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Fluorapophyllite-(Na)

A valid IMA mineral species
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About Fluorapophyllite-(Na)Hide

Formula:
NaCa4(Si8O20)F · 8H2O
Colour:
Brownish-yellow, yellowish-brown, colourless
Lustre:
Vitreous, Pearly
Hardness:
4 - 5
Specific Gravity:
2.50
Crystal System:
Orthorhombic
Name:
From the Greek for "away from" (ἀπό, apo) and "leaf" (φύλλον, phyllos), in allusion to the way it exfoliates upon heating. The "-(NaF)" suffix documents the dominant and distinctive components in this member of the Apophyllite family (sodium and fluoride).

The mineral name changed from apophyllite-(NaF) to fluorapophyllite-(Na) (Hatert et al. 2013)
This page provides mineralogical data about Fluorapophyllite-(Na).


Unique IdentifiersHide

Mindat ID:
2851
Long-form identifier:
mindat:1:1:2851:2

IMA Classification of Fluorapophyllite-(Na)Hide

Classification of Fluorapophyllite-(Na)Hide

9.EA.15

9 : SILICATES (Germanates)
E : Phyllosilicates
A : Single nets of tetrahedra with 4-, 5-, (6-), and 8-membered rings
72.3.1.3

72 : PHYLLOSILICATES Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings
3 : Two-Dimensional Infinite Sheets with Other Than Six-Membered Rings with 3-, 4-, or 5-membered rings and 8-membered rings
17.1.4

17 : Silicates Containing other Anions
1 : Silicates with fluoride (not containing Al)

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
Fapo-NaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
FapoThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of Fluorapophyllite-(Na)Hide

Vitreous, Pearly
Colour:
Brownish-yellow, yellowish-brown, colourless
Streak:
Light gray
Hardness:
4 - 5 on Mohs scale
Cleavage:
Perfect
perfect on {001} and poor on {110}
Density:
2.50 g/cm3 (Measured)    2.30 g/cm3 (Calculated)

Optical Data of Fluorapophyllite-(Na)Hide

Type:
Biaxial (+)
RI values:
nα = 1.536 nβ = 1.538 nγ = 1.544
2V:
Measured: 32° , Calculated: 62°
Max. Birefringence:
δ = 0.008
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate
Dispersion:
r < v strong

Chemistry of Fluorapophyllite-(Na)Hide

Mindat Formula:
NaCa4(Si8O20)F · 8H2O
Element Weights:
Element% weight
O50.273 %
Si25.214 %
Ca17.991 %
Na2.580 %
F2.132 %
H1.810 %

Calculated from ideal end-member formula.
Common Impurities:
K

Crystallography of Fluorapophyllite-(Na)Hide

Crystal System:
Orthorhombic
Cell Parameters:
a = 8.875(4) Å, b = 8.881(6) Å, c = 15.79(1) Å
Ratio:
a:b:c = 0.999 : 1 : 1.778
Unit Cell V:
1,244.55 ų (Calculated from Unit Cell)
Z:
2
Comment:
space group : Pnnm or Pnn2

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000830Fluorapophyllite-(Na)Miura Y, Kato T, Rucklidge J C, Matsueda H (1981) Natroapophyllite, a new orthorhombic sodium analog of apophyllite II. Crystal structure American Mineralogist 66 410-4231981the Sampo mine, Okayama, Japan0293
CIF Raw Data - click here to close

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4a: Earth’s earliest continental crust>4.4-3.0
19 : Granitic intrusive rocks
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Stage 5: Initiation of plate tectonics<3.5-2.5
40 : Regional metamorphism (greenschist, amphibolite, granulite facies)

Type Occurrence of Fluorapophyllite-(Na)Hide

Synonyms of Fluorapophyllite-(Na)Hide

Other Language Names for Fluorapophyllite-(Na)Hide

Relationship of Fluorapophyllite-(Na) to other SpeciesHide

Other Members of Apophyllite Group:
Fluorapophyllite-(Cs)CsCa4(Si8O20)F · 8H2OTet.
Fluorapophyllite-(K)KCa4(Si8O20)(F,OH) · 8H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mnc
Fluorapophyllite-(NH4)NH4Ca4(Si8O20)F · 8H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mnc
Hydroxyapophyllite-(K)KCa4(Si8O20)(OH,F) · 8H2OTet. 4/mmm (4/m 2/m 2/m)
Hydroxymcglassonite-(K)KSr4Si8O20(OH) · 8H2OTet.

Common AssociatesHide

Associated Minerals Based on Photo Data:
2 photos of Fluorapophyllite-(Na) associated with HubeiteCa2Mn2+Fe3+Si4O12(OH) · 2H2O
2 photos of Fluorapophyllite-(Na) associated with InesiteCa2(Mn,Fe)7Si10O28(OH)2 · 5H2O
2 photos of Fluorapophyllite-(Na) associated with AnalcimeNa(AlSi2O6) · H2O
1 photo of Fluorapophyllite-(Na) associated with WollastoniteCa3(Si3O9)
1 photo of Fluorapophyllite-(Na) associated with Stilbite SubgroupM6-7[Al8-9Si27-28O72] · nH2O
1 photo of Fluorapophyllite-(Na) associated with ScoleciteCaAl2Si3O10 · 3H2O

