Have a look at the must read at http://pragprog.com/book/bhtmux/tmux; you'll get anything you need
Further on, try out this:
# Setting the prefix from C-b to C-d
# START:prefix
set -g prefix C-d
# END:prefix
# Ensure that we can send Ctrl-A to other apps
bind C-d send-prefix
# Free the original Ctrl-b prefix keybinding unbind C-b
unbind C-b
bind | split-window -h
bind _ split-window -v
And this for moving between panes:
bind h select-pane -L
bind j select-pane -D
bind k select-pane -U
bind l select-pane -R
Both from the previous reference and the man page.
C-b C-x 2instead of the normalC-x 2to split windows.