:6

IMA Classification of CacoxeniteHide

Approved, 'Grandfathered' (first described prior to 1959)

Classification of CacoxeniteHide

8.DC.40

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
42.13.5.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
13 : Miscellaneous
19.14.27

19 : Phosphates
14 : Phosphates of Fe and other metals

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
CacIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CacoxeniteHide

Silky
Transparency:
Translucent
Colour:
Yellow to brownish yellow, reddish orange, golden yellow, deep orange, green
Comment:
Yellow in transmitted light.
Hardness:
3 - 4 on Mohs scale
Density:
2.2 - 2.6 g/cm3 (Measured)    2.217 g/cm3 (Calculated)

Optical Data of CacoxeniteHide

Type:
Uniaxial (+)
RI values:
nω = 1.575 - 1.585 nε = 1.635 - 1.656
Max. Birefringence:
δ = 0.060 - 0.071
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate
Pleochroism:
Visible
Comments:
O = Pale yellow
E = Canary yellow to yellow orange

Chemistry of CacoxeniteHide

Mindat Formula:
Fe3+24AlO6(PO4)17(OH)12 · 75H2O
Element Weights:
Element% weight
O55.599 %
Fe28.929 %
P11.365 %
H3.524 %
Al0.582 %

Calculated from ideal end-member formula.
Common Impurities:
Al

Crystallography of CacoxeniteHide

Crystal System:
Hexagonal
Class (H-M):
6/m - Dipyramidal
Space Group:
P63/m
Cell Parameters:
a = 27.559(1) Å, c = 10.55 Å
Ratio:
a:c = 1 : 0.383
Unit Cell V:
6,939.21 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals crudely hexagonal, acicular [0001], with a hexagonal cross section at times and indistinct pyramidal faces. Commonly in compact, concentric, spherical to radial aggregates. In bundles, randomly fibrous; as coatings or intergranular cement.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014677CacoxeniteMoore P B, Shen J (1983) An X-ray structural study of cacoxenite, a mineral phosphate Nature 306 356-3581983Avant's Claim, near Shady, Polk County, Arkansas, USA0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
11.94 Å(100)
22.0 Å(80)
3.3452 Å(50)
4.897 Å(40)
6.921 Å(30)
9.065 Å(20)
2.7868 Å(20)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
21 : Chemically precipitated carbonate, phosphate, iron formations
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
48 : Soil leaching zone minerals<0.6
Stage 10b: Anthropogenic minerals<10 Ka
55 : Anthropogenic mine minerals
Geological Setting:
Common accessory mineral in oxidation zone of magnetic and limonite iron ores, novaculites, rarely in iron rich sediments and soils.

Type Occurrence of CacoxeniteHide

Synonyms of CacoxeniteHide

Other Language Names for CacoxeniteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
320 photos of Cacoxenite associated with StrengiteFePO4 · 2H2O
238 photos of Cacoxenite associated with BerauniteFe3+6(PO4)4O(OH)4 · 6H2O
75 photos of Cacoxenite associated with Rockbridgeite(Fe2+0.5Fe3+0.5)2Fe3+3(PO4)3(OH)5
74 photos of Cacoxenite associated with WavelliteAl3(PO4)2(OH)3 · 5H2O
72 photos of Cacoxenite associated with QuartzSiO2
50 photos of Cacoxenite associated with KidwelliteNaFe3+9+x(PO4)6(OH)11 · 3H2O, x = 0.33
47 photos of Cacoxenite associated with Aluminium-bearing Strengite(Fe,Al)PO4 · 2H2O
47 photos of Cacoxenite associated with ChalcosideriteCuFe3+6(PO4)4(OH)8 · 4H2O
47 photos of Cacoxenite associated with DufréniteCa0.5Fe2+Fe3+5(PO4)4(OH)6 · 2H2O
43 photos of Cacoxenite associated with FerristrunziteFe3+Fe3+2(PO4)2(OH)3 · 5H2O

