I downloaded the font RobotoMono-Regular.ttf here, converted it to RobotoMono-Regular.afm with this tool and copied this file to /usr/local/share/enscript/afm where other .afm  files reside. In there is also the file font.map. I added the entry RobotoMono-Regular RobotoMono-Regular (the first entry is the font name, the second the file base name of the .afm. When I use enscript --font=RobotoMono-Regular ..., I don't get the new font, though. Is there anything else that needs to be done? File permissions seem all fine. If I specify the font names of other fonts saved as .afm in this directory, enscript respects them. 
This is under macOS. The question here seems somewhat related but is different.
