You can create field schema for your external data column. You can follow this link for doing it.
Then use following PowerShell script to create field into list
$web = Get-SPWeb "Web Url"
$list = $web.Lists["Your List Title"]
$fields = $list.Fields
$firstNameColXml = "Your field schema here"
$noteFieldSchema = "Your note field schema"
$fieldBCS = $fields.AddFieldAsXml($firstNameColXml,$true [Microsoft.SharePoint.SPAddFieldOptions]::AddFieldToDefaultView)
$fieldBCS .update()
$fieldBCSNote = $fields.AddFieldAsXml($noteFieldSchema,$true,
[Microsoft.SharePoint.SPAddFieldOptions]::AddFieldToDefaultView)
$fieldBCSNote.update()
Your field schema should be as follows
For BCS Field
<Field Type="BusinessData"
DisplayName="test" Required="FALSE"
ID="{3db01d5e-a61e-47ab-922d-a3ba3db906a8}"
StaticName="test" BaseRenderingType="Text"
Name="test" SystemInstance="[External System]"
EntityNamespace="[Namespace]" EntityName="[Name]"
BdcField="[Field Name in BCS]" HasActions="True"
SecondaryFieldBdcNames="0" RelatedField="[Field Name in BCS]"
SecondaryFieldWssNames="0" RelatedFieldBDCField=""
RelatedFieldWssStaticName="[Field Name in BCS]" SecondaryFieldsWssStaticNames="0" AddFieldOption="AddToAllContentTypes, AddFieldToDefaultView" />
For Note field
<Field Type="Note" DisplayName="[Field display name]" Hidden="TRUE" ReadOnly="TRUE"BdcField="[Field Name in BCS]" ID="{9c03ea22-4a95-4902-b549-90ff7a624530}" StaticName="[Field Name in BCS]" Name="[Field Name in BCS]"/>
Hope it will help to you