Related Minerals - Strunz-mindat GroupingHide

8.DC.CésarferreiraiteFe2+ Fe3+2(AsO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.FerrivauxiteFe3+Al2(PO4)2(OH)3 · 5H2OTric. 1 : P1
8.DC.IanbruceiteZn2(AsO4)(OH) · 3H2OMon. 2/m : P21/b
8.DC.05NissoniteCu2Mg2(PO4)2(OH)2 · 5H2OMon. 2/m : B2/b
8.DC.07EuchroiteCu2(AsO4)(OH) · 3H2OOrth. 2 2 2 : P21 21 21
8.DC.10LegranditeZn2(AsO4)(OH) · H2OMon. 2/m : P21/b
8.DC.12StrashimiriteCu8(AsO4)4(OH)4 · 5H2OMon.
8.DC.15EarlshannoniteMn2+Fe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15KunatiteCuFe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15UM2006-27-PO:FeHZnZnFe3+2(PO4)2(OH)2 · 4H2OMon.
8.DC.15UKI-2006-(PO:AlCuFeH)Fe2+Al3+2(PO4)2(OH)2 · 4H2O
8.DC.15CobaltarthuriteCoFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15ArthuriteCuFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15OjuelaiteZnFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15WhitmoreiteFe2+Fe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.15BendadaiteFe2+Fe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/b
8.DC.17KleemaniteZnAl2(PO4)2(OH)2 · 3H2OMon.
8.DC.20MagnesiobermaniteMgMn3+2(PO4)2(OH)2 · 4H2OMon. 2 : P21
8.DC.20BermaniteMn2+Mn3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P2/b
8.DC.20CoralloiteMn2+Mn3+2(AsO4)2(OH)2 · 4H2OTric. 1 : P1
8.DC.22KovdorskiteMg2(PO4)(OH) · 3H2OMon. 2/m : P21/b
8.DC.25ZincostrunziteZnFe3+2(PO4)2(OH)2 · 6.5H2OTric. 1 : P1
8.DC.25MetavauxiteFe2+Al2(PO4)2(OH)2 · 8H2OMon. 2/m : P21/b
8.DC.25MetavivianiteFe2+Fe3+2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.25FerristrunziteFe3+Fe3+2(PO4)2(OH)3 · 5H2OTric.
8.DC.25StrunziteMn2+Fe3+2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.25FerrostrunziteFe2+Fe3+2(PO4)2(OH)2 · 6H2OTric.
8.DC.27BerauniteFe3+6(PO4)4O(OH)4 · 6H2OMon. m : Bb
8.DC.27TvrdýiteFe2+Fe3+2Al3(PO4)4(OH)5(H2O)4 · 2H2OMon. 2/m : B2/b
8.DC.27ZincoberauniteZnFe3+5(PO4)4(OH)5 · 6H2OMon. 2/m : B2/b
8.DC.30MaghrebiteMgAl2(AsO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30FerrolaueiteFe2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30UshkoviteMgFe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30LaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30ParavauxiteFe2+Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30SigloiteFe3+Al2(PO4)2(OH)3 · 7H2OTric. 1 : P1
8.DC.30NordgauiteMnAl2(PO4)2(F,OH)2 · 5H2OTric. 1 : P1
8.DC.30Kayrobertsonite[MnAl2(PO4)2(OH)2(H2O)4] · 2H2OTric. 1 : P1
8.DC.30KummeriteMn2+Fe3+Al(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30MangangordoniteMn2+Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30StewartiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30GordoniteMgAl2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30Kastningite(Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30PseudolaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OMon. 2/m : P21/b
8.DC.32KamarizaiteFe3+3(AsO4)2(OH)3 · 3H2OTric. 1 : P1
8.DC.32TinticiteFe3+3(PO4)2(OH)3 · 3H2OTric. 1 : P1
8.DC.35VauxiteFe2+Al2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.37VantasseliteAl4(PO4)3(OH)3 · 9H2OOrth.
8.DC.45Souzalite(Mg,Fe2+)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2OTric. 1
8.DC.45Gormanite(Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2OTric.
8.DC.47KingiteAl3(PO4)2F2(OH) · 7H2OTric.
8.DC.50AllanpringiteFe3+3(PO4)2(OH)3 · 5H2OMon. 2/m : P21/m
8.DC.50FluorwavelliteAl3(PO4)2(OH)2F · 5H2OOrth. mmm (2/m 2/m 2/m)
8.DC.50WavelliteAl3(PO4)2(OH)3 · 5H2OOrth. mmm (2/m 2/m 2/m)
8.DC.52KribergiteAl5(PO4)3(SO4)(OH)4 · 4H2OTric. 1 : P1
8.DC.55MapimiteZn2Fe3+3(AsO4)3(OH)4 · 10H2OMon. m : Bm
8.DC.57OgdensburgiteCa2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2OOrth. mmm (2/m 2/m 2/m) : Cmmm
8.DC.60CloncurryiteCu0.5(VO)0.5Al2(PO4)2F2 · 5H2OMon. 2/m : P21/b
8.DC.60Nevadaite(Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2OOrth. mmm (2/m 2/m 2/m)
8.DC.62KenngottiteMn2+3Fe3+4(PO4)4(OH)6(H2O)2 Mon. 2/m : P2/b
8.DC.67MolinelloiteCu(H2O)(OH)V4+O(V5+O4)Tric. 1 : P1
8.DC.70WhitecapsiteH16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2OHex. 6/m : P63/m
8.DC.75HeimitePbCu2(AsO4)(OH)3 · 2H2OMon. 2/m
8.DC.80LedneviteCu[PO3(OH)] · H2OMon. 2/m : P21/b

