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Klebelsbergite

A valid IMA mineral species - grandfathered
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About KlebelsbergiteHide

00366640017271924412892.jpg
Kuno von Klebelsberg
Formula:
Sb4O4(SO4)(OH)2
Colour:
Dark yellow; colourless to yellow in transmitted light.
Lustre:
Vitreous, Silky
Hardness:
3½ - 4
Specific Gravity:
4.62
Crystal System:
Orthorhombic
Name:
After Kuno von Klebelsberg (1875-1932), formerly the Hungarian Minister of Education.
The Sb analogue of tavagnascoite.


Unique IdentifiersHide

Mindat ID:
2223
Long-form identifier:
mindat:1:1:2223:7

IMA Classification of KlebelsbergiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Sb3+4O4(SO4)(OH)2

Classification of KlebelsbergiteHide

7.BB.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
B : With medium-sized cations
30.1.5.1

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p>2:1
25.8.1

25 : Sulphates
8 : Sulphates of Sb, V, Cr and U

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
KbbIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KlebelsbergiteHide

Vitreous, Silky
Transparency:
Transparent
Colour:
Dark yellow; colourless to yellow in transmitted light.
Streak:
White to yellow
Hardness:
3½ - 4 on Mohs scale
Hardness:
VHN10=200 kg/mm2 - Vickers
Tenacity:
Brittle
Density:
4.62(6) g/cm3 (Measured)    4.68(1) g/cm3 (Calculated)

Optical Data of KlebelsbergiteHide

Type:
Biaxial (-)
Dispersion:
relatively weak
Pleochroism:
Non-pleochroic

Chemistry of KlebelsbergiteHide

Mindat Formula:
Sb4O4(SO4)(OH)2
Element Weights:
Element% weight
Sb71.506 %
O23.490 %
S4.708 %
H0.296 %

Calculated from ideal end-member formula.

Crystallography of KlebelsbergiteHide

Crystal System:
Orthorhombic
Class (H-M):
mm2 - Pyramidal
Cell Parameters:
a = 11.279(2) Å, b = 14.909(3) Å, c = 5.7648(6) Å
Ratio:
a:b:c = 0.757 : 1 : 0.387
Unit Cell V:
969.40 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Occurs as tufts of tiny, acicular crystals elongated [001] and flattened {010}. Forms include: {001}, {010}, {110}, {101}, and {101}
Comment:
Space Group: P c21b.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000795KlebelsbergiteManchetti S, Sabelli C (1980) The crystal structure of klebelsbergite Sb4O4(OH)2SO4 American Mineralogist 65 931-93519800293
0020337KlebelsbergiteRoper A J, Leverett P, Murphy T D, Williams P A, Hibbs D E (2015) Klebelsbergite, Sb4O4SO4(OH)2: Stability relationships, formation in nature, and refinement of its structure American Mineralogist 100 602-6072015Synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.131 Å(vs)
6.22 Å(s)
3.892 Å(s)
3.545 Å(s)
3.150 Å(s)
2.830 Å(s)
2.435 Å(s)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]
Geological Setting:
Oxidation zone of antimony deposits.

Type Occurrence of KlebelsbergiteHide

Place of Conservation of Type Material:
Hungarian Natural History Museum, Budapest, Hungary, A85135; National Museum of Natural History, Washington, D.C., USA, R6365, B12631, B12640, B12647, 137949.
Geological Setting of Type Material:
Oxidation zone in stibnite deposit.
Associated Minerals at Type Locality:

Other Language Names for KlebelsbergiteHide

Relationship of Klebelsbergite to other SpeciesHide

Other Members of Klebelsbergite Group:
TavagnascoiteBi4O4(SO4)(OH)2Orth. mm2 : Pca21

Common AssociatesHide

Associated Minerals Based on Photo Data:
107 photos of Klebelsbergite associated with StibniteSb2S3
24 photos of Klebelsbergite associated with MetastibniteSb2S3
23 photos of Klebelsbergite associated with Native SulphurS8
22 photos of Klebelsbergite associated with PeretaiteCa(SbO)4(SO4)2(OH)2 · 2H2O
9 photos of Klebelsbergite associated with QuartzSiO2
7 photos of Klebelsbergite associated with SphärosideriteFeCO3
5 photos of Klebelsbergite associated with CalciteCaCO3
5 photos of Klebelsbergite associated with StibiconiteSb3+Sb5+2O6(OH)
3 photos of Klebelsbergite associated with CoquanditeSb6+xO8+x(SO4)(OH)x(H2O)1- x (x = 0.3)
3 photos of Klebelsbergite associated with KermesiteSb2S2O

