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Kutinaite

A valid IMA mineral species
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About KutinaiteHide

08906370017271924541358.jpg
Jan Kutina
Formula:
Ag6Cu14As7
Bindi & Makovicky (2015) suggest the formula (K,Tl)0.25Cu14Ag6As6.75.
Originally assumed to be Cu2AgAs.
Colour:
Silver gray
Lustre:
Metallic
Hardness:
Specific Gravity:
8.38
Crystal System:
Isometric
Name:
Named in 1970 by J. Hak, Z. Johan, and Brian J. Skinner in honor of Dr. Jan Kutina (1924, Prague - 14 August 2008, Maryland, USA), geologist. He held academic positions at the Charles University in Prague and in the USA and Japan. His specialty was ore deposits and metallogenic research.
Restudy of the type material is necessary (Bindi & Makovicky, 2015).


Unique IdentifiersHide

Mindat ID:
2298
Long-form identifier:
mindat:1:1:2298:5

IMA Classification of KutinaiteHide

Classification of KutinaiteHide

2.AA.25

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
A : Alloys
A : Alloys of metalloids with Cu, Ag, Au
2.2.2.2

2 : SULFIDES
2 : AmBnXp, with (m+n):p = 3:1
1.40

1 : Elements and Alloys (including the arsenides, antimonides and bismuthides of Cu, Ag and Au)

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
KtiIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KutinaiteHide

Metallic
Transparency:
Opaque
Colour:
Silver gray
Hardness:
4½ on Mohs scale
Hardness:
VHN25=237 - 270 kg/mm2 - Vickers
Tenacity:
Malleable
Density:
8.38(7) g/cm3 (Measured)    8.400 g/cm3 (Calculated)
Comment:
Measured on synthetic material

Optical Data of KutinaiteHide

Type:
Isotropic
Reflectivity:
WavelengthR1 (%)
400nm49.6%
440nm48.0%
480nm45.6%
520nm43.5%
560nm42.0%
600nm41.1%
640nm40.5%
680nm40.5%
700nm40.9%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 49.6%.
Colour in reflected light:
grayish white to pale blue-gray

Chemistry of KutinaiteHide

Mindat Formula:
Ag6Cu14As7

Bindi & Makovicky (2015) suggest the formula (K,Tl)0.25Cu14Ag6As6.75.
Originally assumed to be Cu2AgAs.
Element Weights:
Element% weight
Cu43.159 %
Ag31.398 %
As25.443 %

Calculated from ideal end-member formula.

Crystallography of KutinaiteHide

Crystal System:
Isometric
Class (H-M):
m3m (4/m 3 2/m) - Hexoctahedral
Cell Parameters:
a = 11.78079(2) Å
Unit Cell V:
1,635.02 ų (Calculated from Unit Cell)
Z:
4
Comment:
Space Group: Pm3m. synthetic

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005793KutinaiteKaranovic L, Poleti D, Makovicky E, Balic-Zunic T, Makovicky M (2002) The crystal structure of synthetic kutinaite, Cu14Ag6As7 The Canadian Mineralogist 40 1437-144920020293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.259 Å(100)
2.078 Å(100)
2.702 Å(90)
2.398 Å(80)
1.991 Å(70)
1.959 Å(70)
1.776 Å(70)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of KutinaiteHide

Synonyms of KutinaiteHide

Other Language Names for KutinaiteHide

Dutch:Kutinaiet
Simplified Chinese:方砷铜银矿
Spanish:Kutínaita
Traditional Chinese:方砷銅銀礦

Related Minerals - Strunz-mindat GroupingHide

2.AA.TrigodomeykiteCu3-xAsTrig. 3 : P3
2.AA.10bDomeykiteCu3AsIso. 4 3m : I4 3d
2.AA.10aAlgodonite(Cu1-xAsx)Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
2.AA.10dKoutekiteCu5As2Hex.
2.AA.15Novákite(Cu,Ag)21As10Mon.
2.AA.20CuprostibiteCu2(Sb,Tl)Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm
2.AA.30Allargentum(Ag1-xSbx)Hex.
2.AA.35DyscrasiteAg3SbOrth. mm2 : Pmm2
2.AA.40MaldoniteAu2BiIso. m3m (4/m 3 2/m) : Fd3m
2.AA.45StistaiteSnSbTrig. 3m (3 2/m) : R3m
2.AA.50ZaccariniiteRhNiAs Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm
2.AA.55DieneriteNi3AsIso. 4 3m : I4 3d

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KutinaiteHide

References for KutinaiteHide

Localities for KutinaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Northwest Territories
    • Great Slave Lake
Harris et al. (1985)
Czech Republic
 
  • Central Bohemian Region
    • Příbram District
      • Háje
Sejkora et al. (2022)
  • Hradec Králové Region
    • Trutnov District
Amer. Min. (1970) +2 other references
France
 
  • Grand Est
    • Haut-Rhin
      • Thann-Guebwiller
        • Sewen
Picot et al. (1978)
Picot et al. (1978)
  • Occitanie
    • Hérault
      • Lodève
        • Le Puech
Germany
 
  • Hesse
    • Darmstadt
      • Darmstadt-Dieburg
        • Mühltal
          • Nieder-Beerbach
Belendorff (1986) +1 other reference
Iran
 
  • Isfahan Province
    • Nain County
      • Anarak District
Anthony et al. (1990)
Khoshnoodi et al. (2025)
Kazakhstan
 
  • Ulytau Region
    • Zhanaarka District
Sal'kov +1 other reference
 
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