Other InformationHide

Notes:
Readily soluble in acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CacoxeniteHide

References for CacoxeniteHide

Reference List:

Localities for CacoxeniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • San Luis Province
    • Coronel Pringles Department
      • Totoral pegmatitic field
Oyarzábal et al. (2016)
Australia
 
  • New South Wales
    • Arrawatta Co.
Dieter Mylius collection
    • Westmoreland County
Cendón et al. (2004)
    • Yancowinna Co.
      • Thackaringa District
Bottrill (2018)
  • Queensland
    • City of Mount Isa
      • Mount Isa
Sielecki (1988)
Sielecki (1988)
  • South Australia
    • Barossa Council
      • Penrice
Harrowfield et al. (1981)
    • Copper Coast Council
      • Moonta
    • District Council of Mount Remarkable
      • Wilmington
Beyer et al. (1996)
    • Light Regional Council
      • Koonunga
Pilkington et al. (1982) +1 other reference
      • St Johns
    • Northern Areas Council
      • Gladstone
Sorrell (n.d.) +1 other reference
    • Pastoral Unincorporated Area
      • Boolcoomatta Reserve (Boolcoomata Station)
    • Robertstown
Francis et al. (2012)
  • Victoria
    • City of Greater Shepparton
      • Dookie
        • Ascot Hills
    • Mansfield Shire
      • Mansfield
Birch et al. (1993)
    • South Gippsland Shire
      • Hoddle Range
        • Fish Creek
Museum Victoria Mineralogy Collection
    • Swan Hill Rural City
      • Lake Boga
Sorrell (n.d.)
Austria
 
  • Salzburg
    • Tamsweg District
      • Muhr
        • Rotgülden
          • Lower Rotgülden lake
Strasser (1992) +1 other reference
  • Styria
    • Bruck-Mürzzuschlag District
      • Krieglach
        • Freßnitzgraben
          • Alpl
Kolitsch (2009)
    • Südoststeiermark District
      • Bad Gleichenberg
        • Klausen
Aufschluss 1972 (SB)
      • Feldbach
        • Gossendorf
Exel (1993)
Meixner (1958)
    • Voitsberg District
      • Edelschrott
        • Modriach
          • Herzogberg
Aufschluss 1972 (SB)
    • Weiz District
      • Fischbach
        • Falkenstein
Michael Reicht collection
          • Schindergraben
M.Reicht collection
Bernhard (1996) +1 other reference
Belgium
 
  • Wallonia
    • Hainaut
      • Bernissart
        • Blaton
Van Tassel (1966) +7 other references
    • Liège
      • Visé
Van Tassel (1959) +2 other references
      • Waimes
perso.infonie.be (2004)
    • Luxembourg
Michel Blondieau. +1 other reference
Fouassin et al. (1975) +2 other references
Fransolet (1987)
Hatert et al. (2002)
Hatert et al. (2002)
        • Cahay
Hatert et al. (2002)
        • Salmchâteau
Blondieau (2005)
    • Namur
      • Anhée
Dillen et al. (1990) +1 other reference
      • Namur
Blondieau et al. (2012)
Brazil
 
  • Minas Gerais
    • Conselheiro Pena
      • Barra do Cuieté
various photographs
    • Galiléia
      • Sapucaia do Norte
Cassedanne et al. (1999)
  • Paraíba
    • Picuí
Sergio Varvello collection
Bulgaria
 
  • Haskovo Province
    • Mineralni Bani Municipality
      • Spahievo
        • Spahievo ore field
Kunov (1996) +2 other references
  • Kardzhali Province
    • Momchilgrad Municipality
      • Obichnik
Kunov et al. (1997)
Burundi
 
  • Kayanza Province
www.trademarksa.org (n.d.)
Cameroon
 
  • Adamawa Region
    • Vina
      • Martap
F. Pillard : "Contribution à l'étude de l'altération de la vivianite : cas de la vivianite d'Anloua (Cameroun)
Canada
 
  • Nova Scotia
    • Hants Co.
      • Cheverie
Boyle (1972)
  • Ontario
    • Leeds and Grenville Counties
      • Elizabethtown Township
Johnston (1915)
Ontario Ministry of Northern ... +1 other reference
    • Rainy River District
      • Freeborn Township
Personal Collection - Bill Morgenstern
Bill Morgenstern
Czech Republic
 
