Try using something with proper Unicode support, such as Python:
$ python3 -c 'import sys; print("\n".join(sorted(set(c for l in sys.stdin.readlines() for c in l.split()))))' < bar
⊙'
☯*
'.
ᵒO
⊕o
½
.ɔ
✖Θ
☜۞
❊۩
๑
ღ
ᴗ
♨ᵒ
O‿
۩⊕
☎⊙
☏◎
o◕
‿☎
۞☏
☞☜
ღ☞
Θ☯
*♋
◕♨
ɔ♬
♋✖
❂
♬
◎❊
$ python3 -c 'import sys; print(len(set(c for l in sys.stdin.readlines() for c in l.split())))' < bar
30