Related Minerals - Strunz-mindat GroupingHide

9.EA.Hydroxymcglassonite-(K)KSr4Si8O20(OH) · 8H2OTet.
9.EA.Miyawakiite-(Y)◻Y4Fe2(Si8O20)(CO3)4(H2O)3Tet. 4/mmm (4/m 2/m 2/m) : I4/mcm
9.EA.Bussyite-(Y)(Y,REE,Ca)3(Na,Ca)6MnSi9Be5(O,OH,F)34Mon. 2 : B2
9.EA.Fluorapophyllite-(NH4)NH4Ca4(Si8O20)F · 8H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mnc
9.EA.05GillespiteBaFe2+Si4O10Tet. 4/mmm (4/m 2/m 2/m) : P4/ncc
9.EA.05CuprorivaiteCaCuSi4O10Tet. 4/mmm (4/m 2/m 2/m) : P4/ncc
9.EA.05WesselsiteSrCuSi4O10Tet. 4/mmm (4/m 2/m 2/m) : P4/ncc
9.EA.05EffenbergeriteBaCuSi4O10Tet. 4/mmm (4/m 2/m 2/m) : P4/ncc
9.EA.07Fluorapophyllite-(Cs)CsCa4(Si8O20)F · 8H2OTet.
9.EA.10EkaniteCa2ThSi8O20Tet. 4 2 2 : I4 2 2
9.EA.15Fluorapophyllite-(K)KCa4(Si8O20)(F,OH) · 8H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mnc
9.EA.15Hydroxyapophyllite-(K)KCa4(Si8O20)(OH,F) · 8H2OTet. 4/mmm (4/m 2/m 2/m)
9.EA.20MagadiiteNa2Si14O29 · 11H2OOrth. mm2 : Fdd2
9.EA.25DalyiteK2ZrSi6O15Tric. 1 : P1
9.EA.25DavaniteK2TiSi6O15Tric.
9.EA.30Sazhinite-(La)Na3La[Si6O15] · 2H2OOrth. mm2 : Pmm2
9.EA.30Sazhinite-(Ce)Na3CeSi6O15 · 2H2OOrth. mm2 : Pmm2
9.EA.35ArmstrongiteCaZr[Si6O15] · 3H2OMon. 2/m : B2/m
9.EA.40OkeniteCa10Si18O46 · 18H2OTric. 1 : P1
9.EA.45Perettiite-(Y)Y2Mn4FeSi2B8O24Orth. mmm (2/m 2/m 2/m) : Pmna
9.EA.45NekoiteCa3Si6O15 · 7H2OTric. 1 : P1
9.EA.45Badakhshanite-(Y)Y2Mn4Al(Si2B7BeO24)Orth. mmm (2/m 2/m 2/m) : Pnma
9.EA.47ShlykoviteKCa[Si4O9(OH)] · 3H2OMon. 2/m : P21/b
9.EA.50DiegogattaiteNa2CaCu2Si8O20 · H2OMon. 2/m : B2/m
9.EA.50CavansiteCa(VO)Si4O10 · 4H2OOrth. mmm (2/m 2/m 2/m)
9.EA.52YangitePbMnSi3O8 · H2OTric. 1 : P1
9.EA.55PentagoniteCa(VO)Si4O10 · 4H2OOrth. mm2
9.EA.60PenkvilksiteNa4Ti2Si8O22 · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbcn
9.EA.60TumchaiteNa2Zr(Si4O11) · 2H2OMon. 2/m : P21/b
9.EA.65NabesiteNa2BeSi4O10 · 4H2OOrth. 2 2 2 : P21 21 21
9.EA.70Ajoite(K,Na)Cu7AlSi9O24(OH)6 · 3H2OTric.
9.EA.75ZeravshaniteNa2Cs4Zr3[Si18O45]*2H2OMon. 2/m : B2/b
9.EA.80Bussyite-(Ce)(Ce,REE)3(Na,H2O)6MnSi9Be5(O,OH)30F4Mon. 2/m : B2/b
9.EA.85PlumbophyllitePb2Si4O10 · H2OOrth. mmm (2/m 2/m 2/m) : Pbcn

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Fluorapophyllite-(Na)Hide

References for Fluorapophyllite-(Na)Hide

Localities for Fluorapophyllite-(Na)Hide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Tasmania
    • Huon Valley municipality
Bottrill et al. (2008)
Canada
 
  • Nova Scotia
    • Kings Co.
Pe-Piper (2000)
China
 
  • Hubei
    • Huangshi
      • Daye Co.
Hawthorne et al. (2002)
Finland
 
  • Southwest Finland
    • Laitila
Hietala
Italy
 
  • Trentino-Alto Adige (Trentino-South Tyrol)
    • South Tyrol
Simone Citon collection
Japan (TL)
 
  • Okayama Prefecture
    • Takahashi City
      • Bitchū
        • Shitouyouze
Matsueda et al. (1981)
Namibia
 
  • Khomas Region
    • Windhoek Rural
      • Aris
Warta et al. (2006)
UK
 
  • Northern Ireland
    • Co. Antrim
      • Templepatrick
www.excaliburmineral.com
USA
 
  • Nevada
Castor et al. (2004)
    • Humboldt County
      • Osgood Mountains
        • Potosi Mining District
          • Adam Peak
Castor et al. (2004)
  • New Jersey
    • Sussex County
      • Franklin
John Cianciulli
EDS by Joy Desor showed essentially no ...
  • Oregon
    • Benton County
      • Coffin Butte
 
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