  • Central Bohemian Region
    • Beroun District
Palache et al. (1951)
Pauliš +4 other references
      • Hudlice
Vrtiška L. et al. (2018)
      • Olešná
Černý P. et al. (2015)
      • Zaječov
        • Svatá Dobrotivá (St Benigna)
Palache et al. (1951) +1 other reference
    • Kutná Hora District
      • Vlkaneč
Povondra et al. (eds.) +1 other reference
    • Rakovník District
      • Roztoky
Černý P (1)
  • Karlovy Vary Region
    • Sokolov District
      • Krásno
Sejkora et al. (2006)
        • Vysoký Kámen
Sejkora et al. (2006)
  • Pardubice Region
    • Pardubice District
Jirásek
  • Plzeň Region
    • Rokycany District
      • Těškov
Janouš +4 other references
Palache et al. (1951)
  • Vysočina Region
    • Jihlava District
      • Kamenice
        • Řehořov
Houzar S.: Přehled minerálů z ...
    • Pelhřimov District
      • Křeč
Vrtiška et al. (2017)
    • Žďár nad Sázavou District
      • Bory
Staněk (1970) +1 other reference
Staněk (1997)
DR Congo
 
  • Haut-Katanga
    • Lubumbashi
De Bondt (n.d.)
Europe
 
Berbain et al. (2012)
France
 
  • Auvergne-Rhône-Alpes
    • Allier
      • Vichy
        • Échassières
Chollet Pascal collection - Self ...
          • Montmins mining district
Yannick Vessely collection +1 other reference
            • Le Mazet
Pierre Le Roch & Jean-Marc Johannet ...
Cuchet et al. (2000)
    • Rhône
      • Villefranche-sur-Saône
        • Chessy
Coueille (1988)
  • Brittany
    • Côtes-d'Armor
      • Guingamp
        • Plélauff
Germain C. (1995)
    • Finistère
      • Quimper
        • Guilligomarc'h
Pierre Le Roch Collection
    • Morbihan
      • Pontivy
        • Le Roc Saint-André
Queneau (n.d.)
        • Plumelin
Le Roc'h P. ()
      • Vannes
        • Rochefort-en-Terre
Palache et al. (1951)
  • Nouvelle-Aquitaine
    • Corrèze
      • Ussel
        • Davignac
Bernard Barrière collection
    • Creuse
      • Aubusson
        • Soumans
          • Montebras
Queneau (n.d.)
      • Guéret
        • Crozant
M. Arliguie collection +1 other reference
    • Deux-Sèvres
      • Bressuire
        • Mauléon
          • La Chapelle-Largeau
Lièvre et al. (2002)
          • Le Temple
Lièvre et al. (2002)
        • Saint-Amand-sur-Sèvre
Lièvre et al. (2002)
    • Haute-Vienne
      • Bellac
        • Bessines-sur-Gartempe
perso.wanadoo.fr (2004)
Boisson (1988)
Alain Hanson Collection (gift from Michel Arliguie 9/2010)
        • Compreignac
          • Margnac Quarry
Patureau (2008)
        • Razès
          • Chanteloube
            • Vilatte Quarries (La Vilate)
Boisson (1988) +1 other reference
      • Limoges
        • Ambazac
Alain Hanson collection
        • Saint-Léonard-de-Noblat
Queneau P. (2001) +1 other reference
        • Saint-Sylvestre
Palache et al. (1951)
    • Pyrénées-Atlantiques
      • Bayonne
        • Arbouet-Sussaute
Pascale & Daniel Journet
  • Occitanie
    • Aveyron
      • Rodez
        • Florentin-la-Capelle
Laurent Gayraud collection
        • Pruines
Lheur (2023)
      • Villefranche-de-Rouergue
        • La Capelle-Bleys
Laurent Gayraud collection
        • Prévinquières
Jean-Marie LAURENT collection
    • Pyrénées-Orientales
      • Céret
        • Argelès-sur-Mer
Berbain et al. (2012)
        • Collioure
Berbain et al. (2012)
    • Tarn-et-Garonne
      • Castelsarrasin
Izaac da Silva Leite collection
    • Tarn
      • Castres
        • Fontrieu
          • Fumade
GAYRAUD (2010) +1 other reference
  • Pays de la Loire
    • Maine-et-Loire
      • Angers
        • St Jean des Mauvrets
Lièvre J.-M. & Pouit D. (2004)
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Ortenaukreis
