If you want to insert other string somewhere else in existing string, you may use selection method below.
Calling character on second position:
>>> s = "0123456789"
>>> s[2]
'2'
Calling range with start and end position:
>>> s[4:6]
'45'
Calling part of a string before that position:
>>> s[:6]
'012345'
Calling part of a string after that position:
>>> s[4:]
'456789'
Inserting your string in 5th position.
>>> s = s[:5] + "L" + s[5:]
>>> s
'01234L56789'
Also s is equivalent to s[:].
With your question you can use all your string, i.e.
>>> s = "L" + s + "LL"
or if "L" is a some other string (for example I call it as l), then you may use that code:
>>> s = l + s + (l * 2)