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Kaliborite

A valid IMA mineral species - grandfathered
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About KaliboriteHide

Formula:
KMg2H[B6O8(OH)5]2(H2O)4
Colour:
Colourless, white, reddish brown; colourless in transmitted light.
Lustre:
Vitreous
Hardness:
4 - 4½
Specific Gravity:
2.05 - 2.109
Crystal System:
Monoclinic
Name:
In allusion to the chemical composition, containing potassium (Latin = KALIum) and being a BORate.
This page provides mineralogical data about Kaliborite.


Unique IdentifiersHide

Mindat ID:
2136
Long-form identifier:
mindat:1:1:2136:0

IMA Classification of KaliboriteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
KHMg2B12O16(OH)10 · 4H2O
First published:
1889

Classification of KaliboriteHide

6.FB.10

6 : BORATES
F : Hexaborates
B : Ino-hexaborates
26.5.13.1

26 : HYDRATED BORATES CONTAINING HYDROXYL OR HALOGEN
5 : Pentaborates
9.2.16

9 : Borates
2 : Borates of Be and Mg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
KboIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KaliboriteHide

Vitreous
Transparency:
Transparent
Colour:
Colourless, white, reddish brown; colourless in transmitted light.
Streak:
White
Hardness:
4 - 4½ on Mohs scale
Cleavage:
Perfect
{001} and {101}; on {100} good.
Density:
2.05 - 2.109 g/cm3 (Measured)    

Optical Data of KaliboriteHide

Type:
Biaxial (+)
RI values:
nα = 1.508 nβ = 1.526 nγ = 1.550
2V:
Measured: 80° , Calculated: 82°
Max. Birefringence:
δ = 0.042
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate
Dispersion:
none

Chemistry of KaliboriteHide

Mindat Formula:
KMg2H[B6O8(OH)5]2(H2O)4
Element Weights:
Element% weight
O66.983 %
B18.105 %
Mg6.784 %
K5.456 %
H2.673 %

Calculated from ideal end-member formula.

Crystallography of KaliboriteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Cell Parameters:
a = 18.57 Å, b = 8.46 Å, c = 14.68 Å
β = 100.02°
Ratio:
a:b:c = 2.195 : 1 : 1.735
Unit Cell V:
2,271.08 ų (Calculated from Unit Cell)
Morphology:
Fine-grained nodular masses. Microscopic rhombic scales with plane angles of about 62°, with the acute angle truncated to yield a hexagonal outline at times. Crystals frequently aggregated and with asymmetrical development.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005415KaliboriteBurns P C, Hawthorne F C (1994) Kaliborite: An example of a crystallographically symmetrical hydrogen bond The Canadian Mineralogist 32 885-89419940293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.22 Å(100)
6.215 Å(100)
3.104 Å(71)
2.488 Å(71)
3.837 Å(50)
3.770 Å(50)
3.359 Å(50)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
25 : Evaporites (prebiotic)

Type Occurrence of KaliboriteHide

Synonyms of KaliboriteHide

Other Language Names for KaliboriteHide

German:Kaliborit
Simplified Chinese:硼钾镁石
Spanish:Kaliborita

Related Minerals - Strunz-mindat GroupingHide

6.FB.05AristarainiteNa2MgB12O20 · 8H2OMon. 2/m : P21/b

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 5.4563% 1,691 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity:

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Other InformationHide

IR Spectrum:
Inder material [cm-1]: 3530sh, 3480sh, 3420, 3350, 3300sh, 3180, 3050sh, 1660sh, 1605w, 1480sh, 1427, 1407, 1338s, 1284s, 1260sh, 1206w, 1174, 1104s, 1051s, 1010sh, 975s, 905sh, 886s, 792, 753, 722, 681, 659, 590, 569, 539, 513, 464
Notes:
Partially soluble in water. Readily soluble in acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KaliboriteHide

References for KaliboriteHide

Reference List:

Localities for KaliboriteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Chile
 
  • Antofagasta
    • Tocopilla Province
      • María Elena
Marta et al. (1996)
Germany (TL)
 
  • Saxony-Anhalt
    • Salzlandkreis
      • Aschersleben
Feit (1889) +1 other reference
      • Staßfurt
Luedecke (1891) +1 other reference
...
Italy
 
  • Sicily
    • Enna Province
      • Calascibetta
Palache et al. (1951)
Kazakhstan
 
  • Aktobe Region
    • Shalkar District
      • Aksai Valley
Pekov (1998) +2 other references
  • Atyrau Region
    • Inder District
Pekov et al. (1993)
  • West Kazakhstan Region
    • Oral
Mineralogical Society of America - ... +1 other reference
Spain
 
  • Catalonia
    • Barcelona
      • Bages
        • Sallent
Pardillo (1947) +1 other reference
Turkey
 
  • Kütahya Province
    • Emet District
      • Doğanlar village
García-Veigas et al. (2010) +2 other references
USA
 
  • California
    • Inyo County
a spectroscopic exploration. Economic ... +1 other reference
 
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