notify-send --icon=/path/to/XX.png will only set the icon displayed in the dialog,
But for the tray icon, you need to refer to your KDE plasma theme, usually a svg image in the folder, e.gwhich is theme_dir/icons/notification.svgz
To find all your kde plasma themes installed, check out these two locations,
/usr/share/kde4/apps/desktoptheme/ (system location)
And ~/.kde4/share/apps/desktoptheme/