I have very long export PATH=A:B:C .... Can I make a multiple lines to have more organized one as follows? 
export PATH = A:
              B:
              C:
You can do:
export PATH="A"
export PATH="$PATH:B"
export PATH="$PATH:C"
Each subsequent line appends onto the previously defined path. This is generally a good habit, as it avoids trashing the existing path. If you want the new component to take precedence, swap the order:
export PATH="A"
export PATH="B:$PATH"
export PATH="C:$PATH"
Alternatively, you might be able to do:
export PATH=A:\
B:\ 
C
where \ marks a line continuation. Haven't tested this method.
export is a built-in command, not a keyword nor a syntactic assignment. So if you have PATH elements containing whitespace (or glob characters), you do need double quotes around export PATH="$PATH:B". You could also write PATH=$PATH:B and so on; you only need to export a variable once, not every time it changes (except in some very old Bourne shells), and you don't need the double quotes in an assignment.
                
                PATH+=:B works for string concatenation.
                
                You can extend lines in bash using a backslash at the end of a line like this:
export PATH=/path/A:\
/path/B:\
/path/C
Please note that the absence of white space is important here.
Another approach:
export PATH=$(tr -d $'\n ' <<< "
   /path/A:
   /path/B:
   /path/C")
Has the added benefit of not messing up your indent levels.