No, using encode() to hexlify isn't nice.
The way you use the hex codec worked in Python 2 because you can call encode() on 8-bit strings in Python 2, ie you can encode something that is already encoded. That doesn't make sense. encode() is for encoding Unicode strings into 8-bit strings, not for encoding 8-bit strings as 8-bit strings.
In Python 3 you can't call encode() on 8-bit strings anymore, so the hex codec became pointless and was removed.
Although you theoretically could have a hex codec and use it like this:
>>> import codecs
>>> hexlify = codecs.getencoder('hex')
>>> hexlify(b'Blaah')[0]
b'426c616168'
Using binascii is easier and nicer:
>>> import binascii
>>> binascii.hexlify(b'Blaah')
b'426c616168'
hex(n).