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Keplerite

A valid IMA mineral species
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05646050017272473285062.jpg
Johannes Kepler
Formula:
Ca9(Ca0.50.5)Mg(PO4)7
Colour:
Colorless
Lustre:
Vitreous
Specific Gravity:
3.122 (Calculated)
Crystal System:
Trigonal
Name:
Named in honor of Johannes Kepler (27 December 1571, Free Imperial City of Weil der Stadt, Holy Roman Empire – 15 November 1630, Free Imperial City of Regensburg, Holy Roman Empire), a prominent German naturalist, for his contributions to astronomy and crystallography. He built new refracting telescopes and is best known for his laws of planetary motion, describing the orbits as ellipses for the first time.
The Mg analogue of matyhite. Also the Ca◻- (or Ca0.50.5)-analogue of merrillite.

Related to merrillite via the heterovalent substitution at the B-site: 2Na+ (merrillite) → Ca2+ + □ (keplerite).

A characteristic crystallochemical feature: half-vacant occupancy of the sixfold-coordinated B-site.


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Unique IdentifiersHide

Mindat ID:
54347
Long-form identifier:
mindat:1:1:54347:7

IMA Classification of KepleriteHide

Classification of KepleriteHide

8.AD.

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
D : With only large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
KepIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KepleriteHide

Vitreous
Transparency:
Transparent
Colour:
Colorless
Streak:
White
Cleavage:
None Observed
Density:
3.122 g/cm3 (Calculated)

Optical Data of KepleriteHide

Type:
Uniaxial (-)
RI values:
nω = 1.622(1) nε = 1.619(1)
Max. Birefringence:
δ = 0.003
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate
Pleochroism:
Non-pleochroic

Chemistry of KepleriteHide

Mindat Formula:
Ca9(Ca0.50.5)Mg(PO4)7
Element Weights:
Element% weight
O41.874 %
Ca35.588 %
P20.266 %
Mg2.272 %

Calculated from ideal end-member formula.

Crystallography of KepleriteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3c
Cell Parameters:
a = 10.3330(4) Å, c = 37.0668(24) Å
Ratio:
a:c = 1 : 3.587
Unit Cell V:
3427.4 ų
Z:
6

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 2: Planetesimal differentiation and alteration4.566-4.550
6 : Secondary asteroid phases4.566-4.560

Type Occurrence of KepleriteHide

General Appearance of Type Material:
From Marjalahti meteorite: ovoidal to cloudy shape, to 50 μm in size.
Place of Conservation of Type Material:
collections of the Mining Museum, Saint Petersburg Mining University, St. Petersburg, Russia, catalogue number MM74/2-1
Geological Setting of Type Material:
High-temperature environments characterized by extreme depletion of Na; near-end-member mineral: main-group pallasites and angrites; terrestrial material: pyrometamorphic
Associated Minerals at Type Locality:

Other Language Names for KepleriteHide

Dutch:Kepleriet
German:Keplerit

Relationship of Keplerite to other SpeciesHide

Other Members of Merrillite Subgroup:
FerromerrilliteCa9NaFe2+(PO4)7Trig. 3m : R3c
MatyhiteCa18(Ca,◻)2Fe2+2(PO4)14Trig. 3m : R3c
MerrilliteCa9NaMg(PO4)7Trig. 3m : R3m

Related Minerals - Strunz-mindat GroupingHide

8.AD.Unnamed (Monoclinic polymorph of ximengite)Bi(PO4)Mon. 2/m : P21/m
8.AD.MazoriteBa3(PO4)2Trig. 3m (3 2/m) : R3m
8.AD.DeynekoiteCa9◻Fe3+(PO4)7Trig. 3m : R3c
8.AD.Monazite-(Gd)Gd(PO4)Mon.
8.AD.05NahpoiteNa2(PO3OH)Mon. 2/m : P21/m
8.AD.10WeiliteCa(HAsO4)Tric. 1 : P1
8.AD.10ŠvenekiteCa(H2AsO4)2Tric. 1 : P1
8.AD.10MonetiteCa(PO3OH)Tric. 1
8.AD.15Archerite(K,NH4)(H2PO4)Tet. 4 2m : I4 2d
8.AD.15BiphosphammiteNH4(H2PO4)Tet. 4 2 2 : I41 2 2
8.AD.20Phosphammite(NH4)2(PO3OH)Mon. 2/m : P21/b
8.AD.25BuchwalditeNaCa(PO4)Orth. mm2 : Pmn21
8.AD.30SchultenitePb(HAsO4)Mon. 2/m : P2/b
8.AD.35DreyeriteBi(VO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.35Wakefieldite-(La)La(VO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.35Anningite-(Ce)(Ca0.5Ce4+0.5)(VO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.35PretuliteSc(PO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.35Wakefieldite-(Ce)Ce(VO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.35Wakefieldite-(Y)Y(VO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.35Xenotime-(Yb)Yb(PO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.35Chernovite-(Ce)(Ce,Y)(AsO4)Tet.
8.AD.35Xenotime-(Gd)Gd(PO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.35Chernovite-(Y)Y(AsO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.35Xenotime-(Y)Y(PO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.35Wakefieldite-(Nd)Nd(VO4)Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
8.AD.40PucheriteBi(VO4)Orth. mmm (2/m 2/m 2/m)
8.AD.45XimengiteBi(PO4)Trig. 3 2 : P31 2 1
8.AD.50UM2005-35-VO:CaFePSiTh(Th,Ca)(VO4,SiO4,PO4)
8.AD.50RooseveltiteBi(AsO4)Mon. 2/m
8.AD.50Gasparite-(Ce)Ce(AsO4)Mon. 2/m
8.AD.50Monazite-(Sm)Sm(PO4)Mon. 2/m
8.AD.50Monazite-(Ce)Ce(PO4)Mon. 2/m
8.AD.50Monazite-(La)La(PO4)Mon. 2/m
8.AD.50Monazite-(Nd)Nd(PO4)Mon. 2/m
8.AD.50Gasparite-(La)La(AsO4)Mon. 2/m
8.AD.50CheraliteCaTh(PO4)2Mon. 2/m
8.AD.55TetrarooseveltiteBi(AsO4)Tet. 4/m : I41/a
8.AD.60Chursinite[Hg2]2+Hg2+2[AsO4]2Mon. 2/m : P21/b
8.AD.65ClinobisvaniteBi(VO4)Mon. 2/m
8.AD.70GurimiteBa3(VO4)2Trig. 3m : R3m
8.AD.75PicaiteNaCa[AsO3OH][AsO2(OH)2]Mon. 2/m : P21/b

Fluorescence of KepleriteHide

Not fluorescent

Other InformationHide

Notes:
Cation disorder related with vacancy induces splitting of the ν(PO4) vibrational mode (in Raman spectra).
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KepleriteHide

References for KepleriteHide

Localities for KepleriteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Brazil
 
  • Rio de Janeiro
    • Angra dos Reis
      • Ilha Grande
Britvin et al. (2021)
Israel
 
  • Southern District
    • Beersheba Subdistrict
Britvin et al. (2021)
      • Tamar Regional Council
        • Hatrurim Basin
Britvin et al. (2021) +1 other reference
Morocco
 
  • Souss-Massa Region
    • Tata Province
      • Tata Cercle
Slabic (2022)
Russia (TL)
 
  • Republic of Karelia
    • Ladoga Region
      • Viipuri
Britvin et al. (2020)
 
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