X[Y] is identical to *(X + Y) as long as one of X and Y is of pointer type and the other has integral type. So b[-1] is the same as *(b - 1), which is an expression that may or may not be evaluated in a well-formed program – it all depends on the initial value of b! For example, the following is perfectly fine:
int q[24];
int * b = q + 13;
b[-1] = 9;
assert(q[12] == 9);
In general, it is your responsibility as a programmer to guarantee that pointers have permissible values when you perform operations with them. If you get it wrong, your program has undefined behaviour. For example:
int * c = q; // q as above
c[-1] = 0; // undefined behaviour!
Finally, just to reinforce the original statement, the following is fine, too:
std::cout << 2["Good morning"] << 4["Stack"] << 8["Overflow\n"];
bto.[]operator). As others have pointed out, the negative index can be legal. Tricky code like this makes a good learning exercise, but try to avoid it in production code.