The symbol / is the matrix right division operator in MATLAB, which calls the mrdivide function. From the documentation, matrix right division is related to matrix left division in the following way:
B/A = (A'\B')'
If A is a square matrix, B/A is roughly equal to B*inv(A) (although it's computed in a different, more robust way). Otherwise, x = B/A is the solution in the least squares sense to the under- or over-determined system of equations x*A = B. More detail about the algorithms used for solving the system of equations is given here. Typically packages like LAPACKLAPACK or BLASBLAS are used under the hood.
The NumPy packageNumPy package for Python contains a routine lstsqlstsq for computing the least-squares solution to a system of equations. This routine will likely give you comparable results to using the mrdivide function in MATLAB, but it is unlikely to be exact. Any differences in the underlying algorithms used by each function will likely result in answers that differ slightly from one another (i.e. one may return a value of 1.0, whereas the other may return a value of 0.999). The relative size of this error could end up being larger, depending heavily on the specific system of equations you are solving.
To use lstsq, you may have to adjust your problem slightly. It appears that you want to solve an equation of the form cB = a, where B is 25-by-18, a is 1-by-18, and c is 1-by-25. Applying a transposetranspose to both sides gives you the equation BTcT = aT, which is a more standard form (i.e. Ax = b). The arguments to lstsq should be (in this order) BT (an 18-by-25 array) and aT (an 18-element array). lstsq should return a 25-element array (cT).
Note: while NumPy doesn't make any distinction between a 1-by-N or N-by-1 array, MATLAB certainly does, and will yell at you if you don't use the proper one.