(I do realise the question is old, but it's among the top hits on Google.)
A common situation where you want to know the response code is in exception handling. As of C# 7, you can use pattern matching to actually only enter the catch clause if the exception matches your predicate:
catch (WebException ex) when (ex.Response is HttpWebResponse rresponse)
{
&& r.StatusCode == HttpStatusCode.NotFound) ..doSomething(response.StatusCode)
}
This can easily be extended to further levels, such as in this case where the WebException was actually the inner exception of another (and we're only interested in 404):
catch (StorageException ex) when (ex.InnerException is WebException wex && wex.Response is HttpWebResponse r && r.StatusCode == HttpStatusCode.NotFound)
Finally: note how there's no need to re-throw the exception in the catch clause when it doesn't match your criteria, since we don't enter the clause in the first place with the above solution.