Definitely not in the default constructor. According to the JLS, it happens as a part of evaluation of a class instance creation expression (when you do new ClassName...), before any constructor call. From the JLS, Java SE 8 Edition, 15.9.4:
Next, space is allocated for the new class instance. If there is insufficient space to allocate the object, evaluation of the class instance creation expression completes abruptly by throwing an OutOfMemoryError.
The new object contains new instances of all the fields declared in the specified class type and all its superclasses. As each new field instance is created, it is initialized to its default value (§4.12.5).
Next, the actual arguments to the constructor are evaluated, left-to-right. If any of the argument evaluations completes abruptly, any argument expressions to its right are not evaluated, and the class instance creation expression completes abruptly for the same reason.
Next, the selected constructor of the specified class type is invoked. This results in invoking at least one constructor for each superclass of the class type. This process can be directed by explicit constructor invocation statements (§8.8) and is specified in detail in §12.5.