        • Gengenbach
          • Gengenbach
Ko Jansen collection
        • Oberwolfach
Walenta (1992)
      • Waldshut
        • St Blasien
          • Menzenschwand
Walenta (1992)
    • Karlsruhe Region
      • Neckar-Odenwald-Kreis
        • Waldbrunn
          • Katzenbuckel
in the collection of Christof Schäfer
  • Bavaria
    • Lower Bavaria
      • Regen District
        • Zwiesel
          • Rabenstein
Palache et al. (1951) +2 other references
Obermüller et al. (1993)
    • Lower Franconia
      • Aschaffenburg District
        • Schöllkrippen
Lorenz (2003)
    • Upper Franconia
      • Bayreuth District
        • Mehlmeisel
58. +1 other reference
    • Upper Palatinate
      • Amberg-Sulzbach District
        • Auerbach in der Oberpfalz
          • Nitzlbuch (Nitzelbuch)
Dana 7:II:772
          • Schleichershof
Geipel (1982)
      • Amberg
von Voith (1836)
      • Cham District
        • Waldmünchen
          • Althütte
Fehr et al. (1985)
      • Neustadt an der Waldnaab District
        • Pleystein
Dill et al. (2009)
Dill et al. (2012)
Dill et al. (2008) +1 other reference
        • Waidhaus
www.mineralienatlas.de (n.d.) +2 other references
Weiß (1990)
web.archive.org (2001)
Kastning et al. (1996) +2 other references
      • Tirschenreuth District
        • Erbendorf
          • Grötschenreuth
Pöllmann et al. (2005)
        • Plößberg
Weiß (1990)
DILL et al. (2009)
      • Weiden in der Oberpfalz
        • Oedenthal
Weber (2013)
  • Hesse
    • Darmstadt
      • Bergstraße
        • Heppenheim
          • Kirschhausen
Wittern (2001)
      • Wetteraukreis
        • Rosbach vor der Höhe
          • Ober-Rosbach (Oberrosbach)
Kirnbauer (1984)
    • Giessen Region
      • Giessen
        • Biebertal
          • Fellingshausen
Palache et al. (1951) +1 other reference
          • Königsberg
Weiß (1990)
      • Lahn-Dill-Kreis
        • Braunfels
in the collection of Christof Schäfer
        • Lahnau
          • Waldgirmes
Palache et al. (1951) +1 other reference
      • Limburg-Weilburg
        • Weinbach
Blaß (2002)
  • North Rhine-Westphalia
    • Arnsberg
      • Hochsauerlandkreis
        • Arnsberg
          • Uentrop
Weiß (1990)
        • Bestwig
Blaß et al. (1998) +1 other reference
        • Sundern
          • Hellefeld
Wittern (2001)
      • Soest
        • Warstein
Stieglitz et al. (1987) +1 other reference
    • Düsseldorf
      • Wuppertal
        • Aprath castle
Emser Hefte 1988 (4)
  • Rhineland-Palatinate
    • Altenkirchen
      • Betzdorf-Gebhardshain
        • Kausen
Wittern (2001) +1 other reference
    • Rhein-Lahn-Kreis
      • Aar-Einrich
        • Mudershausen
www.mineralienatlas.de (2016)
  • Saxony-Anhalt
    • Harz
      • Oberharz am Brocken
        • Trautenstein
Gröbner et al. (2011)
  • Saxony
    • Erzgebirgskreis
      • Aue-Bad Schlema
Witzke (1992)
      • Ehrenfriedersdorf
Wittern (2001)
      • Raschau-Markersbach
        • Raschau
Martin (1994)
Lapis 30 (7/8)
    • Görlitz District
      • Kodersdorf
        • Rengersdorf
Witzke et al. (1997)
      • Neißeaue
Witzke et al. (2013)
    • Vogtlandkreis
      • Heinsdorfergrund
        • Hauptmannsgrün
Pestel et al. (2012)
      • Muldenhammer
        • Tannenbergsthal
          • Schneckenstein
Martin (1994)
    • Zwickau District
      • Lichtentanne
        • Stenn
www.mineralienatlas.de (2016)
  • Thuringia
    • Greiz District
      • Kauern
Witzke et al. (1998)
    • Saale-Orla District
      • Bad Lobenstein
Wittern (2001)
      • Hirschberg
        • Ullersreuth
Witzke et al. (2001)
Greece
 
