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With awk you can try:
awk
awk -F, -v OFS='|' 'NR==1{print $0} NR>1{$1=$1; $5 = $5 FS $6; print $1,$2,$3,$4,$5,$7,$8}' file Name,Age,Country,ID,Address,Category,DOB John Doe|19|England|3653|Manchester, England|Main Worker|20-05-1995
awk -F, -v OFS='|' 'NR==1{print $0} NR>1{$5 = $5 FS $6; print $1,$2,$3,$4,$5,$7,$8}' file Name,Age,Country,ID,Address,Category,DOB John Doe|19|England|3653|Manchester, England|Main Worker|20-05-1995
awk -F, -v OFS='|' 'NR==1{print $0} NR>1{$1=$1; $5 = $5","$5 FS $6; print $1,$2,$3,$4,$5,$7,$8}' file Name,Age,Country,ID,Address,Category,DOB John Doe|19|England|3653|Manchester, England|Main Worker|20-05-1995
awk -F, -v OFS='|' 'NR==1{print $0} NR>1{$1=$1; $5 = $5"," $6; print $1,$2,$3,$4,$5,$7,$8}' file Name,Age,Country,ID,Address,Category,DOB John Doe|19|England|3653|Manchester, England|Main Worker|20-05-1995
awk -F, -v OFS='|' 'NR>1'NR==1{print $0} NR>1{$1=$1; $5 = $5"," $6; print $1,$2,$3,$4,$5,$7,$8}' file Name,Age,Country,ID,Address,Category,DOB John Doe|19|England|3653|Manchester, England|Main Worker|20-05-1995
awk -F, -v OFS='|' 'NR>1 {$1=$1; $5 = $5"," $6; print $1,$2,$3,$4,$5,$7,$8}' file John Doe|19|England|3653|Manchester, England|Main Worker|20-05-1995