Related Minerals - Strunz-mindat GroupingHide

7.BB.IskandaroviteSb6O7(SO4)2Orth. mm2 : Ccc2
7.BB.BrumadoiteCu3(Te6+O4)(OH)4 · 5H2OMon. 2/m : P21/m
7.BB.Novikovite(NH4)4Mo6+2Mo5+2O8(SO4)5Mon. 2/m
7.BB.10HauckiteFe3+3(Mg,Mn2+)24Zn18(SO4)4(CO3)2(OH)81Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
7.BB.15AntleriteCu3(SO4)(OH)4Orth. mmm (2/m 2/m 2/m)
7.BB.20DolerophaniteCu2(SO4)OMon. 2/m : B2/m
7.BB.25BrochantiteCu4(SO4)(OH)6Mon. 2/m : P21/b
7.BB.25RamaccioniiteCu4[SeO4](OH)6Mon. 2/m : P21/b
7.BB.30VergasovaiteCu3(SO4)(MoO4,SO4)OOrth. mmm (2/m 2/m 2/m)
7.BB.30CupromolybditeCu3O(MoO4)2Orth. mmm (2/m 2/m 2/m) : Pnma
7.BB.35TavagnascoiteBi4O4(SO4)(OH)2Orth. mm2 : Pca21
7.BB.40SchuetteiteHg2+3(SO4)O2Trig. 3 2 : P31 2 1
7.BB.45ParaotwayiteNi(OH)2-x(SO4,CO3)0.5xMon.
7.BB.50XocomecatliteCu3(TeO4)(OH)4Orth.
7.BB.55Pauflerite(V4+O)SO4Orth. mmm (2/m 2/m 2/m) : Pnma
7.BB.60GrandviewiteCu3Al2(SO4)(OH)10 · H2OTric. 1 : P1
7.BB.65TimroseitePb2Cu5(TeO6)2(OH)2Orth. mm2 : Pmn21
7.BB.70GlikiniteZn3O(SO4)2Mon. 2/m : P21/m
7.BB.80MojaveiteCu6[Te6+O4(OH)2](OH)7ClTrig. 3 : R3
7.BB.85ParatimroseitePb2Cu4(TeO6)2(H2O)2Orth. 2 2 2 : P21 21 21

Other InformationHide

Notes:
Slowly soluble in cold concentated HCl.
May be weakly magnetic if have iron impurities.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KlebelsbergiteHide

References for KlebelsbergiteHide

Localities for KlebelsbergiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Burgenland
    • Oberwart District
      • Stadtschlaining
Sorrell (n.d.)
France
 
  • Auvergne-Rhône-Alpes
    • Haute-Loire
      • Brioude
        • Ally
Sebastian Axt Collection
        • Saint-Just-près-Brioude
Christophe Samyn collection
  • Brittany
    • Finistère
      • Quimper
        • Quimper
Pierre Le Roch photo & collection
  • Provence-Alpes-Côte d'Azur
    • Hautes-Alpes
      • Gap
        • La Chapelle-en-Valgaudemar
Bourgoin et al. (2011)
Hungary
 
  • Heves County
    • Gyöngyös District
      • Gyöngyösoroszi
HOM Collection-Szakáll S.-2010
Italy
 
  • Tuscany
    • Grosseto Province
      • Scansano
Sitta et al. (1981)
    • Pisa Province
      • Pomarance
Nannoni R. et al. (PI) +1 other reference
    • Siena Province
      • Chiusdino
Sabelli et al. (1984) +1 other reference
Japan
 
  • Ehime Prefecture
    • Saijo City
specimens seen at Kyoto show
Kyrgyzstan
 
  • Batken Region
    • Kadamjay District
      • Aydarken
...
Kolesar et al. (1993)
Luxembourg
 
  • Canton Wiltz
    • Goesdorf
Filella et al. (2009)
Portugal
 
  • Beja
    • Beja
      • Nossa Senhora das Neves
Alves (n.d.)
  • Faro
    • Alcoutim
      • Alcoutim e Pereiro
Pedro Alves analytical data
  • Porto
    • Gondomar
      • Medas
Romania (TL)
 
  • Maramureș County
V. Zsivny (1929) +1 other reference
Damian +7 other references
Marias Francisc
Minerals of Carpathians
Collection: Gábor Koller
Slovakia
 
  • Banská Bystrica Region
    • Žiar nad Hronom District
      • Kremnica
Števko M. et al. (2011) +3 other references
Spain
 
  • Andalusia
    • Almería
      • Pechina
        • Baños de Alhamilla
Rewitzer et al. (2020)
USA
 
  • Nevada
    • White Pine County
      • Taylor Mining District
Castor et al. (2004)
 
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