  • South Aegean
    • Milos
Frenzel (1895)
Hungary
 
  • Borsod-Abaúj-Zemplén County
    • Kazincbarcika District
NAGY et al. (2000)
Szakáll: Minerals of Rudabánya
    • Miskolc District
Zajzon N et al. (20014)
      • Miskolc
        • Diósgyőr
GEODA
    • Nekézseny
Szakáll et al. (1996)
Ireland
 
  • Munster
    • Limerick County
Ryback et al. (1988)
Italy
 
  • Liguria
    • Savona Province
      • Magliolo
Castellaro-Kampf
      • Vado Ligure
Marco Ciriotti 2010
Gianluca Armellino et al. (2024) +1 other reference
  • Piedmont
    • Verbano-Cusio-Ossola Province
      • Vanzone con San Carlo
Mattioli (1979) +1 other reference
  • Sardinia
    • Metropolitan City of Cagliari
      • Capoterra
Olmi F.
      • Pula
Bortolozzi (n.d.)
      • Sarroch
Luigi Chiappino data +1 other reference
      • Villa San Pietro
I. Campostrini personal comunication
Japan
 
  • Hyogo Prefecture
    • Kobe city
      • Nishi-ku
Yamada (2004)
S. Matsubara (2000)
  • Kochi Prefecture
    • Kochi City
      • Toyoda
Yamada (2004)
  • Kyoto Prefecture
    • Soraku District
      • Wazuka-cho
SHIMOBAYASHI et al. (2012)
  • Nagano Prefecture
    • Chino City
Kitahara (1949)
  • Shizuoka Prefecture
    • Shimoda City
      • Rendaiji
Takashi Yamada et al. (1999)
  • Tochigi Prefecture
    • Nikko City
      • Imaichi
Esaka collection +1 other reference
Mali
 
  • Sikasso Region
    • Kadiolo Cercle
Gineste (2012)
Mexico
 
  • Durango
    • Indé Municipality
Michael Shannon specimens
Morocco
 
  • Marrakesh-Safi Region
    • Rehamna Province
      • Sidi Bou Othmane Cercle
        • Jebilet Mountain (Djebilet Mountain)
          • Sidi Bou Othmane
Favreau (2012)
Namibia
 
  • Erongo Region
    • Karibib Constituency
      • Okatjimukuju Farm 55 (Friedrichsfelde Farm)
Keller et al. (1989)
New Zealand
 
  • Tasman Region
    • Glenhope
Stott (pers. notes)
Poland
 
  • Lower Silesian Voivodeship
    • Złotoryja County
      • Gmina Świerzawa
        • Sędziszowa
Lis et al. (1986)
Portugal
 
  • Bragança
    • Torre de Moncorvo
      • Felgar e Souto da Velha
luigi chiappino specimen
Alves (n.d.)
  • Castelo Branco
    • Vila Velha de Ródão
      • Vila Velha de Ródão
Martins da Pedra collection +1 other reference
  • Coimbra
    • Góis
      • Cadafaz e Colmeal
Artur Neves' collection - August 2014
  • Évora
    • Alandroal
      • Alandroal (Nossa Senhora da Conceição), São Brás dos Matos (Mina do Bugalho) e Juromenha (Nossa Senhora do Loreto)
        • São Brás dos Matos
Rui Nunes visit 18 July 2015
    • Évora
      • São Bento do Mato
        • Azaruja
Nunes (n.d.)
    • Vila Viçosa
      • Nossa Senhora da Conceição e São Bartolomeu
  • Guarda
    • Gouveia
      • Folgosinho
Alves (n.d.)
    • Guarda
      • Vela
Pedro Alves collection. Characterized ...
    • Sabugal
      • Bendada
Schnorrer-Köhler et al. (1991)
Alves (n.d.)
  • Viana do Castelo
    • Caminha
      • Arga de Baixo
    • Ponte da Barca
      • Touvedo (São Lourenço e Salvador)
Self-collected by Pedro Alves.
    • Ponte de Lima
      • Cabração e Moreira do Lima
Alves (n.d.)
        • Moreira do Lima
    • Vila Nova de Cerveira
      • Covas
Alves (n.d.)
  • Viseu
    • Mangualde
      • Mangualde (Mesquitela e Cunha Alta)
Mineralien Atlas
      • Tavares (Chãs; Várzea e Travanca)
        • Corvaceira
    • Sátão
      • Ferreira de Aves
        • Aldeia Nova
Rui Nunes 2011
    • Vila Nova de Paiva
Identified in Rebentão Mine
      • Queiriga
        • Lagares do Estanho Mines
self-find
Romania
 
  • Maramureș County
    • Târgu Lăpuș
minerals-of-the-carpathians.eu (2008) +1 other reference
Rwanda
 
  • Western Province
    • Ngororero District
      • Muhororo
Bertossa (1968) +1 other reference
Slovakia
 
  • Banská Bystrica Region
    • Revúca District
      • Sirk
Martin Števko & Dušan ...
South Africa
 
  • Gauteng
    • City of Tshwane Metropolitan Municipality
Atanasova et al. (2016)
  • Mpumalanga
    • Nkangala District Municipality
      • Victor Khanye Local Municipality
        • Delmas
Woolf (2023)
            • Dwarsfontein Farm
              • Transvaal Mine
SAMS (South African Micromount Society)
Spain
 
  • Andalusia
    • Córdoba
      • Torrecampo
Christian Rewitzer collection - SEM-EDS ...
    • Jaén
      • Andújar
mti-minas-andalucia.blogspot.com (n.d.)
  • Castile-La Mancha
    • Ciudad Real
      • Almodóvar del Campo
Sáinz de Baranda et al. (2004)
www.foro-minerales.com (2022) +1 other reference
  • Catalonia
    • Barcelona
      • Baix Llobregat
        • Gavà
          • Bruguers
Bareche (2005)
  • Extremadura
    • Badajoz
      • La Haba
www.foro-minerales.com (n.d.)
www.foro-minerales.com (n.d.)
      • Quintana de la Serena
www.foro-minerales.com (n.d.)
      • Tejeda de Tiétar
Cesar Menor Salvan
Nunes (n.d.) +1 other reference
Viñals et al. (2011)
  • Galicia
    • A Coruña
      • Arteixo
Miguel Calvo Rebollar (2015)
    • Ourense
      • Valdeorras
        • Villamartín de Valdeorras
          • Robledo
Miguel Calvo Rebollar (2015)
    • Pontevedra
      • Gondomar
        • Vincios
          • Galiñeiro Complex
NÚÑEZ-GARCÍA et al. (2012) +1 other reference
      • Moaña
Vérez et al. (2024)
      • Tomiño
Calvo Rebollar (2015)
  • Murcia
    • La Unión
  • Navarre
    • Esteríbar
      • Eugui
Calvo et al. (2003)
Sweden
 
