The most important advice I can give you: just start. A big project can seem overwhelming, especially when you're looking at it like a big project. Instead, break it into small achievable tasks. Find something you can do right now, the ever-so-smallest subset of functionality, and do it. Then do the next one. And the next.
That said, I'll tell you my personal process. When I start on a new application or piece of an application, I first like to create my models. That way I can play with the interactions between them, flesh out the relationships, and think about the needs of my application in a somewhat low-pressure, easily disposable way. I also use code-first, whereas you've gone an created your database tables already. Some people prefer to do it that way. Personally, I find starting with my classes and letting those translate into an underlying data store much more organic. In a sense, it relegates the database to almost a non-existent layer. I don't have to think about what datatype things need to be, what should be indexed and what shouldn't, how querying will work, what kind of stored procedures I need, etc. Those questions have their time and place -- the nascent development stage is not that time and place. You want to give your brain a place to play with ideas, and classes are a cheap and low-friction medium. If an idea doesn't work out, throw the class away and create a new one.
Once I have my models, I like to hit my controllers next. This lets me start to see my models in action. I can play around with the actual flow of my application and see how my classes actually work. I can then make changes to my models where necessary, add additional functionality, etc. I can also start playing around with view models, and figuring out what data should or should not be passed to the view, how it will need to be displayed (will I need a drop down list for that? etc.), and such. This, then, naturally leads me into my views. Again, I'm testing my thinking. With each new layer, I'm hardening the previous by getting a better and better look at how it's working.
Each stage of this process is very liquid. Once I start working on my controllers, I will make changes to my models. Once I hit the views, the controllers will need to be adjusted and perhaps the models as well. You have to give yourself the freedom to screw up. Inevitably, you'll forget something, or design something in a bone-headed way, that you'll only see once you get deeper in. Again, that's the beauty of code-first. Up to this point, I don't even have a database, so any change I make is no big deal. I could completely destroy everything I have and go in a totally different way and I don't have to worry about altering tables, migrating data, etc.
Now, by this point my models are pretty static, and that's when I do my database creation and initial migration. Although, even now, really, only because it's required before I can actually fire this up in a browser to see my views in action. You can always do a migration later, but once you're working with something concrete, the friction starts to increase.
I'll tend to do some tweaking to my controllers and obviously my views, now that I'm seeing them live. Once I'm happy with everything, then I start looking at optimization and refactoring -- How can I make the code more effective? More readable? More efficient? I'll use a tool like Glimpse to look at my queries, render time, etc., and then make decisions about things like stored procedures and such.
Then, it's just a lot of rinse and repeat. Notice that it's all very piecemeal. I'm not building an application; I'm building a class, and then another class, and then some HTML, etc. You focus on just that next piece, that small chunk you need to move on to the next thing, and it's much less overwhelming. So, just as I began, I'll close the same: just start. Writers have a saying that the hardest thing is the first sentence. It's not because the first sentence is really that difficult; it's because once you get that, then you write the second sentence, and the third, and before you know it, you've got pages of writing. The hardest part is in the starting. Everything flows from there.
The other answers here have great advice and important nuggets of information, but I think they do you a disservice at this stage. I'm the first to advocate best practice, proper layering of your applications, etc. But, ultimately, a complete app that follows none of this is more valuable than an incomplete app that incorporates it all. Thankfully, we're working with a malleable medium -- digital text -- and not stone. You can always change things, improve things later. You can go back and separate your app out into the proper layers, create the repositories and services and other abstractions, add in the inversion of control and dependency injection, etc. Those of us who have been doing this awhile do that stuff from the start, but that's because we've been doing this awhile. We know how to do that stuff -- a lot of times we already have classes and libraries we drop in for that stuff. For someone just starting off, or for an app in its earliest nascent stage, it can be crippling, though. Instead of just developing your app, you end up spending days or weeks pouring through recommendations, practices, libraries, etc. trying to get a handle on it all, and by the end you have nothing really to show for it. Don't worry about doing things right and do something. Then, refactor until it's right.