  • Norrbotten County
    • Kiruna
      • Kiruna Town Mining District
Palache et al. (1951)
      • Svappavaara
Bjällerud (1989) +1 other reference
Switzerland
 
  • Ticino
    • Locarno
      • Brissago
EDXS analyses
UK
 
  • England
    • Cornwall
      • Carn Brea
        • Carnkie
          • Basset Mines
George Eric Stanley Curtis collection
      • Kea
Lapis 11 (2) +1 other reference
      • Lezant
Golley et al. (1995)
      • Linkinhorne
        • Minions
Golley et al. (1995)
Richard Bell personal collection
      • St Columb Major
        • Castle-an-Dinas
Ryback et al. (1988) +1 other reference
      • Treverbyn
        • Stenalees
Golley et al. (1995) +3 other references
    • Cumbria
      • Allerdale
        • Caldbeck
          • Coombe Height
Hartley (1984) +2 other references
Stanley et al. (1991)
    • Devon
      • North Devon
        • Bishop's Tawton
Steve Rust collection
Alysson Rowan collection
  • Wales
    • Swansea
      • Pennard
Uruguay
 
  • Artigas Department
    • Tres Cerros de Santiño
Fabre (n.d.)
USA
 
  • Alabama
    • Calhoun County
      • Jacksonville
Barwood et al. (1978) +1 other reference
Rocks & Min.: 58:57-62. +1 other reference
    • Cherokee County
Henry Barwood
Rocks & Min.: 64:203. +1 other reference
Cook et al. (1982)
      • Rock Run
Simkev Micromounts Collection
        • Wolfden Mountain
Dean (1995)
Dean (1995)
    • Coosa County
      • Rockford Mining District
        • Two Bit pegmatite
Dean (1995)
Rocks & Minerals: 70 (5)
    • Shelby County
      • Alabaster
chris bryant +1 other reference
    • St. Clair County
Cook et al. (1982)
    • Tuscaloosa County
      • Woodstock Mining District
        • Woodstock
Dean (1995)
  • Alaska
    • Valdez-Cordova Census Area
      • Chisana Mining District
U. S. Geological Survey Open-File ...
  • Arizona
    • Pima County
      • Silver Bell Mountains
        • Silver Bell Mining District
          • Mineral Mountain
            • Silver Bell Mine
Anthony et al. (1995)
Anthony et al. (1995)
  • Arkansas
    • Garland County
      • Avant
        • Dug Hill
Arthur E. Smith (2008)
      • Wilson Springs (Potash Sulfur Springs)
        • Union Carbide Mine
R&M 70:3 pp 154-170
Howard +1 other reference
R&M 70:3 pp 154-170
    • Hot Spring County
      • Magnet Cove
Henry Barwood - unpublished (2010)
Rocks & min.: 64:297.
Rocks & Min.: 63:109.
    • Montgomery County
      • North Mountain
Rocks & Min.: 63: 113. +2 other references
Howard (2007)
    • Polk County
      • Big Fork
Rocks & Min.:63:118.
Smith (1988)
      • Gilham
Smith (1988)
        • Porter Mountain
Rocks & Min.: 63:120.
      • Shady
Rocks & Min.:64:297-298.
Am Min 51:1811-1814
Smith (1988)
      • Three Oak Gap
Smith (1988)
  • California
    • El Dorado County
      • Slate Mountains
        • Slate Mountain District
          • Slate Mountain
Pemberton (1983) +2 other references
  • Colorado
    • Teller County
      • Cripple Creek Mining District
Carnein et al. (2005)
Blanchard et al. (1968)
    • Polk County
      • Central Florida Phosphate Mining District (Bone Valley)
        • Homeland
Min News 21:8 pp 1 +1 other reference
        • Noralyn/Phosphoria Mines (IMC-Agrico)
Marc V. Hurst (2012)
Kelley Collection
Am Min 53:2096-2101
  • Georgia
    • Bartow County
      • Cartersville Mining District
Rocks & Min.: 64:185.
      • Emerson
Cook (1978)
    • Burke County
      • Girard District
Jason Smith & M.E. Ciriotti (2005)
    • Lincoln County
Barwood (1999) +1 other reference
    • Murray County
Cook (1978)
    • Polk County
      • Cedartown
Rocks & Min.: 21:347 +1 other reference
Rocks & Minerals 54:4 pp161-165
  • Idaho
    • Caribou County
      • Soda Springs
Kampf et al. (2013)
  • Maryland
    • Baltimore City
Ostrander et al. (1940)
    • Charles County
Paul P.Hearn et al. (1988)
    • Prince Georges County
Bernstein (1976)
  • Missouri
    • Crawford County
      • Steelville
Dana 6:1083.
  • Nevada
    • Eureka County
      • Carlin Trend
        • Maggie Creek Mining Subdistrict
Jensen et al. (1995)
      • Lynn Mining District
        • Elko
Jensen et al. (1995)
Castor et al. (2004)
    • Humboldt County
      • Buffalo Mountain Mining District
Castor et al. (2004)
      • Iron Point Mining District
        • Valmy
Silver Coin Mine. Compact Disc. Paul ...
    • Lander County
      • Simpson Park Mountains
Collected by and in the collection of ...
    • Lyon County
      • Singatse Range
        • Yerington Mining District
Collected by Dick Thomssen.
Castor et al. (2004)
Castor et al. (2004)
          • Yerington
Jeremy Zolan
      • Talapoosa Mining District
Castor et al. (2004)
    • Mineral County
      • Candelaria Mining District
        • Candelaria Silver Mine
Collection of Kelly Starnes 1990
      • Rawhide Mining District
Castor et al. (2004)
    • Nye County
      • San Antonio Mountains
        • Tonopah Mining District
Castor et al. (2004)
    • Pershing County
      • Willard Mining District
Wilson et al. (2008)
  • New Hampshire
    • Grafton County
      • Groton
Moore (1973)
    • Hillsborough County
      • Deering
Smith (2005)
  • New Jersey
    • Gloucester County
      • Harrison Township
Henderson (1980)
Locality description: "[...] all the ...
    • Monmouth County
      • Upper Freehold Township
        • Arneytown
C.G.Segeler (personal communication)
  • New Mexico
    • Doña Ana County
      • Organ Mountains
        • Organ Mining District
See specimen ...
    • Grant County
      • Burro Mountains Mining District
        • Tyrone Area
D.Court collection +1 other reference
    • Hidalgo County
      • Pyramid Mountains
        • Lordsburg Mining District
          • Lordsburg
            • Virginia District
Walstrom (n.d.)
  • New York
    • Jefferson County
Palache et al. (1951)
  • North Carolina
    • Alamance County
      • Snow Camp
Rocks & Min.: 60:84. +1 other reference
    • Cleveland County
      • Kings Mountain
Rocks & Minerals: 60 (2) +1 other reference
    • Moore County
      • Glendon Mining District
Kenny Gay personal message
    • Orange County
      • Hillsborough
www.mindat.org/mesg-11-168140.html
  • Pennsylvania
    • Cumberland County
      • Mount Holly Springs
Palache et al. (1951) +1 other reference
    • Lancaster County
      • Fulton Township
Lapham et al. (1965)
      • Little Britain Township
        • Texas
Lapham et al. (1965)
      • Salisbury Township
        • Gap
Dana 6: 1069 +1 other reference
    • Montgomery County
      • Whitemarsh Township
Sloto (2019)
    • Northampton County
      • Lower Saucon Township
Palache et al. (1951)
Henderson (1980)
    • Snyder County
      • Middlecreek Township
Min. Col. PA +2 other references
      • Perry Township
        • Mount Pleasant Mills
          • Lime Ridge
K. Cabaniss & L.E. Kearns (2011)
    • Union County
      • Winfield
  • South Carolina
    • Abbeville County
      • Antreville
Steve Stuart specimen
    • Cherokee County
      • Kings Creek Mining District
        • Kings Creek Mine
Rocks & Minerals 54:4 pp173-175
  • South Dakota
    • Custer County
      • Custer Mining District
        • Custer
Seaman (1976)
Loomis (2011)
    • Pennington County
      • Keystone Mining District
        • Keystone
Rocks & Minerals: 67 (6)
  • Tennessee
    • Wayne County
      • Iron City
Paris (2011)
  • Virginia
    • Pittsylvania County
Dietrich (1990)
    • Rockbridge County
      • Lyndhurst-Vesuvius Mining District
Rocks & Min.:64:42-45 (also see Rocks & Min.:57:20-22 & 60:168) +1 other reference
Dietrich (1990)
Rocks & Min.: 57:20-22 +1 other reference
      • Midvale
        • South Mountain
Dietrich (1990)
  • Wisconsin
    • Jackson County
Klemic et al. (1972) +1 other reference
 
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